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Volumn 18, Issue 10, 2010, Pages 967-973

Deuterium labeling and mechanistic insights in the polymerization of propylene promoted by benzamidinate complexes

Author keywords

benzamidinate complexes; mechanistic insights; polypropylene

Indexed keywords

ACTIVE SPECIES; BENZAMIDINATE COMPLEXES; DEUTERIUM LABELING; DIALKYL COMPLEXES; ELASTIC MATERIALS; EPIMERIZATION; MECHANISTIC INSIGHTS;

EID: 78649566099     PISSN: 15985032     EISSN: 20927673     Source Type: Journal    
DOI: 10.1007/s13233-010-1013-z     Document Type: Article
Times cited : (7)

References (54)
  • 4
    • 39649083806 scopus 로고    scopus 로고
    • Bimetallic effects in homopolymerization of styrene and copolymerization of ethylene and styrenic comonomers: Scope, kinetics, and mechanism
    • DOI 10.1021/ja076407m
    • N. Guo C. L. Stern T. J. Marks 2008 J. Am. Chem. Soc. 130 2246 1:CAS:528:DC%2BD1cXhtVaitbs%3D 10.1021/ja076407m (Pubitemid 351288002)
    • (2008) Journal of the American Chemical Society , vol.130 , Issue.7 , pp. 2246-2261
    • Guo, N.1    Stern, C.L.2    Marks, T.J.3
  • 6
    • 29244488559 scopus 로고    scopus 로고
    • Ansa-metallocene polymerization catalysts: Effects of the bridges on the catalytic activities
    • DOI 10.1016/j.ccr.2005.05.012, PII S0010854505001359, Metallocene Complexes as Cata;ysts for Olefin Polymerazxation
    • B. Wang 2006 Coord. Chem. Rev. 250 242 1:CAS:528:DC%2BD2MXhtlCnt7bF 10.1016/j.ccr.2005.05.012 (Pubitemid 41819014)
    • (2006) Coordination Chemistry Reviews , vol.250 , Issue.1-2 , pp. 242-258
    • Wang, B.1
  • 7
    • 29144494083 scopus 로고    scopus 로고
    • Insights into group 4 and 5 ansa-bis(cyclopentadienyl) complexes with a single-atom bridge
    • DOI 10.1016/j.ccr.2005.05.017, PII S0010854505001384, Metallocene Complexes as Cata;ysts for Olefin Polymerazxation
    • S. Prashar A. Antinolo A. Otero 2006 Coord. Chem. Rev. 250 133 1:CAS:528:DC%2BD2MXhtlCnt7bO 10.1016/j.ccr.2005.05.017 (Pubitemid 41815555)
    • (2006) Coordination Chemistry Reviews , vol.250 , Issue.1-2 , pp. 133-154
    • Prashar, S.1    Antinolo, A.2    Otero, A.3
  • 8
    • 29144511091 scopus 로고    scopus 로고
    • Metallocene catalyzed ethene- and propene co-norbornene polymerization: Mechanisms from a detailed microstructural analysis
    • DOI 10.1016/j.ccr.2005.06.019, PII S0010854505001530, Metallocene Complexes as Cata;ysts for Olefin Polymerazxation
    • I. Tritto L. Boggioni D. R. Ferro 2006 Coord. Chem. Rev. 250 212 1:CAS:528:DC%2BD2MXhtlCnt7bE 10.1016/j.ccr.2005.06.019 (Pubitemid 41815559)
    • (2006) Coordination Chemistry Reviews , vol.250 , Issue.1-2 , pp. 212-241
    • Tritto, I.1    Boggioni, L.2    Ferro, D.R.3
  • 10
    • 4644338699 scopus 로고    scopus 로고
    • 1:CAS:528:DC%2BD2cXmtFert74%3D 10.1002/masy.200450911
    • W. Kaminsky P.-D. Tran R. Werner 2004 Macromol. Symp. 213 101 1:CAS:528:DC%2BD2cXmtFert74%3D 10.1002/masy.200450911
    • (2004) Macromol. Symp. , vol.213 , pp. 101
    • Kaminsky, W.1    Tran, P.-D.2    Werner, R.3
