Kinetics and mechanisms of gas phase elimination of ethyl 1-piperidine carboxylate, ethyl pipecolinate, and (revisited) ethyl 1-methyl pipecolinate

International Journal of Chemical Kinetics

Volumn 37, Issue 6, 2005, Pages 383-389

  Rosas, Felix ^a   Monsalve, Angiebelk ^b   Tosta, Maria ^c   Herize, Armando ^c   Domínguez, Rosa M ^c   Brusco, Doris ^a   Chuchani, Gabriel ^c  

^a UNIVERSIDAD DE ORIENTE   (Venezuela)

^b UNIVERSIDAD DE CARABOBO   (Venezuela)

^c INSTITUTO VENEZOLANO DE INVESTIGACIONES CIENTÍFICAS   (Venezuela)

Author keywords

[No Author keywords available]

Indexed keywords

CARBOXYLATION; CARBOXYLIC ACIDS; ESTERS; ETHYLENE; MOLECULAR STRUCTURE; REACTION KINETICS; THERMODYNAMICS;

DECARBOXYLATION PROCESSES; GAS-PHASE ELIMINATIONS; STATIC REACTION SYSTEM; UNIMOLECULAR;

INORGANIC COMPOUNDS;

EID: 27744487624     PISSN: 05388066     EISSN: None     Source Type: Journal    
DOI: 10.1002/kin.20084     Document Type: Article

References (25)

1. Ensuncho, A.; Lafont, J.; Rotinov, A.; Domínguez, R. M.; Herize, A.; Quijano, J.; Chuchani, G. Int J Chem Kinet 2001, 33, 465-471, and references therein.
2. Lafont, J.; Ensuncho, A.; Domínguez, R. M.; Rotinov, A.; Herize, A.; Quijano, J.; Chuchani, G. J Phys Org Chem 2003, 16, 84-88.
3. Dominguez, R. M.; Tosta, M.; Chuchani, G. J Phys Org Chem 2003, 16, 869-874.
4. Safont, V. S.; Moliner, V.; Andres, J.; Domingo, L. R. J Phys Chem A 1997, 101, 1859-1865.
5. Domingo, L. R.; Andres, J.; Moliner, V.; Safont, V. S. J Am Chem Soc 1997, 119, 6415-6422.
6. Domingo, L. R.; Pitcher, M. T.; Andres, J.; Moliner, V.; Safont, V. S; Chuchani, G. Chem Phys Lett 1997, 274, 422-428.
7. Domingo, L. R.; Pitcher, M. T.; Safont, V.; Andres, J.; Chuchani, G. J Phys Chem A 1999, 103, 3935-3943.
8. Rotinov, A.; Chuchani, G.; Andres, J.; Domingo, L. R.; Safont, V. S. Chem Phys 1999, 246, 1-12.
9. Chuchani, G.; Domínguez, R. M.; Rotinov, A.; Martín, I. J Phys Org Chem 1999, 12, 612-618.
10. Chuchani, G.; Domínguez, R. M.; Herize, A.; Romero, R. J Phys Org Chem 2000, 13, 757-764.
11. Daly, N. J.; Ziolkowski, F. Aust J Chem 1971, 24, 2451-2456.
12. Gordon, A. S.; Norris, W. P. J Phys Chem 1965, 69, 3013-3017.
13. Kwart, H.; Slutsky, J. J Chem Soc Chem Commun 1972, 552-553.
14. Daly, N. J.; Ziolkowski, F. Aust J Chem 1972, 25, 1453-1458.
15. Kwart, H.; Slutsky, J. J Chem Soc Chem Commun 1972, 1182-1183.
16. Herize, A.; Domínguez, R. M.; Rotinov, A.; Nuñez, O.; Chuchani, G. J Phys Org Chem 1999, 12, 201-206.
17. Daly, N. J.; Ziolkowsky, F. J Chem Soc Chem Commun 1972, 911-912.
18. Luiggi, M.; Dominguez, R. M.; Rotinov, A.; Herize, A.; Cordova, M.; Chuchani, G. Int J Chem Kinet 2002, 34, 1-5.
19. Chuchani, G.; Nuñez, O.; Marcano, N.; Napolitano, S.; Rodríguez, H.; Domínguez, M.; Ascanio, J.; Rotinov, A.; Domínguez, R. M.; Herize, A. J Phys Org Chem 2001, 14, 146-158.
20. Chuchani, G.; Domínguez, R. M.; Rotinov, A.; Herize, A. J Phys Org Chem 1999, 16, 40-46.
21. Maccoll, A. J Chem Soc 1955, 965-973.
22. Swinbourne, E. S. Aust J Chem 1958, 11, 314-330.
23. Dominguez, R. M.; Herize, A.; Rotinov, A.; Alvarez-Aular, A.; Visbal, G.; Chuchani, G. J Phys Org Chem 2004, 17, 399-408.
24. Taylor, R. The Chemistry of Functional Groups, Supplementary Volume B: Acid Derivatives, Patai, S. (Ed); Wiley: Chichester, 1979; Ch. 15, pp. 859-914.
25. Holbrook, K. A. The Chemistry of Acids Derivatives, Volume 2: Vapor and Gas Phase Reactions of Carboxylic Acids and Their Derivatives, Patai, S. (Ed); Wiley: Chichester, 1992; Ch. 12, pp. 703-746.