Macropolyhedral boron-containing cluster chemistry. Ligand-induced two-electron variations of intercluster bonding intimacy. Structures of nineteen-vertex [(η5-C5Me5)HIrB 18H19(PMe2PH)] and the related carbene complex [(η5-C5Me5)HIrB18H 19{C(NHMe)2}]

Dalton Transactions

Volumn , Issue 10, 2004, Pages 1521-1523

  Shea, Suzanne L ^a   Jelínek, Tomáš ^a,b   Perera, Sarath D ^a,c   Štíbr, Bohumil ^b   Thornton Pett, Mark ^a   Kennedy, John D ^a  

^a UNIVERSITY OF LEEDS   (United Kingdom)

^b INSTITUTE OF INORGANIC CHEMISTRY   (Czech Republic)

^c OPEN UNIVERSITY OF SRI LANKA   (Sri Lanka)

Author keywords

[No Author keywords available]

Indexed keywords

BORON COMPOUNDS; CHEMICAL BONDS; CHEMICAL REACTIONS; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SINGLE CRYSTALS; X RAY DIFFRACTION;

INTERCLUSTER FUSION; LIGANDS; SUBCLUSTERS;

AROMATIC COMPOUNDS;

EID: 3042830004     PISSN: 14779226     EISSN: None     Source Type: Journal    
DOI: 10.1039/B404322G     Document Type: Article

References (21)

