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To the best of our knowledge, no study has been reported for the structural analysis of the nontethered NHC-oxazoline Pd complex. Therefore, it is not clear whether these Pd complexes naturally prefer to form trans complexes. We assume that these complexes prefer to form trans complexes since several nontethered trans NHC-pyridine Pd complexes and a trans NHC-imidazole Pd complex and a dinuclear trans NHC-oxazole Pd complex (ref 2) have been reported in the literature. See
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To the best of our knowledge, no study has been reported for the structural analysis of the nontethered NHC-oxazoline Pd complex. Therefore, it is not clear whether these Pd complexes naturally prefer to form trans complexes. We assume that these complexes prefer to form trans complexes since several nontethered trans NHC-pyridine Pd complexes and a trans NHC-imidazole Pd complex and a dinuclear trans NHC-oxazole Pd complex (ref 2) have been reported in the literature. See: O'Brien, C. J.; Kantchev, E. A. B.; Valente, C.; Hadei, N.; Chass, G. A.; Lough, A.; Hopkinson, A. C.; Organ, M. G. Chem.-Eur. J. 2006, 12, 4743-4748
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6 rather than that of 15-Cl
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6 rather than that of 15-Cl.
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23
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78649811267
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-1)) and found that the values of the C=N stretching vibrations were different. However, it is difficult to determine whether the binding of an oxazoline onto a metal is present by infrared spectroscopy in this study. It is also possible that the exchange of the anion occurred during the observation of IR of the compounds in KBr pellet
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-1)) and found that the values of the C=N stretching vibrations were different. However, it is difficult to determine whether the binding of an oxazoline onto a metal is present by infrared spectroscopy in this study. It is also possible that the exchange of the anion occurred during the observation of IR of the compounds in KBr pellet.
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