Carbon and hydrogen isotopic reversals in deep basin gas: Evidence for limits to the stability of hydrocarbons

Organic Geochemistry

Volumn 41, Issue 12, 2010, Pages 1285-1296

  Burruss, R C ^a   Laughrey, C D ^b,c  

^a U S GEOLOGICAL SURVEY   (United States)

^b Topographic and Geologic Survey   (United States)

^c Weatherford Laboratories   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AB INITIO; APPALACHIAN BASIN; C-C BONDS; CARBON AND HYDROGENS; CARBON ISOTOPIC COMPOSITION; CATAGENESIS; CURRENT MODELS; DEEP BASIN; FORMATION WATER; FRACTIONATION FACTORS; HYDROCARBON GAS; ISOTOPIC EXCHANGE; LATE STAGE; NATURAL GAS RESOURCES; ORDOVICIAN; RAYLEIGH FRACTIONATION; SEDIMENTARY BASIN; THERMAL MATURITY; UNCONVENTIONAL NATURAL GAS;

ENERGY RESOURCES; ETHANE; GASES; METHANE; NATURAL GAS; NATURAL GAS DEPOSITS; ORGANIC COMPOUNDS; PETROLEUM DEPOSITS; PROPANE; REDOX REACTIONS; TRANSITION METALS;

ISOTOPES;

ALKANE; CARBON ISOTOPE; GAS; HYDROGEN ISOTOPE; ISOTOPIC COMPOSITION; ISOTOPIC FRACTIONATION; NUMERICAL MODEL; OBSERVATIONAL METHOD; PALEOENVIRONMENT; PALEOZOIC; RAYLEIGH NUMBER; REDOX POTENTIAL; SEDIMENT CHEMISTRY; SEDIMENTARY BASIN; TEMPERATURE EFFECT;

APPALACHIAN BASIN;

EID: 78649634278     PISSN: 01466380     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.orggeochem.2010.09.008     Document Type: Article

References (60)