1. R. E. Williams, Inorg. Chem., 1971, 10, 210; R. E. Williams, Adv. Inorg. Chem. Radiochem., 1976, 18, 64; R. E. Williams, Adv. Organomet. Chem., 1994, 36, 1; K. Wade, Chem. Commmun., 1971, 79; K. Wade, Adv. Inorg. Chem. Radiochem., 1976, 18, 1.
2. R. E. Williams, Inorg. Chem., 1971, 10, 210; R. E. Williams, Adv. Inorg. Chem. Radiochem., 1976, 18, 64; R. E. Williams, Adv. Organomet. Chem., 1994, 36, 1; K. Wade, Chem. Commmun., 1971, 79; K. Wade, Adv. Inorg. Chem. Radiochem., 1976, 18, 1.
3. R. E. Williams, Inorg. Chem., 1971, 10, 210; R. E. Williams, Adv. Inorg. Chem. Radiochem., 1976, 18, 64; R. E. Williams, Adv. Organomet. Chem., 1994, 36, 1; K. Wade, Chem. Commmun., 1971, 79; K. Wade, Adv. Inorg. Chem. Radiochem., 1976, 18, 1.
4. R. E. Williams, Inorg. Chem., 1971, 10, 210; R. E. Williams, Adv. Inorg. Chem. Radiochem., 1976, 18, 64; R. E. Williams, Adv. Organomet. Chem., 1994, 36, 1; K. Wade, Chem. Commmun., 1971, 79; K. Wade, Adv. Inorg. Chem. Radiochem., 1976, 18, 1.
5. R. E. Williams, Inorg. Chem., 1971, 10, 210; R. E. Williams, Adv. Inorg. Chem. Radiochem., 1976, 18, 64; R. E. Williams, Adv. Organomet. Chem., 1994, 36, 1; K. Wade, Chem. Commmun., 1971, 79; K. Wade, Adv. Inorg. Chem. Radiochem., 1976, 18, 1.
6. J. D. Kennedy, in Advances in Boron Chemistry, ed. W. Siebert, Royal Society of Chemistry, Cambridge, 1997, pp. 451-462; T. Jelínek, B. Štíbr, J. D. Kennedy and M. Thornton-Pett, in Advances in Boron Chemistry, ed. W. Siebert, Royal Society of Chemistry, Cambridge, 1997, pp. 426-429; T. Jelínek, J. D. Kennedy, B. Štíbr and M. Thornton-Pett, Inorg. Chem. Commun., 1998, 1, 179; T. Jelínek, I. Cisařová, B. Štíbr, J. D. Kennedy and M. Thornton-Pett, J. Chem. Soc., Dalton Trans., 1998, 2965; J. Bould, W. Clegg, S. J. Teat, L. Barton, N. P. Rath, M. Thornton-Pett and J. D. Kennedy, Inorg. Chim. Acta, 1999, 289, 95.
7. J. D. Kennedy, in Advances in Boron Chemistry, ed. W. Siebert, Royal Society of Chemistry, Cambridge, 1997, pp. 451-462; T. Jelínek, B. Štíbr, J. D. Kennedy and M. Thornton-Pett, in Advances in Boron Chemistry, ed. W. Siebert, Royal Society of Chemistry, Cambridge, 1997, pp. 426-429; T. Jelínek, J. D. Kennedy, B. Štíbr and M. Thornton-Pett, Inorg. Chem. Commun., 1998, 1, 179; T. Jelínek, I. Cisařová, B. Štíbr, J. D. Kennedy and M. Thornton-Pett, J. Chem. Soc., Dalton Trans., 1998, 2965; J. Bould, W. Clegg, S. J. Teat, L. Barton, N. P. Rath, M. Thornton-Pett and J. D. Kennedy, Inorg. Chim. Acta, 1999, 289, 95.
8. J. D. Kennedy, in Advances in Boron Chemistry, ed. W. Siebert, Royal Society of Chemistry, Cambridge, 1997, pp. 451-462; T. Jelínek, B. Štíbr, J. D. Kennedy and M. Thornton-Pett, in Advances in Boron Chemistry, ed. W. Siebert, Royal Society of Chemistry, Cambridge, 1997, pp. 426-429; T. Jelínek, J. D. Kennedy, B. Štíbr and M. Thornton-Pett, Inorg. Chem. Commun., 1998, 1, 179; T. Jelínek, I. Cisařová, B. Štíbr, J. D. Kennedy and M. Thornton-Pett, J. Chem. Soc., Dalton Trans., 1998, 2965; J. Bould, W. Clegg, S. J. Teat, L. Barton, N. P. Rath, M. Thornton-Pett and J. D. Kennedy, Inorg. Chim. Acta, 1999, 289, 95.
9. J. D. Kennedy, in Advances in Boron Chemistry, ed. W. Siebert, Royal Society of Chemistry, Cambridge, 1997, pp. 451-462; T. Jelínek, B. Štíbr, J. D. Kennedy and M. Thornton-Pett, in Advances in Boron Chemistry, ed. W. Siebert, Royal Society of Chemistry, Cambridge, 1997, pp. 426-429; T. Jelínek, J. D. Kennedy, B. Štíbr and M. Thornton-Pett, Inorg. Chem. Commun., 1998, 1, 179; T. Jelínek, I. Cisařová, B. Štíbr, J. D. Kennedy and M. Thornton-Pett, J. Chem. Soc., Dalton Trans., 1998, 2965; J. Bould, W. Clegg, S. J. Teat, L. Barton, N. P. Rath, M. Thornton-Pett and J. D. Kennedy, Inorg. Chim. Acta, 1999, 289, 95.
10. J. D. Kennedy, in Advances in Boron Chemistry, ed. W. Siebert, Royal Society of Chemistry, Cambridge, 1997, pp. 451-462; T. Jelínek, B. Štíbr, J. D. Kennedy and M. Thornton-Pett, in Advances in Boron Chemistry, ed. W. Siebert, Royal Society of Chemistry, Cambridge, 1997, pp. 426-429; T. Jelínek, J. D. Kennedy, B. Štíbr and M. Thornton-Pett, Inorg. Chem. Commun., 1998, 1, 179; T. Jelínek, I. Cisařová, B. Štíbr, J. D. Kennedy and M. Thornton-Pett, J. Chem. Soc., Dalton Trans., 1998, 2965; J. Bould, W. Clegg, S. J. Teat, L. Barton, N. P. Rath, M. Thornton-Pett and J. D. Kennedy, Inorg. Chim. Acta, 1999, 289, 95.
11. S. L. Shea, T. D. McGrath, T. Jelínek, B. Štíbr, M. Thornton-Pett and J. D. Kennedy, Inorg. Chem. Commun., 1998, 1, 97.
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13. 2 = 0.1132 for all 27971 collcted reflections. CCDC reference numbers 233343 (3) and 165856 (4). See http://www.rsc.org/suppdata/dt/b4/b404322g/ for crystallographic data in CIF or other electronic format. For both 3 and 4, methods and programs were standard: G. M. Sheldrick, SHELXS-97, Program for solution of crystal structures, University of Göttingen, Germany, 1997; G. M. Sheldrick, SHELXL-97, Program for refinement of crystal structures, University of Göttingen, Germany, 1997.
14. 2 = 0.1132 for all 27971 collcted reflections. CCDC reference numbers 233343 (3) and 165856 (4). See http://www.rsc.org/suppdata/dt/b4/b404322g/ for crystallographic data in CIF or other electronic format. For both 3 and 4, methods and programs were standard: G. M. Sheldrick, SHELXS-97, Program for solution of crystal structures, University of Göttingen, Germany, 1997; G. M. Sheldrick, SHELXL-97, Program for refinement of crystal structures, University of Göttingen, Germany, 1997.
15. 5), at +3.20 (3H, NMe) and +2.92 (3H, NMe), at +0.96 (1NK) and +0.88 (1NH) and at -14.93 (1H, IrH).
16. R. Macias, J. Holub, W. Clegg, M. Thornton-Pett, B. Štíbr and J. D. Kennedy, J. Chem. Soc., Dalton Trans., 1997, 149.
17. T. Jelínek, J. D. Kennedy, B. Štíbr and M. Thornton-Pett, J. Chem. Soc., Chem. Commun., 1994, 1999.
18. M. A. Fox, J. A. K. Howard, J. M. Moloney and K. Wade, Chem. Commun., 1998, 2487.
19. See, for example, A. A. Arduengo, H. V. R. Dias, J. C. Calabrese and F. Davidson, J. Am. Chem. Soc., 1992, 114, 9724.
20. E. J. Ditzel, X. L. R. Fontaine, N. N. Greenwood, J. D. Kennedy, Zhu Sisan, B. Štíbr and M. Thornton-Pett, J. Chem. Soc., Chem. Commun., 1990, 1741.
21. P. McArdle, ORTEX, version 5, J. Appl. Crystallogr., 1995, 28, 65.