  • 15
  • 16
    • 29144493787 scopus 로고    scopus 로고
    • "Dual-side" catalysts for high and ultrahigh molecular weight homopolypropylene elastomers and plastomers
    • DOI 10.1016/j.ccr.2005.06.007, PII S0010854505001499, Metallocene Complexes as Cata;ysts for Olefin Polymerazxation
    • C. Cobzaru S. Hild A. Boger C. Troll B. Rieger 2006 Coord. Chem. Rev. 250 189 1:CAS:528:DC%2BD2MXhtlCnt7bK 10.1016/j.ccr.2005.06.007 (Pubitemid 41815558)
    • (2006) Coordination Chemistry Reviews , vol.250 , Issue.1-2 , pp. 189-211
    • Cobzaru, C.1    Hild, S.2    Boger, A.3    Troll, C.4    Rieger, B.5
  • 17
    • 41849116745 scopus 로고    scopus 로고
    • Fluorinated bis(phenoxyketimine)titanium complexes for the living, isoselective polymerization of propylene: Multiblock isotactic polypropylene copolymers via sequential monomer addition
    • DOI 10.1021/ja077772g
    • J. B. Edson Z. Wang E. J. Kramer G. W. Coates 2008 J. Amer. Chem. Soc. 130 4968 1:CAS:528:DC%2BD1cXjsVGmsrY%3D 10.1021/ja077772g (Pubitemid 351500130)
    • (2008) Journal of the American Chemical Society , vol.130 , Issue.14 , pp. 4968-4977
    • Edson, J.B.1    Wang, Z.2    Kramer, E.J.3    Coates, G.W.4
  • 18
    • 0037007888 scopus 로고    scopus 로고
    • Catalysts for the living insertion polymerization of alkenes: Access to new polyolefin architectures using Ziegler-Natta chemistry
    • DOI 10.1002/1521-3773(20020703)41:13<2236::AID-ANIE2236>3.0.CO;2-3
    • G. W. Coates P. D. Hustad S. Reinartz 2002 Angew. Chem., Int. Ed. 41 2236 1:CAS:528:DC%2BD38XlsVyqsrk%3D 10.1002/1521-3773(20020703)41:13<2236::AID- ANIE2236>3.0.CO;2-3 (Pubitemid 34778537)
    • (2002) Angewandte Chemie - International Edition , vol.41 , Issue.13 , pp. 2236-2257
    • Coates, G.W.1    Hustad, P.D.2    Reinartz, S.3
  • 19
    • 22744439252 scopus 로고    scopus 로고
    • Living Ziegler-Natta polymerizations: True or false?
    • DOI 10.1002/masy.200550801
    • V. Busico G. Talarico R. Cipullo 2005 Macromol. Symp. 226 1 1:CAS:528:DC%2BD2MXmvVehtr4%3D 10.1002/masy.200550801 (Pubitemid 41028225)
    • (2005) Macromolecular Symposia , vol.226 , pp. 1-16
    • Busico, V.1    Talarico, G.2    Cipullo, R.3
  • 20
    • 33746305578 scopus 로고    scopus 로고
    • Discrete, multiblock isotactic-atactic stereoblock polypropene microstructures of differing block architectures through programmable stereomodulated living Ziegler-Natta polymerization
    • DOI 10.1002/anie.200600027
    • M. B. Harney Y. Zhang L. R. Sita 2006 Angew. Chem., Int. Ed. 45 2400 1:CAS:528:DC%2BD28XjvVCrsbg%3D 10.1002/anie.200600027 (Pubitemid 44105118)
    • (2006) Angewandte Chemie - International Edition , vol.45 , Issue.15 , pp. 2400-2404
    • Harney, M.B.1    Zhang, Y.2    Sita, L.R.3
  • 21
    • 33749002588 scopus 로고    scopus 로고
    • Bimolecular control over polypropene stereochemical microstructure in a well-defined two-state system and a new fundamental form: Stereogradient polypropene
    • DOI 10.1002/anie.200601616