1. Barker J.F., Pollock S.J. The geochemistry and origin of natural gases in southern Ontario. Bulletin of Canadian Petroleum Geology 1984, 32:313-326.
2. Behar F., Kressmann S., Rudkiewicz J.L., Vandenbroucke M. Experimental simulation in a confined system and kinetic modelling of kerogen and oil cracking. Organic Geochemistry 1992, 19:173-189.
3. Bernard B.B., Brooks J.M., Sackett W.M. Natural gas seepage in the Gulf of Mexico. Earth and Planetary Science Letters 1976, 31:48-54.
4. Berner U., Faber E., Scheeder G., Panten D. Primary cracking of algal and landplant kerogens: kinetic models of isotope variations in methane, ethane, and propane. Chemical Geology 1995, 126:233-245.
5. Bottinga Y. Calculated fractionation factors for carbon and hydrogen isotope exchange in the system calcite-carbon dioxide-graphite-methane-hydrogen-water vapor. Geochimica et Cosmochimica Acta 1969, 33:49-64.
6. Breen, K.J., Angelo, C.G., Masters, R.W., Sedam, A.C., 1985. Chemical and isotopic characteristics of brines from three oil- and gas-producing sandstones in eastern Ohio, with applications to the geochemical tracing of brine sources. US Geological Survey Water-Resources Investigations Report 84-4314, 63 p.
7. Burruss, R.C., 1993. Stability and flux of methane in the deep crust - a review. In: Howell, D.G. (Ed.), The Future of Energy Gases, US Geological Survey Professional Paper 1570, pp. 21-29.
8. Burruss, R.C., Ryder, R.T., 2003. Composition of crude oil and natural gas produced from 14 wells in the Lower Silurian "Clinton" sandstone and Medina Group, northeastern Ohio and northwestern Pennsylvania, US Geological Survey Open File Report 03-409, 64 p.
9. Chung H.M., Gormly J.R., Squires R.M. Origin of gaseous hydrocarbons in subsurface environments: theoretical considerations of carbon isotope distribution. Chemical Geology 1988, 71:97-103.
10. Cole, D.R., Chakraborty, S., 2001. Rates and mechanisms of isotopic exchange. In: Valley, J.W., Cole, D.R. (Eds.), Stable Isotope Geochemistry, Reviews in Mineralogy and Geochemistry 43, pp. 83-191.
11. Cook J.E., Dunne W.M., Onasch C.M. Development of a dilatant damage zone along a thrust relay in a low-porosity quartz arenite. Journal of Structural Geology 2006, 28:776-792.
12. 13C values for biogenic gases in China. Organic Geochemistry 2004, 35:405-411.
13. Dennen, K.O., Deering, M., Burruss, R.C., 2007. The geochemistry of oils and gases from the Cumberland Overthrust Block in Virgnia and Tennessee. In: Ruppert, L. (Ed.), Coal and Petroleum Resources in the Appalachian Basin: Distribution, Geologic Framework, and Geochemical Character, US Geological Survey Professional Paper 1708, pp. 220-242.
14. Des Marais D.J., Donchin J.H., Nehring N.L., Truesdell A.H. Molecular carbon isotopic evidence for the origin of geothermal hydrocarbons. Nature 1981, 292:826-828.
15. Dresel P.E. The geochemistry of oilfield brines from western Pennsylvania 1985, M.S. disseration, Department of Geosciences, The Pennsylvanian State University, State College. PA 168 p.
16. Evans M.A., Battles D.A. Fluid inclusion and stable isotope analyses of veins from the central Appalachian Valley and Ridge Province; implications for regional synorogenic hydrologic structure and fluid migration. Geological Society of American Bulletin 1999, 111:1841-1860.
17. Gherardi F., Panichi C., Gonfiantini R., Magro G., Scandiffio G. Isotope systematics of C-bearing gas compounds in the geothermal fluids of Lardarello, Italy. Geothermics 2005, 35:442-470.
18. Giggenbach W.F. Redox processes governing the chemistry of fumarolic gas discharges from White Island, New Zealand. Applied Geochemistry 1987, 2:143-161.
19. Harrison M.J., Marshak S., Onasch C.M. Stratigraphic control of hot fluids on anthracitization, Lackawanna synclinorium, Pennsylvania. Tectonophysics 2004, 378:85-103.
20. Hatch J.R., Jacobson S.R., Witzke B.J., Rissatti J.B., Anders D.E., Watney W.L., Newell K.D., Vuletich A.K. Possible late Middle Ordovician organic carbon isotope excursion: evidence from Ordovician oil and hydrocarbon source rocks, mid-continent and east-central United States. American Association of Petroleum Geologists Bulletin 1987, 71:1342-1354.
