Two metal-monocarbollide relatives of the {B20H18} double-cluster boranes

Organometallics

Volumn 29, Issue 21, 2010, Pages 4790-4792

  Franken, Andreas ^a   McGrath, Thomas D ^a   Stone, F Gordon A ^a  

^a BAYLOR UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 78149291010     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om100471n     Document Type: Article

References (42)

1. The chemistry of silicon involving probable use of d-type orbitals. Stone, F. G. A.; Seyferth, D. J. Inorg. Nucl. Chem. 1955, 1, 112
2. For example: Masalles, C.; Llop, J.; Viñas, C.; Teixidor, F. Adv. Mater. 2002, 14, 826
3. Gentil, S.; Crespo, E.; Rojo, I.; Friang, A.; Viñas, C.; Teixidor, F.; Grüner, B.; Gabel, D. Polymer 2005, 46, 12218
4. Kawasaki, Y.; Kuroi, T.; Yamashita, T.; Horita, K.; Hayashi, T.; Ishibashi, M.; Togawa, M.; Ohno, Y.; Yoneda, M.; Horsky, T.; Jacobson, D.; Krull, W. Nucl. Instrum. Methods Phys. Res., Sect. B 2005, 237, 25
5. Mola, J.; Mas-Marza, E.; Sala, X.; Romero, I.; Rodríguez, M.; Viñas, C.; Parella, T.; Llobet, A. Angew. Chem., Int. Ed. 2008, 47, 5830
6. Nieuwenhuyzen, M.; Seddon, K. R.; Teixidor, F.; Puga, A. V.; Viñas, C. Inorg. Chem. 2009, 48, 889
7. Stoica, A.-I.; Viñas, C.; Teixidor, F. Chem. Commun. 2009, 4988
8. González-Cardoso, P.; Stoica, A.-I.; Farràs, P.; Pepiol, A.; Viñas, C.; Teixidor, F. Chem.-Eur. J. 2010, 16, 6660
9. Examples include: El-Zaria, M. E.; Dörfler, U.; Gabel, D. J. Med. Chem. 2002, 45, 5817
10. Valliant, J. F.; Guenther, K. J.; King, A. S.; Morel, P.; Schaffer, P.; Sogbein, O. O.; Stephenson, K. A. Coord. Chem. Rev. 2002, 232, 173
11. Cígler, P.; Kožíšek, M.; Řezá čová, P.; Brynda, J.; Otwinowski, Z.; Pokorná, J.; Plešek, J.; Grüner, B.; Dolečková- Marešová, L.; Máša, M.; Sedláček, J.; Bodem, J.; Kräusslich, H.; Král, V.; Konvalinka, J. Proc. Natl. Acad. Sci. U. S. A. 2005, 102, 15394
12. Hawthorne, M. F. Angew. Chem., Int. Ed. Engl. 1993, 32, 950
13. Hawthorne, M. F. Chem. Eng. News 2009, 87, 16
14. Hawthorne, M. F.; Shelly, K.; Li, F. Chem. Commun. 2002, 547, and references therein.
15. For example: Kiani, F. A.; Hofmann, M. Dalton Trans. 2007, 1207
16. Shameema, O.; Jemmis, E. D. Chem. Asian J. 2009, 4, 1346
17. Examples include: Bould, J.; Kennedy, J. D.; Barton, L.; Rath, N. P. Chem. Commun. 1997, 2405
18. Hosmane, N. S.; Franken, A.; Zhang, G.; Srivastava, R. R.; Smith, R. Y.; Spielvogel, B. F. Main Group Met. Chem. 1998, 21, 319
19. Shea, S. L.; Jelínek, T.; Perera, S. D.; Štíbr, B.; Thornton-Pett, M.; Kennedy, J. D. Dalton Trans. 2004, 1521
20. Carr, M. J.; Perera, S. D.; Jelínek, T.; Štíbr, B.; Clegg, W.; Kilner, C. A.; Kennedy, J. D. Chem. Commun. 2007, 3559
21. Londesborough, M. G. S.; Bould, J.; Baše, T.; Hnyk, D.; Bakardjiev, M.; Holub, J.; Císařová, I.; Kennedy, J. D. Inorg. Chem. 2010, 49, 4092
