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It should be noted that also here, as with the amino groups, the impact of the reduction potential of the benzonitrile unit on the energy E(ICT) only shows a correlation factor much smaller than unity (ref. [9]).
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The modification of the Fluoromax-3 spectrofluorometer consists in the Peltier-cooling down to -10°C of the detector photomultiplier (PMT, Hamamatsu R928P) located in a housing (with external water circuit) outside of the Fluoromax-3. The exit slit of the monochromator is focused on the PMT photocathode by an optimized toric mirror.
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27844473735
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note
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It is of interest to note here that the maximum of the main band in the absorption spectrum of the ICT state of DMABN in MeCN is at a longer wavelength (320 nm, refs. [6,51]) than that of the benzonitrile radical anion (314 nm) in the similar aprotic solvent dimethylformamide (ref. [53]). Such a rather small difference is not too surprising, in view of the presence of the electronically coupled (ref. [9]) dimethyl-amino group in DMABN.
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76
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27844451481
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note
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-1 (DMABN).
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78
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0036201889
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