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Volumn 29, Issue 23, 2010, Pages 6291-6297

Synthesis and characterization of silver and palladium complexes with xanthene-based n-heterocyclic carbene-oxazoline ligands

Author keywords

[No Author keywords available]

Indexed keywords

AG ATOMS; DONOR LIGANDS; N-HETEROCYCLIC CARBENES; NHC LIGANDS; OXAZOLINE LIGANDS; OXAZOLINES; PALLADIUM COMPLEXES; PD COMPLEX; SEQUENTIAL COUPLING; SILVER COMPLEXES; SYNTHESIS AND CHARACTERIZATIONS; TRANS CONFIGURATION; X-RAY CRYSTALLOGRAPHIC ANALYSIS;

EID: 78649811408     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om100673e     Document Type: Article
Times cited : (18)

References (26)
  • 19
    • 33745472389 scopus 로고    scopus 로고
    • To the best of our knowledge, no study has been reported for the structural analysis of the nontethered NHC-oxazoline Pd complex. Therefore, it is not clear whether these Pd complexes naturally prefer to form trans complexes. We assume that these complexes prefer to form trans complexes since several nontethered trans NHC-pyridine Pd complexes and a trans NHC-imidazole Pd complex and a dinuclear trans NHC-oxazole Pd complex (ref 2) have been reported in the literature. See
    • To the best of our knowledge, no study has been reported for the structural analysis of the nontethered NHC-oxazoline Pd complex. Therefore, it is not clear whether these Pd complexes naturally prefer to form trans complexes. We assume that these complexes prefer to form trans complexes since several nontethered trans NHC-pyridine Pd complexes and a trans NHC-imidazole Pd complex and a dinuclear trans NHC-oxazole Pd complex (ref 2) have been reported in the literature. See: O'Brien, C. J.; Kantchev, E. A. B.; Valente, C.; Hadei, N.; Chass, G. A.; Lough, A.; Hopkinson, A. C.; Organ, M. G. Chem.-Eur. J. 2006, 12, 4743-4748
    • (2006) Chem.-Eur. J. , vol.12 , pp. 4743-4748
    • O'Brien, C.J.1    Kantchev, E.A.B.2    Valente, C.3    Hadei, N.4    Chass, G.A.5    Lough, A.6    Hopkinson, A.C.7    Organ, M.G.8
  • 22
    • 78649812874 scopus 로고    scopus 로고
    • 6 rather than that of 15-Cl
    • 6 rather than that of 15-Cl.
  • 23
    • 78649811267 scopus 로고    scopus 로고
    • -1)) and found that the values of the C=N stretching vibrations were different. However, it is difficult to determine whether the binding of an oxazoline onto a metal is present by infrared spectroscopy in this study. It is also possible that the exchange of the anion occurred during the observation of IR of the compounds in KBr pellet
    • -1)) and found that the values of the C=N stretching vibrations were different. However, it is difficult to determine whether the binding of an oxazoline onto a metal is present by infrared spectroscopy in this study. It is also possible that the exchange of the anion occurred during the observation of IR of the compounds in KBr pellet.
  • 26
    • 37549039510 scopus 로고    scopus 로고
    • A short history of SHELX
    • A short history of SHELX. Sheldrick, G. M. Acta Crystallogr. 2008, A64, 112-122
    • (2008) Acta Crystallogr. , vol.64 , pp. 112-122
    • Sheldrick, G.M.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.