Regiospecific analysis of mono- and diglycerides in glycerolysis products by GC × GC-TOF-MS

JAOCS, Journal of the American Oil Chemists' Society

Volumn 87, Issue 11, 2010, Pages 1255-1262

  Indrasti, Dias ^a   Che Man, Yaakob B ^a   Chin, Sung Tong ^a   Mustafa, Shuhaimi ^a   Mat Hashim, Dzulkifly ^a   Abdul Manaf, Marina ^a  

^a UNIVERSITY PUTRA MALAYSIA   (Malaysia)

Author keywords

Comprehensive two dimensional gas chromatography; Diglycerides; GC GC; Mass spectrometry; Monoglycerides; PCA; Time of flight

Indexed keywords

COMPREHENSIVE TWO-DIMENSIONAL GAS CHROMATOGRAPHY; DIGLYCERIDES; MONOGLYCERIDES; PCA; TIME OF FLIGHT;

EFFLUENTS; GALERKIN METHODS; GLYCEROL; INDUCTIVELY COUPLED PLASMA; MASS SPECTROMETRY; PRINCIPAL COMPONENT ANALYSIS; SMOKE DETECTORS; TWO DIMENSIONAL; VEGETABLE OILS;

GAS CHROMATOGRAPHY;

ZEA MAYS;

EID: 78149285107     PISSN: 0003021X     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11746-010-1614-x     Document Type: Article

References (23)

