Construction of the tricyclic 5-7-6 scaffold of fungi-derived diterpenoids. Total synthesis of (±)-heptemerone G and an approach to Danishefsky's intermediate for guanacastepene A synthesis

Journal of Organic Chemistry

Volumn 75, Issue 24, 2010, Pages 8337-8350

  Michalak, Karol ^a   Michalak, Michał ^a   Wicha, Jerzy ^a  

^a POLISH ACADEMY OF SCIENCES   (Poland)

Author keywords

[No Author keywords available]

Indexed keywords

AZULENES; BUILDING BLOCKES; CONJUGATE ADDITION; DIASTEREOSELECTIVE; DITERPENOIDS; ENOLATES; FACIAL SELECTIVITY; KETALIZATION; KEY FEATURE; METATHESIS REACTIONS; METHYLENATION; SYNTHETIC METHODS; TOTAL SYNTHESIS;

ALKYLATION; KETONES; LIPIDS; SCAFFOLDS; STEREOCHEMISTRY;

SYNTHESIS (CHEMICAL);

AZULENE DERIVATIVE; CARBONYL DERIVATIVE; DITERPENOID; GUANACASTEPENE A; HEPTEMERONE G; KETONE; UNCLASSIFIED DRUG;

ADDITION REACTION; ALKYLATION; ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; DRUG STRUCTURE; DRUG SYNTHESIS; EPOXIDATION; MUKAIYAMA MICHAEL REACTION; PROTON NUCLEAR MAGNETIC RESONANCE; STEREOCHEMISTRY;

ALKYLATION; CATALYSIS; DITERPENES; FUNGI; KETONES; KINETICS; MAGNETIC RESONANCE SPECTROSCOPY; MOLECULAR STRUCTURE; STEREOISOMERISM;

EID: 78650403061     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo101758t     Document Type: Article

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