Electrostatically controlled hierarchical arrangement of monocationic silver(I) and dicationic mercury(II) ions between disk-shaped template ligands

Journal of the American Chemical Society

Volumn 128, Issue 40, 2006, Pages 13038-13039

  Hiraoka, Shuichi ^a,b   Tanaka, Takaaki ^a   Shionoya, Mitsuhiko ^a  

^a UNIVERSITY OF TOKYO   (Japan)

^b JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CATION; LIGAND; MERCURY; SILVER;

ARTICLE; BINDING AFFINITY; COMPLEX FORMATION; ELECTROSPRAY MASS SPECTROMETRY; METAL BINDING; PROTON NUCLEAR MAGNETIC RESONANCE; THERMODYNAMICS;

EID: 33749511625     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja064194f     Document Type: Article

References (15)

1. (a) Kahn, O. Acc. Chem. Res. 2000, 33, 647-657.
2. (b) Patitjen, A.; Kyritsakas, N.; Lehn, J.-M. Chem. Commun. 2004, 1168-1169.
3. (c) Uppadine, L. H.; Gisselbech, J.-P.; Kyritsakas, N.; Nättinen, K.; Rissanen, K.; Lehn, J.-M. Chem.-Eur. J. 2005, 11, 2549-2565.
4. (d) Bassani, D. M.; Lehn, J.-M.; Serroni, S.; Puntoriero, F.; Campagna, S. Chem.-Eur. J. 2003, 9, 5936-5946.
5. (e) Albrecht, M.; Mlrtschin, S.; de Groot, M.; Janser, I.; Runsink, J.; Raabe, G.; Kogej, M.; Schalley, C. A.; Fröhlich, R. J. Am. Chem. Soc. 2005, 127, 10371-10387 and references therein.
6. (f) Akine, S.; Taniguchi, T.; Saiki, T.; Nabeshima, T. J. Am. Chem. Soc. 2005, 127, 540-541.
7. (g) Akine, S.; Matsumoto, T.; Taniguchi, T.; Nabeshima, T. Inorg. Chem. 2005, 44, 3270-3274.
8. (h) Yamamoto, K.; Higuchi, M.; Shiki, S.; Tsuruta, M.; Chiba, H. Nature 2002, 415, 509-511.
9. Okada, T.; Tanaka, K.; Shiro, M.; Shionoya, M. Chem. Commun. 2005, 1484-1486. For heterometal arrangement of coordinatively inert metal ions that prefer six-coordinate octahedral geometry (Ru, Os, Fe), a sequential self-assembly with protection/deprotection steps has been established. See ref 1d.
10. Hiraoka, S.; Harano, K.; Tanaka, T.; Shiro, M.; Shionoya, M. Angew. Chem., Int. Ed. 2003, 42, 5182-8185.
11. 2+.
12. 2 complex.
13. 1 of the ligand 1 were assigned according to data of model compounds 3 and 4 (Figure 2a and d).
14. 2+. See Supporting Information.
15. 2 sites, respectively, is most stable among other isomers. See Supporting Information.