Pentacyano-N,N-dimethylaniline in the excited state. only locally excited state emission, in spite of the large electron affinity of the pentacyanobenzene subgroup

Journal of Physical Chemistry A

Volumn 114, Issue 50, 2010, Pages 13031-13039

  Zachariasse, Klaas A ^a   Druzhinin, Sergey I ^a   Galievsky, Victor A ^a,b   Demeter, Attila ^a,c   Allonas, Xavier ^d   Kovalenko, Sergey A ^e   Senyushkina, Tamara A ^a  

^a MAX PLANCK INSTITUTE FOR BIOPHYSICAL CHEMISTRY   (Germany)

^b B I STEPANOV INSTITUTE OF PHYSICS   (Belarus)

^c CHEMICAL RESEARCH CENTER   (Hungary)

^d UNIVERSITÉ DE HAUTE ALSACE   (France)

^e HUMBOLDT UNIVERSITY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

4-(DIMETHYLAMINO)BENZONITRILE; BENZONITRILES; DECAY TIME; EXCITED STATE ABSORPTION; FEMTOSECONDS; FLUORESCENCE DECAY TIME; FLUORESCENCE QUANTUM YIELD; INTERNAL CONVERSIONS; INTERSYSTEM CROSSING; INTRAMOLECULAR CHARGE TRANSFERS; LOCALLY EXCITED STATE; N ,N-DIMETHYLANILINE; N-HEXANE; PHENYLPYRROLE; POLAR SOLVENTS; RADIATIVE RATE CONSTANTS; RATE CONSTANT K; REDUCTION POTENTIAL; ROOM TEMPERATURE; SATURATED CALOMEL ELECTRODE; SINGLET EXCITED STATE; TWIST ANGLES;

ACETONITRILE; CHARGE TRANSFER; DECAY (ORGANIC); ELECTRON AFFINITY; ENERGY GAP; FLUORESCENCE; HEXANE; ION EXCHANGE; ORGANIC POLYMERS; ORGANIC SOLVENTS; POLYMER BLENDS; QUANTUM YIELD; RATE CONSTANTS; SOLIDS;

EXCITED STATES;

4 DIMETHYLAMINOBENZONITRILE; 4-(N,N-DIMETHYLAMINO)BENZONITRILE; ACETONITRILE; ACETONITRILE DERIVATIVE; ANILINE DERIVATIVE; BENZENE; BETA (DIETHYLAMINO)ISOBUTYRONITRILE; BETA-(DIETHYLAMINO)ISOBUTYRONITRILE; NITRILE;

ABSORPTION; ARTICLE; CHEMISTRY; ELECTRON; KINETICS; SPECTROFLUOROMETRY; THERMODYNAMICS;

ABSORPTION; ACETONITRILES; ANILINE COMPOUNDS; BENZENE; ELECTRONS; KINETICS; NITRILES; SPECTROMETRY, FLUORESCENCE; THERMODYNAMICS;

EID: 78650338762     PISSN: 10895639     EISSN: 15205215     Source Type: Journal    
DOI: 10.1021/jp108804q     Document Type: Article

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