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Volumn 29, Issue 21, 2010, Pages 5215-5229

Niobaziridine hydrides

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EID: 78149314235     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om100522p     Document Type: Article
Times cited : (28)

References (127)
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    • Experimental details are provided in the Supporting Information
    • Experimental details are provided in the Supporting Information.
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    • 11 (30.0 ± 1.0)., 67 th ed.; CRC Press: Boca Raton, FL
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    • (1987) CRC Handbook of Chemistry and Physics
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    • 6), thereby ruling out a complicated, Nb-mediated exchange process between all C-H bonds of the N[Np]Ar ligand framework
    • 6), thereby ruling out a complicated, Nb-mediated exchange process between all C-H bonds of the N[Np]Ar ligand framework.
  • 74
    • 33845281614 scopus 로고
    • Typically the reverse reaction, namely, transfer of a terminal oxo moiety to phosphine, is encountered; see
    • Typically the reverse reaction, namely, transfer of a terminal oxo moiety to phosphine, is encountered; see: Holm, R. H. Chem. Rev. 1987, 87, 1401-1449
    • (1987) Chem. Rev. , vol.87 , pp. 1401-1449
    • Holm, R.H.1
  • 79
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    • For examples of organonitrile insertion into early transition metal and lanthanide hydrides, see
    • For examples of organonitrile insertion into early transition metal and lanthanide hydrides, see: Churchill, M. R.; Wasserman, H. J.; Belmonte, P. A.; Schrock, R. R. Organometallics 1982, 1, 559-561
    • (1982) Organometallics , vol.1 , pp. 559-561
    • Churchill, M.R.1    Wasserman, H.J.2    Belmonte, P.A.3    Schrock, R.R.4
  • 82
    • 0000613295 scopus 로고
    • 2 into early transition metal hydride complexes has been reported previously; see
    • 2 into early transition metal hydride complexes has been reported previously; see: Gambarotta, S.; Floriani, C.; Chiesi-Villa, A.; Guastini, C. Inorg. Chem. 1983, 22, 2029-2034
    • (1983) Inorg. Chem. , vol.22 , pp. 2029-2034
    • Gambarotta, S.1    Floriani, C.2    Chiesi-Villa, A.3    Guastini, C.4
  • 91
    • 78149323889 scopus 로고    scopus 로고
    • Np-NC(H)Ph is characterized by a well-resolved, diagnostic aldehydic-type proton resonance centered at δ 9.57 ppm, which is observed to decay over time
    • Np-NC(H)Ph is characterized by a well-resolved, diagnostic aldehydic-type proton resonance centered at δ 9.57 ppm, which is observed to decay over time.
  • 92
    • 78149326191 scopus 로고    scopus 로고
    • 2, where the amino-methyl groups appear as distinct singlets at room temperature, thus indicating hindered rotation
    • 2, where the amino-methyl groups appear as distinct singlets at room temperature, thus indicating hindered rotation.
  • 111
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    • nitrile bond
    • nitrile bond.
  • 112
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    • 2Ad-H as induced by the pendent 1-Ad substituents
    • 2Ad-H as induced by the pendent 1-Ad substituents.
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    • Np-H. See ref 29
    • Np-H. See ref 29.
  • 114
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    • 1H NMR time scale
    • 1H NMR time scale.
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    • 2Ph. For details, see the Supporting Information
    • 2Ph. For details, see the Supporting Information.
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    • Such a negative reduction potential is within the range attainable by strong chemical reductants; see
    • Such a negative reduction potential is within the range attainable by strong chemical reductants; see: Connelly, N. G.; Geiger, W. E. Chem. Rev. 1996, 96, 877-910
    • (1996) Chem. Rev. , vol.96 , pp. 877-910
    • Connelly, N.G.1    Geiger, W.E.2
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    • Np-H
    • Np-H.
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    • Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA
    • Fickes, M. G. Ph.D. Thesis, Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA, 1998.
    • (1998) Ph.D. Thesis
    • Fickes, M.G.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.