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Volumn 50, Issue 47, 2009, Pages 6601-6605

Remarkable enhancement of aerobic epoxidation reactivity for olefins catalyzed by μ-oxo-bisiron(III) porphyrins under ambient conditions

Author keywords

Dioxygen; Epoxidation; Olefins; Oxo dimeric iron(III) porphyrins

Indexed keywords

ALDEHYDE; ALKENE DERIVATIVE; CYCLOHEXENE DERIVATIVE; ISOBUTYLALDEHYDE; METALLOPORPHYRIN; MU OXO DIMERIC IRON PORPHYRIN; OXYGEN; UNCLASSIFIED DRUG;

EID: 78249289988     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2009.09.061     Document Type: Article
Times cited : (54)

References (66)
  • 50
    • 85031272785 scopus 로고    scopus 로고
    • note
    • -1.
  • 51
    • 85031242501 scopus 로고    scopus 로고
    • note
    • -9 mmol) and naphthalene (0.8 mmol, inert internal standard) at room temperature. The consumption of the starting olefins and formation of oxidized products were monitored by GC (Shimadzu GC-14C) and GC-MS (Shimadzu GCMS-QP2010 plus).
  • 58
    • 85031251830 scopus 로고    scopus 로고
    • note
    • -9 mmol) were added to 60 mL dichloromethane in the presence of molecular oxygen at room temperature while stirring. The crude products were purified via column chromatography (silica geland cyclohexane as eluting agents). After removing the solvent under reduced pressure, the pure cyclohexene oxide was obtained with the yield of 87%.
  • 59
    • 85031240593 scopus 로고    scopus 로고
    • TOF is commonly used to express the catalytic efficiency of the catalyst with the definition as converted substrate (mol) per catalyst (mol) per minute
    • TOF is commonly used to express the catalytic efficiency of the catalyst with the definition as converted substrate (mol) per catalyst (mol) per minute.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.