    • M. B. Harney Y. Zhang L. R. Sita 2006 Angew. Chem., Int. Ed. 45 6140 1:CAS:528:DC%2BD28XhtVWju7jN 10.1002/anie.200601616 (Pubitemid 44453058)
    • (2006) Angewandte Chemie - International Edition , vol.45 , Issue.37 , pp. 6140-6144
    • Harney, M.B.1    Zhang, Y.2    Sita, L.R.3
  • 22
    • 0029219187 scopus 로고
    • 1:CAS:528:DyaK2MXjt1ensLo%3D 10.1126/science.267.5195.217
    • G. W. Coates R. M. Waymouth 1995 Science 267 217 1:CAS:528: DyaK2MXjt1ensLo%3D 10.1126/science.267.5195.217
    • (1995) Science , vol.267 , pp. 217
    • Coates, G.W.1    Waymouth, R.M.2
  • 23
    • 0036736762 scopus 로고    scopus 로고
    • 1:CAS:528:DC%2BD38XktlChtLs%3D 10.1021/ar010081j
    • S. Lin R. M. Waymouth 2002 Acc. Chem. Res. 35 765 1:CAS:528: DC%2BD38XktlChtLs%3D 10.1021/ar010081j
    • (2002) Acc. Chem. Res. , vol.35 , pp. 765
    • Lin, S.1    Waymouth, R.M.2
  • 26
    • 0033608107 scopus 로고    scopus 로고
    • 1- symmetric zirconocene catalysts for propylene polymerization. Synthesis and molecular structure of a dilithio double silylene-bridged bis(cyclopentadienyl) complex and the corresponding zirconium dichloride complex
    • DOI 10.1021/ja982868j
    • D. Veghini L. M. Henling T. J. Brookhart J. E. Bercaw 1999 J. Am. Chem. Soc. 121 564 1:CAS:528:DyaK1MXjsFyg 10.1021/ja982868j (Pubitemid 29070482)
    • (1999) Journal of the American Chemical Society , vol.121 , Issue.3 , pp. 564-573
    • Veghini, D.1    Henling, L.M.2    Burkhardt, T.J.3    Bercaw, J.E.4
  • 27
    • 0035497160 scopus 로고    scopus 로고
    • Ancillary ligand and olefin substituent effects on olefin dissociation for cationic zirconocene complexes bearing a coordinated pendant olefin
    • DOI 10.1021/om010363n
    • C. G. Brandow A. Mendiratta J. E. Bercaw 2001 Organometallics 20 4253 1:CAS:528:DC%2BD3MXmsVyrtb8%3D 10.1021/om010363n (Pubitemid 35348949)
    • (2001) Organometallics , vol.20 , Issue.20 , pp. 4253-4261
    • Brandow, C.G.1    Mendiratta, A.2    Bercaw, J.E.3
  • 28
    • 0013440761 scopus 로고    scopus 로고
    • 1:CAS:528:DC%2BD38XptVKltQ%3D%3D 10.1021/om010788+
    • S. A. Miller J. E. Bercaw 2002 Organometallics 21 934 1:CAS:528:DC%2BD38XptVKltQ%3D%3D 10.1021/om010788+
    • (2002) Organometallics , vol.21 , pp. 934
    • Miller, S.A.1    Bercaw, J.E.2
  • 29
    • 1842738507 scopus 로고    scopus 로고
    • Marked Counteranion Effects on Single-Site Olefin Polymerization Processes. Correlations of Ion Pair Structure and Dynamics with Polymerization Activity, Chain Transfer, and Syndioselectivity
    • DOI 10.1021/ja036288k
    • M. C. Chen J. A. S. Roberts T. J. Marks 2004 J. Am. Chem. Soc. 126 4605 1:CAS:528:DC%2BD2cXitV2qtr0%3D 10.1021/ja036288k (Pubitemid 38469108)
    • (2004) Journal of the American Chemical Society , vol.126 , Issue.14 , pp. 4605-4625
    • Chen, M.-C.1    Roberts, J.A.S.2    Marks, T.J.3
  • 30
    • 0037036815 scopus 로고    scopus 로고
    • Direct observation of the structural isomerization of a cationic group 4 Ziegler-Natta insertion product
    • DOI 10.1021/ja026820o
    • R. J. Keaton L. R. Sita 2002 J. Am. Chem. Soc. 124 9070 1:CAS:528:DC%2BD38XltlWksb8%3D 10.1021/ja026820o (Pubitemid 34847666)