22. Janoušek, Z.; Štíbr, B.; Fontaine, X. L. R.; Kennedy, J. D.; Thornton-Pett, M. J. Chem. Soc., Dalton Trans. 1996, 3813
23. Brellochs, B. In Contemporary Boron Chemistry; Davidson, M. G.; Hughes, A. K.; Marder, T. B.; Wade, K., Eds.; Royal Society of Chemistry: Cambridge, U.K., 2000; p 212.
24. Brellochs, B.; Backovsky, J.; Stíbr, B.; Jelínek, T.; Holub, J.; Bakardjiev, M.; Hnyk, D.; Hofmann, M.; Císarová, I.; Wrackmeyer, B. Eur. J. Inorg. Chem. 2004, 3605
25. - was first reported in 2001: Jelínek, T.; Stíbr, B.; Holub, J.; Bakardjiev, M.; Hnyk, D.; Ormsby, D. L.; Kilner, C. A.; Thornton-Pett, M.; Schanz, H.-J.; Wrackmeyer, B.; Kennedy, J. D. Chem. Commun. 2001, 1756
26. For example: Franken, A.; McGrath, T. D.; Stone, F. G. A. Organometallics 2005, 24, 5157
27. Lu, X. L.; McGrath, T. D.; Stone, F. G. A. Organometallics 2006, 25, 2590
28. Carr, M. J.; McGrath, T. D.; Stone, F. G. A. Inorg. Chem. 2008, 47, 713
29. Stone, F. G. A. J. Organomet. Chem. 1975, 100, 257
30. Tolman, C. A. Chem. Rev. 1977, 77, 313
31. Baker, R. T.; Delaney, M. S.; King, R. E.; Knobler, C. B.; Long, J. A.; Marder, T. B.; Paxson, T. E.; Teller, R. G.; Hawthorne, M. F. J. Am. Chem. Soc. 1984, 106, 2965
32. Chizhevsky, I. T.; Pisareva, I. V.; Petrovskii, P. V.; Bregadze, V. I.; Yanovsky, A. I.; Struchkov, Yu. T.; Knobler, C. B.; Hawthorne, M. F. Inorg. Chem. 1993, 32, 3393
33. Jeffery, J. C.; Lebedev, V. N.; Stone., F. G. A. Inorg. Chem. 1996, 35, 2967
34. Wolf, J.; Poli, R.; Xie, J.-H.; Nichols, J.; Xi, B.; Zavalij, P.; Doyle, M. P. Organometallics 2008, 27, 5836
35. Cambridge Structural Database. Allen, F. H. Acta Crystallogr. 2002, B58, 380
36. 10]}, the two subclusters are identical but use different B-H units to form the reciprocal B-H→Rh linkages.
37. Londesborough, M. G. S.; Kilner, C. A.; Kennedy, J. D. Collect. Czech. Chem. Commun. 2007, 72, 1639 Note that the intercluster Pd⋯B distance cited in this paper is 2.499(6) Å; we believe this to be erroneous on the basis of our own calculations.
38. Cationic metallcarboranes are relatively rare. See, for example: Ferguson, G.; Pollock, J.; McEneaney, P. A.; O'Connell, D. P.; Spalding, T. R.; Gallagher, J. F.; Macias, R.; Kennedy, J. D. Chem. Commun. 1996, 679
39. Ellis, D. D.; Jelliss, P. A.; Stone, F. G. A. Dalton Trans. 2000, 2113
40. See, for example: Brown, M. P.; Cooper, S. J.; Frew, A. A.; Manojlovic-Muir, L.; Muir, K. W.; Puddephatt, R. J.; Seddon, K. R.; Thomson, M. A. Inorg. Chem. 1981, 20, 1500
41. Djinovic, V. M.; Galanski, M.; Arion, V. B.; Keppler, B. K. Dalton Trans. 2010, 3633, and references therein.
42. Franken, A.; McCown, R. A.; McGrath, T. D.; Stone, F. G. A., unpublished observations.