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Accordingly, it has been demonstrated in the isoquinolin-1-ylidene series (ref 8) that the substitution pattern in the aromatic ring strongly influences the catalytic activity of the complex.
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The complex shows a torsion C(ortho)-C-(ipso)-C(carbene)-Rh angle of 35.0(4)°.
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1H NMR spectrum (see Supporting Information), a relatively fast H-Rh bond exchange is assumed to occur in solution.
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1H NMR spectrum (see Supporting Information), a relatively fast H-Rh bond exchange is assumed to occur in solution.
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