    • (2002) Journal of the American Chemical Society , vol.124 , Issue.31 , pp. 9070-9071
    • Keaton, R.J.1    Sita, L.R.2
  • 32
    • 3242817616 scopus 로고
    • 1:CAS:528:DyaK2cXmtVKju7s%3D 10.1021/ja00099a060
    • V. Busico R. Cipullo 1994 J. Am. Chem. Soc. 116 9329 1:CAS:528: DyaK2cXmtVKju7s%3D 10.1021/ja00099a060
    • (1994) J. Am. Chem. Soc. , vol.116 , pp. 9329
    • Busico, V.1    Cipullo, R.2
  • 34
    • 0037080579 scopus 로고    scopus 로고
    • 2-symmetric ansa-metallocenes and the "trigger" hypothesis
    • DOI 10.1021/ma011401h
    • V. Busico R. Cipullo F. Cutillo M. Vacatello 2002 Macromolecules 35 349 1:CAS:528:DC%2BD3MXovFelsbc%3D 10.1021/ma011401h (Pubitemid 34097177)
    • (2002) Macromolecules , vol.35 , Issue.2 , pp. 349-354
    • Busico, V.1    Cipullo, R.2    Cutillo, F.3    Vacatello, M.4
  • 35
    • 0033589290 scopus 로고    scopus 로고
    • 1:CAS:528:DyaK1MXns1SntLk%3D 10.1016/S1381-1169(99)00101-6
    • L. Resconi 1999 J. Mol. Catal. A: Chem. 146 167 1:CAS:528: DyaK1MXns1SntLk%3D 10.1016/S1381-1169(99)00101-6
    • (1999) J. Mol. Catal. A: Chem. , vol.146 , pp. 167
    • Resconi, L.1
  • 36
    • 0035858973 scopus 로고    scopus 로고
    • 2/MAO catalyst. 2. Combined DFT/MM analysis of chain propagation and chain release reactions
    • DOI 10.1021/om000680e
    • G. Moscardi L. Resconi L. Cavallo 2001 Organometallics 20 1918 1:CAS:528:DC%2BD3MXisFemu7s%3D 10.1021/om000680e (Pubitemid 35344288)
    • (2001) Organometallics , vol.20 , Issue.10 , pp. 1918-1931
    • Moscardi, G.1    Resconi, L.2    Cavallo, L.3
  • 38
    • 0030472690 scopus 로고    scopus 로고
    • New NMR spectroscopic probe of the absolute stereoselectivity for metal-hydride and metal-alkyl additions to the carbon-carbon double bond. Demonstration with a single-component, isospecific Ziegler-Natta α-olefin polymerization catalyst
    • DOI 10.1021/ja962869g, PII S0002786396028697
    • J. H. Gilchrist J. E. Bercaw 1996 J. Amer. Chem. Soc. 118 12021 1:CAS:528:DyaK28Xmsl2hsb0%3D 10.1021/ja962869g (Pubitemid 27006548)
    • (1996) Journal of the American Chemical Society , vol.118 , Issue.48 , pp. 12021-12028
    • Gilchrist, J.H.1    Bercaw, J.E.2
  • 39
    • 0029639069 scopus 로고
    • 1:CAS:528:DyaK2MXjtlOnsLs%3D 10.1021/ja00110a027
    • M. K. Leclerc H.- H. Brintzinger 1995 J. Am. Chem. Soc. 117 1651 1:CAS:528:DyaK2MXjtlOnsLs%3D 10.1021/ja00110a027
    • (1995) J. Am. Chem. Soc. , vol.117 , pp. 1651
    • Leclerc, M.K.1    Brintzinger - H, H.2
  • 40
    • 0037139611 scopus 로고    scopus 로고
    • Chain epimerization during propylene polymerization with metallocene catalysts: Mechanistic studies using a doubly labeled propylene
    • DOI 10.1021/ja0123296
    • J. C. Yoder J. E. Bercaw 2002 J. Am. Chem. Soc. 124 2548 1:CAS:528:DC%2BD38XhtlCmu7k%3D 10.1021/ja0123296 (Pubitemid 34251768)
    • (2002) Journal of the American Chemical Society , vol.124 , Issue.11 , pp. 2548-2555
    • Yoder, J.C.1    Bercaw, J.E.2
  • 42
    • 33947583909 scopus 로고    scopus 로고
