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Volumn 29, Issue 22, 2010, Pages 5941-5945

Phthalazin-2-ylidenes as cyclic amino aryl carbene ligands in rhodium(I) and iridium(I) complexes

Author keywords

[No Author keywords available]

Indexed keywords

ARYL RINGS; BOND DISTANCE; CARBENE LIGANDS; CARBENES; ELECTRON DENSITY DELOCALIZATION; METALATIONS; SINGLE BOND;

EID: 78650091937     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om100723b     Document Type: Article
Times cited : (29)

References (41)
  • 20
    • 44649120827 scopus 로고    scopus 로고
    • Tautomerization from a 1,4-benzodiazepine complex
    • Tautomerization from a 1,4-benzodiazepine complex: Gribble, M. W., Jr.; Ellman, J. A.; Bergman, R. G. Organometallics 2008, 27, 2152-2155
    • (2008) Organometallics , vol.27 , pp. 2152-2155
    • Gribble Jr., M.W.1    Ellman, J.A.2    Bergman, R.G.3
  • 22
    • 77950956676 scopus 로고    scopus 로고
    • Direct metalation from indazolium salts
    • Direct metalation from indazolium salts: Jothibasu, R.; Huynh, H. V. Chem. Commun. 2010, 46, 2986-2988
    • (2010) Chem. Commun. , vol.46 , pp. 2986-2988
    • Jothibasu, R.1    Huynh, H.V.2
  • 31
    • 78650081874 scopus 로고    scopus 로고
    • Accordingly, it has been demonstrated in the isoquinolin-1-ylidene series (ref 8) that the substitution pattern in the aromatic ring strongly influences the catalytic activity of the complex.
    • Accordingly, it has been demonstrated in the isoquinolin-1-ylidene series (ref 8) that the substitution pattern in the aromatic ring strongly influences the catalytic activity of the complex.
  • 32
    • 78650116861 scopus 로고    scopus 로고
    • The complex shows a torsion C(ortho)-C-(ipso)-C(carbene)-Rh angle of 35.0(4)°.
    • The complex shows a torsion C(ortho)-C-(ipso)-C(carbene)-Rh angle of 35.0(4)°.
  • 36
    • 78650082724 scopus 로고    scopus 로고
    • 1H NMR spectrum (see Supporting Information), a relatively fast H-Rh bond exchange is assumed to occur in solution.
    • 1H NMR spectrum (see Supporting Information), a relatively fast H-Rh bond exchange is assumed to occur in solution.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.