Living Ziegler-Natta polymerizations: True or false?

Macromolecular Symposia

Volumn 226, Issue , 2005, Pages 1-16

  Busico, Vincenzo ^a   Talarico, Giovanni ^a   Cipullo, Roberta ^a  

^a UNIVERSITY OF NAPLES FEDERICO II   (Italy)

Author keywords

Controlled; Living; Polypropylene; Ziegler Natta polymerization

Indexed keywords

CATALYSTS; MONOMERS; POLYOLEFINS; POLYPROPYLENES; SYNTHESIS (CHEMICAL); TRANSITION METALS;

CONTROLLED; LIVING; POLYINSERTION; ZIEGLER-NATTA POLYMERIZATION;

POLYMERIZATION;

EID: 22744439252     PISSN: 10221360     EISSN: None     Source Type: Journal    
DOI: 10.1002/masy.200550801     Document Type: Conference Paper

References (38)

1. Leading reference: G. W. Coates, P.D. Hustad, S. Reinartz, Angew. Chem. Int. Ed 2002, 41, 2236.
2. A.D. Jenkins, P. Kratochvil, R.F.T. Stepto, U.W. Suter, Pure Appl. Chem. 1996, 68, 2287.
3. K. Matyjaszewski, A.H.E. Mueller, Am. Chem. Soc., Macromolecular Nomenclature Note No. 12; http://www.polyacs.org/main/nomenclature.shtml.
4. (a) H. Mori, M. Terano, Trends Polym. Sci. 1997, 5, 314.
5. (b) V. Busico, R. Cipullo, V. Esposito, Macromol. Rapid Commun. 1999, 20, 116.
6. (c) F. Song, R.D. Cannon, M. Bochmann, J. Am. Chem. Soc. 2003, 125, 7641.
7. Leading reference: H. Makio, N. Kashiwa, T. Fujita, Adv. Synth. Catal. 2002, 344, 1.
8. J. Tian, P.D. Hustad, G.W. Coates, J. Am. Chem. Soc. 2001, 123, 5134.
9. M. Mitani, T. Nakano, T. Fujita, Chem. Eur. J. 2003, 9, 2396, and references therein.
10. S. Reinartz, A.F. Mason, E.B. Lobkovsky, G.W. Coates, Organometallics 2003, 22, 2542.
11. G. Milano, L. Cavallo, G. Guerra, J. Am. Chem. Soc. 2002, 124, 13368.
12. E.T. Tshuva, I. Goldberg, M. Kol, J. Am. Chem. Soc. 2000, 122, 10706.
13. V. Busico, R. Cipullo, N. Friederichs, S. Ronca, M. Togrou, Macromolecules 2003, 36, 3806.
14. V. Busico, R. Cipullo, N. Friederichs, S. Ronca, G. Talarico, M. Togrou, B. Wang, Macromolecules 2004, 37, 8201.
15. S.C.F. Kui, N. Zhu, M.C.W. Chan, Angew. Chem. Int. Ed. 2003, 42, 1628.
16. G. Talarico, V. Busico, L. Cavallo, Organometallics 2004, 23, 5989.
17. L. Resconi, L. Cavallo, A. Fait, F. Piemontesi, Chem. Rev. 2000, 100, 1253.
18. (a) M. Borrelli, V. Busico, R. Cipullo, S. Ronca, P.H.M. Budzelaar, Macromolecules 2003, 36, 8171.
19. (b) M. Borrelli, V. Busico, R. Cipullo, S. Ronca, P.H.M. Budzelaar, Macromolecules 2002, 35, 2835.
20. G. Talarico, V. Busico, L. Cavallo, J. Am. Chem. Soc. 2003, 125, 7172.
21. K. Vanka, Z. Xu, T. Ziegler, Can. J. Chem. 2003, 81, 1413.
22. K. Vanka, Z. Xu, T. Ziegler, Organometallics 2004, 23, 2900.
23. M. Lamberti, D. Pappalardo, A. Zambelli, C. Pellecchia, Macromolecules 2002, 35, 658.
24. P.D. Hustad, J. Tian, G.W. Coates, J. Am. Chem. Soc. 2002, 124, 3614.
25. H. Makio, Y. Tohi, J. Saito, M. Onda, T. Fujita, Macromol. Rapid Commun. 2003, 24, 894.
26. T-P value.
27. This effect is related in part to the higher strength of the Zr-H bond compared to the Ti-H bond.
28. A.F. Mason, J. Tian, P.D. Hustad, E.B. Lobkovsky, G.W. Coates, Isr. J. Chem. 2002, 42, 301.
29. 2/MAO (see: R. Furuyama, J. Saito, S.-i. Ishii, M. Mitani, S. Matsui, Y. Tohi, H. Makio, N. Matsukawa, H. Tanaka, T. Fujita, J. Mol. Cat. A: Chemical 2003, 200, 31), probably due to the high steric congestion at the metal center.
30. A.E. Reed, L.A. Curtiss, F. Weinhold, Chem. Rev. 1988, 88, 899.
31. L. Deng, T.K. Woo, L. Cavallo, P. Margl, T. Ziegler, J. Am. Chem. Soc. 1997, 119, 6177.
32. P. Margl, L. Deng, T. Ziegler, J. Am. Chem. Soc. 1999, 121, 154.
33. U. Stehling, J. Diebold, R. Kirsten, W. Roell, H.H. Brintzinger, S. Juengling, R. Muelhaupt, F. Langhauser, Organometallics 1994, 13, 964.
34. S.D. Ittel, L.K. Johnson, M. Brookhart, Chem. Rev. 2000, 100, 1169.
35. V. Busico, R. Cipullo, S. Ronca, P.H.M. Budzelaar, Macromol. Rapid Commun. 2001, 22, 1405.
36. V. Busico, R. Cipullo, F. Cutillo, N. Friederichs, S. Ronca, B. Wang, J. Am. Chem. Soc. 2003, 125, 12402.
37. V. Busico, R. Cipullo, Progr. Polym. Sci. 2001, 26, 443.
38. -1.