    • Reactivity of group 4 benzamidinate complexes towards mono- and bis-substituted silanes and 1,5-hexadiene
    • DOI 10.1016/j.jorganchem.2007.01.002, PII S0022328X07000320
    • V. Volkis C. Averbuj M. S. Eisen 2007 J. Organomet. Chem. 692 1940 1:CAS:528:DC%2BD2sXjvValtrw%3D 10.1016/j.jorganchem.2007.01.002 (Pubitemid 46483505)
    • (2007) Journal of Organometallic Chemistry , vol.692 , Issue.10 , pp. 1940-1950
    • Volkis, V.1    Averbuj, C.2    Eisen, M.S.3
  • 44
    • 33750302921 scopus 로고    scopus 로고
    • Stereoerror formation in the polymerization of propylene catalyzed by a titanium bis(benzamidinate) dichloride complex activated by MAO
    • DOI 10.1021/om060611l
    • V. Volkis M. Rodensky A. Lisovskii Y. Balazs M. S. Eisen 2006 Organometallics 25 4934 1:CAS:528:DC%2BD28Xptlektbw%3D 10.1021/om060611l (Pubitemid 44629306)
    • (2006) Organometallics , vol.25 , Issue.21 , pp. 4934-4937
    • Volkis, V.1    Rodensky, M.2    Lisovskii, A.3    Balazs, Y.4    Eisen, M.S.5
  • 45
    • 33745764176 scopus 로고    scopus 로고
    • Unusual synergetic effect of cocatalysts in the polymerization of propylene by a zirconium bis(benzamidinate) dimethyl complex
    • DOI 10.1021/om0602815
    • V. Volkis B. Tumanskii M. S. Eisen 2006 Organometallics 25 2722 1:CAS:528:DC%2BD28XjslKgtL8%3D 10.1021/om0602815 (Pubitemid 44013541)
    • (2006) Organometallics , vol.25 , Issue.11 , pp. 2722-2724
    • Volkis, V.1    Tumanskii, B.2    Eisen, M.S.3
  • 49
    • 0037080579 scopus 로고    scopus 로고
    • 2-symmetric ansa-metallocenes and the "trigger" hypothesis
    • DOI 10.1021/ma011401h
    • V. Busico R. Cipullo F. Cutillo M. Vacatello 2002 Macromolecules 35 349 1:CAS:528:DC%2BD3MXovFelsbc%3D 10.1021/ma011401h (Pubitemid 34097177)
    • (2002) Macromolecules , vol.35 , Issue.2 , pp. 349-354
    • Busico, V.1    Cipullo, R.2    Cutillo, F.3    Vacatello, M.4
  • 51
    • 0033589290 scopus 로고    scopus 로고
    • 1:CAS:528:DyaK1MXns1SntLk%3D 10.1016/S1381-1169(99)00101-6
    • L. Resconi 1999 J. Mol. Catal. A: Chem. 146 167 1:CAS:528: DyaK1MXns1SntLk%3D 10.1016/S1381-1169(99)00101-6
    • (1999) J. Mol. Catal. A: Chem. , vol.146 , pp. 167
    • Resconi, L.1
  • 52
    • 0037139611 scopus 로고    scopus 로고
    • Chain epimerization during propylene polymerization with metallocene catalysts: Mechanistic studies using a doubly labeled propylene
    • DOI 10.1021/ja0123296
    • J. C. Yoder J. E. Bercaw 2002 J. Am. Chem. Soc. 124 2548 1:CAS:528:DC%2BD38XhtlCmu7k%3D 10.1021/ja0123296 (Pubitemid 34251768)
    • (2002) Journal of the American Chemical Society , vol.124 , Issue.11 , pp. 2548-2555
    • Yoder, J.C.1    Bercaw, J.E.2
  • 54
    • 0003258684 scopus 로고    scopus 로고
    • 1:CAS:528:DyaK28Xnt1KqtLs%3D 10.1016/S0020-1693(96)05317-0
    • J. M. Brown G. D. Hughes 1996 Inorg. Chim. Acta 252 229 1:CAS:528:DyaK28Xnt1KqtLs%3D 10.1016/S0020-1693(96)05317-0
    • (1996) Inorg. Chim. Acta , vol.252 , pp. 229
    • Brown, J.M.1    Hughes, G.D.2


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