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78149323889
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Np-NC(H)Ph is characterized by a well-resolved, diagnostic aldehydic-type proton resonance centered at δ 9.57 ppm, which is observed to decay over time
-
Np-NC(H)Ph is characterized by a well-resolved, diagnostic aldehydic-type proton resonance centered at δ 9.57 ppm, which is observed to decay over time.
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92
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78149326191
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2, where the amino-methyl groups appear as distinct singlets at room temperature, thus indicating hindered rotation
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2, where the amino-methyl groups appear as distinct singlets at room temperature, thus indicating hindered rotation.
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0011393323
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For a proposed nucleophilic attack on an incipient formyl ligand, see
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For a proposed nucleophilic attack on an incipient formyl ligand, see: Fryzuk, M. D.; Mylvaganam, M.; Zaworotko, M. J.; MacGillivray, L. R. Organometallics 1996, 15, 1134-1138
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111
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78149329235
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nitrile bond
-
nitrile bond.
-
-
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112
-
-
78149348569
-
-
2Ad-H as induced by the pendent 1-Ad substituents
-
2Ad-H as induced by the pendent 1-Ad substituents.
-
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113
-
-
78149302257
-
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Np-H. See ref 29
-
Np-H. See ref 29.
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-
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114
-
-
78149310854
-
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1H NMR time scale
-
1H NMR time scale.
-
-
-
-
115
-
-
78149328473
-
-
2Ph. For details, see the Supporting Information
-
2Ph. For details, see the Supporting Information.
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117
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0000239406
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Kubas, G. J.; Wasserman, H. J.; Ryan, R. R. Organometallics 1985, 4, 2012-2021
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6844239208
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Such a negative reduction potential is within the range attainable by strong chemical reductants; see
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Such a negative reduction potential is within the range attainable by strong chemical reductants; see: Connelly, N. G.; Geiger, W. E. Chem. Rev. 1996, 96, 877-910
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78149326907
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Np-H.
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127
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78149320327
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Fickes, M.G.1
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