Supramolecular balance: Using cooperativity to amplify weak interactions

Journal of the American Chemical Society

Volumn 132, Issue 47, 2010, Pages 16818-16824

  Roman, Mihaela ^a   Cannizzo, Caroline ^b   Pinault, Thomas ^b   Isare, Benjamin ^b   Andrioletti, Bruno ^a   Van Der Schoot, Paul ^c,d   Bouteiller, Laurent ^b  

^a UNIVERSITÉ LYON 1   (France)

^b SORBONNE UNIVERSITÉ   (France)

^c EINDHOVEN UNIVERSITY OF TECHNOLOGY   (Netherlands)

^d UTRECHT UNIVERSITY   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMISTRY; SYNTHESIS (CHEMICAL);

CONFIGURATIONAL TRANSITIONS; EXPERIMENTAL APPROACHES; HIGHLY COOPERATIVES; MOLECULAR BUILDING BLOCKS; SCIENTIFIC FIELDS; STERIC REPULSIONS; SUPRAMOLECULAR INTERACTIONS; WEAK INTERACTIONS;

SUPRAMOLECULAR CHEMISTRY;

ALKYL GROUP; UREA; VINYL DERIVATIVE;

ARTICLE; CHEMICAL MODIFICATION; MOLECULAR INTERACTION; SOLUTION AND SOLUBILITY; SOLVATION; STEREOCHEMISTRY; SUPRAMOLECULAR CHEMISTRY; THERMOGRAPHY;

EID: 78649499913     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja105717u     Document Type: Article

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45. We could also envisage that the transition is affected by a change of conformation of the alkyl chains. (20) However, FTIR spectroscopy shows that the proportion of gauche conformations is not affected by the tube to filament transition, whatever the chain length of the bisurea (see Figure S4 in the Supporting Information).
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49. We count as alkyl groups all the methylene and methyl groups coming either from the alkyl or from the alkylene side chains.
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