Enantioselective total synthesis of a trans-hydrindane rings/side-chain building-block of vitamin D - Asymmetric induction in an acid-catalyzed conjugate-addition reaction

European Journal of Organic Chemistry

Volumn , Issue 4, 2004, Pages 783-799

  Gorobets, Evgueni ^a   Stepanenko, Viatcheslav ^a   Wicha, Jerzy ^a  

^a INSTITUTE OF ORGANIC CHEMISTRY   (Poland)

Author keywords

Asymmetric synthesis; Diastereoselectivity; Induced diastereoselectivity; Total synthesis; Vitamin D

Indexed keywords

1 (PHENYLTHIO)BUT 3 EN 2 ONE; 1 (TERT BUTYLTHIO) 3 (2,2 DIMETHYL 1,3 DIOXOLAN 4 YL) 1 (TRIMETHYLSILYLOXY)PROP 1 ENE; 1 (TERT BUTYLTHIO) 3 (2,2,5,5 TETRAMETHYL 1,3 DIOXOLAN 4 YL) 1 (TRIMETHYLSILYLOXY)PROP 1 ENE; 1 (TERT BUTYLTHIO) 4 (2,2,5,5 TETRAMETHYL 1,3 DIOXOLAN 4 YL) 1 TRIMETHYLSILYLOXYBUT 1 ENE; 1,3 DIOXOLANE DERIVATIVE; 2 METHYL 6 [7A METHYL 4 (PHENYLSULFONYL)OCTAHYDRO 1H INDEN 1 YLHEPTAN 2 OL]; 2 METHYLCYCLOPENT 2 EN 1 ONE; 6 O (TERT BUTYLDIMETHYLSILYL) 7,7 DIMETHYL 2 O (TRIMETHYLSILYL) 4,5,6,7 TETRAHYDROOXEPINE 2,6 DIOL; ACETAL DERIVATIVE; ACID; CALCITRIOL; CYCLOPENTENONE DERIVATIVE; HEPTANE DERIVATIVE; HEXANOIC ACID; KETENE DERIVATIVE; METHYL GROUP; PHENYL GROUP; PROPYLENE; UNCLASSIFIED DRUG; VITAMIN D;

ADDITION REACTION; ARTICLE; CATALYSIS; CHEMICAL REACTION; CONJUGATE; ENANTIOSELECTIVITY; STEREOCHEMISTRY; STEREOSPECIFICITY; SYNTHESIS;

EID: 4544268731     PISSN: 1434193X     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejoc.200300611     Document Type: Article

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