Stereoselective construction of seven-membered rings with an all-carbon quaternary center by direct tiffeneau-demjanov-type ring expansion

Journal of the American Chemical Society

Volumn 131, Issue 18, 2009, Pages 6614-6617

  Hashimoto, Takuya ^a   Naganawa, Yuki ^a   Maruoka, Keiji ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS;

C-C BONDS; CARBOCYCLES; CYCLOHEXANONES; DIASTEREOSELECTIVE; DIAZOALKANES; NUCLEOPHILIC ADDITIONS; QUATERNARY CENTERS; RING EXPANSION; SEVEN-MEMBERED RINGS; STEREOGENIC CENTERS; STEREOSELECTIVE CONSTRUCTION; STRAIGHT-FORWARD METHOD;

STEREOSELECTIVITY;

CYCLOHEPTANE DERIVATIVE; CYCLOHEPTANONE; CYCLOHEXANONE DERIVATIVE;

CHEMISTRY; STEREOISOMERISM; SYNTHESIS;

CYCLOHEPTANES; CYCLOHEXANONES; STEREOISOMERISM;

EID: 69949118503     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja900941k     Document Type: Article

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