21. Hayes, J.M., 2001. Fractionation of carbon and hydrogen isotopes in biosynthetic processes. In: Valley, J.W., Cole, D.R. (Eds.), Stable Isotope Geochemistry, Reviews in Mineralogy and Geochemistry 43, pp. 225-318.
22. Horibe Y., Craig H. D/H fractionation in the system methane-hydrogen-water. Geochimica et Cosmochimica Acta 1995, 59:5209-5217.
23. Huang H., Yang J., Yang Y., Du X. Geochemistry of natural gases in deep strata of the Songliao basin, NE China. International Journal of Coal Geology 2004, 58:231-244.
24. Hulston J.R., Hilton D.R., Kaplan I.R. Helium and carbon isotope systematics of natural gases from Taranaki Basin, New Zealand. Applied Geochemistry 2001, 16:419-436.
25. Hunt J.M. Petroleum Geochemistry and Geology 1996, W.H. Freeman and Company, New York, 743 p.
26. James A.T. Correlation of natural gas by use of carbon isotopic distribution between hydrocarbon components. American Association of Petroleum Geologists Bulletin 1983, 67:1176-1191.
27. James A.T., Burns B.J. Microbial alteration of subsurface natural gas accumulations. American Association of Petroleum Geologists Bulletin 1984, 68:957-960.
28. Jenden P.D., Drazan D.J., Kaplan I.R. Mixing of thermogenic natural gases in northern Appalachian basin. American Association of Petroleum Geologists Bulletin 1993, 77:980-998.
29. Kendall C., Caldwell E.A. Fundamentals of isotope geochemistry. Isotope Traces in Catchment Hydrology 1998, 51-86. Elsevier, New York. C. Kendall, J.J. McDonnell (Eds.).
30. 4-rich inclusions form quartz veins in the Valley-and-Ridge province and the anthracite fields of the Pennsylvania Appalachians. American Mineralogist 1991, 76:230-240.
31. Krouse H.R., Viau C.A., Eliuk A.L.S., Ueda S., Halas S. Chemical and isotopic evidence of thermochemical sulfate reduction by light hydrocarbon gases in deep carbonate reservoirs. Nature 1988, 333:415-419.
32. Laughrey C.D., Baldassare F.J. Geochemistry and origin of some natural gases in the Plateau province of the central Appalachian basin, Pennsylvania and Ohio. American Association of Petroleum Geologists Bulletin 1998, 82:317-335.
33. Laughrey, C.D., Harper, R.M., 1996. Upper Ordovician Bald Eagle Formation fractured anticlinal play. In: Roen, J.B., Walker, B.J. (Eds.), The atlas of major Appalachian gas plays, West Virginia Geological and Economic Survey Publication V-25, pp. 164-167.
34. Laughrey, C.D., Kostelnik, J., 2007. Geochemistry of natural gases from Trenton and Black River Formation (Middle Ordovician) Carbonate Reservoirs, Appalachian Basin. In: Patchen, D.G., Hickman, J.B., Harris, D.C., Drahovzal, J.A. (Eds.), Final Report: A Geologic Play Book for Trenton-Black River Appalachian Basin Exploration, US Department of Energy Award Number DE-FC26-03NT41856, Department of Energy/National Energy Technology Laboratories, pp. 161-210.
35. Lewan M.D. Experiments on the role of water in petroleum formation. Geochimica et Cosmochimica Acta 1997, 61:3671-3723.
36. Lorant F., Behar F. Late generation of methane from mature kerogens. Energy & Fuels 2002, 16(2):412-427.
37. Lorant F., Prinzhofer A., Behar F., Huc A.-Y. Carbon isotopic and molecular constraints on the formation and the expulsion of thermogenic hydrocarbon gases. Chemical Geology 1998, 147:249-264.
38. Mastalerz M., Schimmelmann A., Hower J.C., Lis G., Hatch J.R., Jacobson S.R. Chemical and isotopic properties of kukersites from Iowa and Estonia. Organic Geochemistry 2003, 34:1419-1427.
39. Mueller, E., Schulz, T., 2004. Application of geochemistry in the evaluation and development of deep Rotliegend dry gas reservoirs, NW Germany. In: Cubitt, J.M., England, W.A., Larter, S. (Eds.), Understanding Petroleum Reservoirs: Towards an Integrated Reservoir Engineering and Geochemical Approach, Special Publication 237. Geological Society of London, pp. 221-230.
40. O'Kane A., Onasch C.M., Farver J.R. The role of fluids in low temperature, fault-related deformation of quartz arenite. Journal of Structural Geology 2007, 29:819-836.