1. Stauffer CE (2005) Emulsifier for the Food Industry. Wiley, New Jersey
2. NOV Sonntag 1982 Glycerolysis of fats and methyl esters-status, review and critique J Am Oil Chem Soc 59 795A 802A 1:CAS:528:DyaL38XlvVCgs70%3D 10.1007/BF02634442
3. GC Lee DL Wang YF Ho JF Shaw 2004 Lipase-catalyzed alcoholysis of triglycerides for short-chain monoglycerides production J Am Oil Chem Soc 81 533 536 1:CAS:528:DC%2BD2cXlvFKqt7c%3D 10.1007/s11746-006-0936-1
4. H Noureddini V Medikonduru 1997 Glycerolysis of fats and methyl esters J Am Oil Chem Soc 74 419 425 1:CAS:528:DyaK2sXislWgu7k%3D 10.1007/s11746-997-0100- 6
5. T Yang H Zhang AJ Sinclair X Xu 2004 Diacylglycerols from butterfat: production by glycerolysis and short path distillation and analysis of physical properties J Am Oil Chem Soc 81 979 987 1:CAS:528:DC%2BD2cXhtVOit73P 10.1007/s11746-004-1010-8
6. AOAC Official Method 993.18 (2000) Mono- and diglycerides in fats and oils, gas chromatography method. AOAC International Chapter 41: 59-61
7. P Fagan C Wijasundera P Watkins 2004 Determination of mono- and diglycerides in milk lipids J Chromatogr A 1054 251 259 1:CAS:528: DC%2BD2cXos12jsbw%3D 10.1016/j.chroma.2004.04.052 (Pubitemid 39445827)
8. V Ruiz-Gutierrez MC PeRez-Camino 2000 Update on solid-phase extraction for the analysis of lipid classes and related compounds J Chromatogr A 885 321 341 1:CAS:528:DC%2BD3cXktlKmsrs%3D 10.1016/S0021-9673(00)00181-3 (Pubitemid 30392484)
9. L Deng H Nakanao Y Iwasaki 2008 Direct separation of monoacylglycerol isomers by enantioselective high performance liquid chromatography J Chromatogr A 1198-1199 67 72 10.1016/j.chroma.2008.03.095
10. J Dalluge J Been UATh Brinkman 2003 Comprehensive two-dimensional gas chromatography: a powerful and versatile analytical tool J Chromatogr A 1000 69 108 1:CAS:528:DC%2BD3sXktFGgsrs%3D 10.1016/S0021-9673(03)00242-5 (Pubitemid 36638454)
11. LM Blumberg G David MS Klee P Sandra 2008 Comparison of one-dimensional and comprehensive two-dimensional separation by gas chromatography J Chromatogr A 1188 2 16 1:CAS:528:DC%2BD1cXksVKltrk%3D 10.1016/j.chroma.2008.02.044
12. M Junge S Bieri H Huegel PJ Marriott 2007 Fast comprehensive two-dimensional gas chromatography with cryogenic modulation Anal Chem 79 4448 4454 1:CAS:528:DC%2BD2sXlt1WhtLw%3D 10.1021/ac062351n (Pubitemid 46999558)
13. C Chifuntwe F Zhu H Huegel PJ Marriott 2010 Dynamic interconversion of chiral oxime compounds in gas chromatography J Chromatogr A 1217 1114 1125 1:CAS:528:DC%2BC3cXot1yjsA%3D%3D 10.1016/j.chroma.2009.11.084
14. E De Pedro M Casillas CM Miranda 1997 Microwave oven application in the extraction of fat from subcutaneous tissue of Iberian pig ham Meat Sci 45 45 51 10.1016/S0309-1740(96)00097-6 (Pubitemid 127014553)
15. Agilent Technologies DB 17-ht Column (2009). http://www.chem.agilent.com/ en-us/products/consumables/columns/gcandgc-ms/jwdb-17ht/pages/default.aspx. Accessed Oct 2009
16. Sigma-Aldrich SLB™-5 ms (2009). http://www.sigmaaldrich.com/ catalog/ProductDetail.do?N4=28465U|SUPELCO&N5=SEARCH-CONCAT-PNO|BRAND- KEY&F=SPEC&lang=en-US%3E. Accessed Oct 2009
17. VA Isidorov M Rusak L Szczepaniak S Witkowski 2007 Gas chromatographic retention indices of trimethylsilyl derivatives of mono- and diglycerides on capillary column with non-polar stationary phase J Chromatogr A 1166 207 211 1:CAS:528:DC%2BD2sXhtVWmtLnL 10.1016/j.chroma.2007.07.047 (Pubitemid 47361155)
18. MC Perez-Camino W Moreda A Cert 1996 Determination of diacylglycerol isomers in vegetable oils by solid-phase extraction followed by gas chromatography in a polar phase J Chromatogr A 721 305 314 1:CAS:528: DyaK28Xht1Wks7g%3D 10.1016/0021-9673(95)00802-0 (Pubitemid 26049853)
19. A Bareth W Strohmar E Kitzelmann 2003 Gas chromatographic determination of mono- and diglycerides in milk and milk products Eur Food Res Technol 216 365 368 1:CAS:528:DC%2BD3sXisleqsbg%3D
20. O Koprivnjak L Conte O Boschelle S Morassi 1997 Validation of diglyceride contents in cheeses using co-ordinated chromatographic technique Z Lebensm Unters Forsch 204 429 432 1:CAS:528:DyaK2sXkt1Wjtr4%3D 10.1007/s002170050107
21. ST Chin YB Che Man CP Tan DM Hashim 2009 Rapid profiling of animal-derived fatty acids using fast GC × GC coupled to time-of-flight mass spectrometry J Am Oil Chem Soc 86 949 958 1:CAS:528:DC%2BD1MXhtFaqtrfE 10.1007/s11746-009-1427-y
22. MS Klee LM Blumberg 2002 Theoretical and practical aspects of fast gas chromatography and method translation J Chrom Sci 14 234 247
23. KA Fliszar WP Wuelfing Z Li RA Reed 2006 Profiling of medium chain glycerides used in pharmaceutical formulation development by reversed-phase HPLC J Pharm Biomed Anal 40 896 900 1:CAS:528:DC%2BD28Xhs1Sgt7k%3D 10.1016/j.jpba.2005.08.024 (Pubitemid 43257893)