41. Onasch C.M., Dunne W.M., Cook J.E., O'Kane A. The effect of fluid composition on the behavior of well cemented, quartz-rich sandstone during faulting. Journal of Structural Geology 2009, 31:96-971.
42. O'Reilly C., Parnell J. Fluid flow and thermal histories for Cambrian-Ordovician platform deposits, New York: evidence from fluid inclusion studies. Geological Society of America Bulletin 1999, 111:1884-1896.
43. Pan C., Yu L., Fu J. Chemical and carbon isotopic fractionations of gaseous hydrocarbons during abiogenic oxidation. Earth and Planetary Science Letters 2006, 246:70-89.
44. Patchen, D.G., Hickman, J.B., Harris, D.C., Drahovzal, J.A., Lake, P.D., Smith, L.B., Nyahay, R., Schulze, R., Riley, R.A., Baranowski, M.T., Wickstrom, L.H., Laughrey, C.D., Kostelnik, J., Harper, R.M., Avary, K.L., Bocan, J., Hohn, M.E., McDowell, R., 2006. A geologic play book for Trenton-Black River Appalachian basin exploration, US Department of Energy, 632 p.
45. Prinzhofer A., Huc A.Y. Genetic and post-genetic molecular and isotopic fractionations in natural gases. Chemical Geology 1995, 126:281-290.
46. Proskurowski G., Lilley M.D., Seewald J.S., Fruh-Green G.L., Olson E.J., Lupton J.E., Sylva S.P., Kelley D.S. Abiogenic hydrocarbon production at Lost City hydrothermal field. Science 2008, 319:604-607.
47. Repetski, J.E., Ryder, R.T., Weary, D.J., Harris, A.G., Trippi, M.H., 2008. Thermal maturity patterns (CAI and %Ro) in upper Ordovician and Devonian rocks of the Appalachian basin: a major revision of USGS Map I-917-E using new subsurface collections. US Geological Survey Scientific Investigations Map 3006, 30 p.
48. Rooney M.A., Claypool G.E., Chung H.M. Modeling thermogenic gas generation using carbon isotope ratios of natural gas hydrocarbons. Chemical Geology 1995, 126:219-232.
49. Rowan, E.L., 2006. Burial and thermal history of the central Appalachian basin, based on three 2-D models of Ohio, Pennsylvania, and West Virginia. US Geological Survey Open File Report 2006-1019, 37 p.
50. Ryder R.T., Zagorski W.A. Nature, origin, and production characteristics of the Lower Silurian regional oil and gas accumulation, central Appalachian basin, United States. American Association of Petroleum Geologists Bulletin 2003, 87:847-872.
51. Ryder R.T., Burruss R.C., Hatch J.R. Black shale source rocks and oil generation in the Cambrian and Ordovician of the Central Appalachian Basin, USA. The American Association of Petroleum Geologists Bulletin 1998, 82:412-441.
52. Schimmelmann A., Sessions A.L., Mastalerz M. Hydrogen isotopic composition (D/H) of organic matter during diagenesis and thermal maturation. Annual Reviews of Earth and Planetary Science 2006, 34:501-533.
53. Schoell M. Genetic characterization of natural gases. American Association of Petroleum Geologists Bulletin 1983, 67:2225-2238.
54. Schumaker, R.C., 1996. Structural history of the Appalachian basin. In: Roen, J.B., Walker, B.J. (Eds.), The atlas of major Appalachian gas plays, West Virginia Geological and Economical Survey Publication V-25, pp. 8-21.
55. Seewald J.S., Zolotov M.Y., McCollom T. Experimental investigation of single carbon compounds under hydrothermal conditions. Geochimica et Cosmochimica Acta 2006, 70:446-460.
56. Sherwood Lollar B., Westgate T.D., Ward J.A., Slater G.F., Lacrampe-Couloume G. Abiogenic formation of alkanes in the Earth's crust as a minor source for global hydrocarbon reservoirs. Nature 2002, 416:522-524.
57. Sherwood Lollar B., Lacrampe-Couloume G., Slater G.F., Ward J.A., Moser D.P., Gihring T.M., Lin L.-H., Onstott T.C. Unraveling abiogenic and biogenic sources of methane in the earth's deep subsurface. Chemical Geology 2006, 226:328-339.
58. 4 and higher hydrocarbon gases from Precambrian Shield sites: a model for abiogenic polymerization of hydrocarbons. Geochimica et Cosmochimica Acta 2008, 72:4778-4795.
59. Swezey, C.S., 2002. Regional stratigraphy and petroleum systems of the Appalachian basin, North America. US Geological Survey Geologic Investigations Series Map I-2768.
60. Tang Y., Perry J.K., Jenden P.D., Schoell M. Mathematical modeling of stable carbon isotope ratios in natural gases. Geochimica et Cosmochimica Acta 2000, 64:2673-2687.