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Volumn 43, Issue 21, 2010, Pages 8828-8835

Ring-opening polymerization of trimethylene carbonate catalyzed by methanesulfonic acid: Activated monomer versus active chain end mechanisms

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATED MONOMERS; COMPETITIVE MECHANISMS; CYCLIC CARBONATES; CYCLIC ETHER; END GROUPS; ETHER LINKAGES; H NMR SPECTROSCOPY; METHANE SULFONIC ACID; MONOMER CONCENTRATION; MULTI-FEED; N-PENTANOL; POLY(TRIMETHYLENE CARBONATE); TRIFLUOROMETHANE SULFONIC ACID; TRIMETHYLENE CARBONATE;

EID: 78149250247     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma101461y     Document Type: Article
Times cited : (110)

References (56)
  • 5
    • 33845961531 scopus 로고    scopus 로고
    • The mechanism of the DMAP-catalyzed ROP of lactide and related O -carboxy-anhydrides has been investigated computationally. In addition to strong basic activation of the alcohol, the acidic o -hydrogen atoms were predicted to slightly activate the monomer by nonclassical hydrogen bonding
    • The mechanism of the DMAP-catalyzed ROP of lactide and related O -carboxy-anhydrides has been investigated computationally. In addition to strong basic activation of the alcohol, the acidic o -hydrogen atoms were predicted to slightly activate the monomer by nonclassical hydrogen bonding: Thillaye du Boullay, O.; Marchal, E.; Martin-Vaca, B.; Cossio, F. P.; Bourissou, D. J. Am. Chem. Soc. 2006, 128, 16442-16443
    • (2006) J. Am. Chem. Soc. , vol.128 , pp. 16442-16443
    • Thillaye Du Boullay, O.1    Marchal, E.2    Martin-Vaca, B.3    Cossio, F.P.4    Bourissou, D.5
  • 19
    • 77957162868 scopus 로고    scopus 로고
    • The mechanism of the HOTf- and MSA-catalyzed ROP of ε-caprolactone has been investigated computationally. In addition to strong electrophilic activation of the monomer, the basic oxygen atoms of the sulfonic acids were predicted to slightly activate the alcohol by hydrogen bonding:;, - 6587
    • The mechanism of the HOTf- and MSA-catalyzed ROP of ε-caprolactone has been investigated computationally. In addition to strong electrophilic activation of the monomer, the basic oxygen atoms of the sulfonic acids were predicted to slightly activate the alcohol by hydrogen bonding: Susperregui, N.; Delcroix, D.; Martin-Vaca, B.; Bourissou, D.; Maron, L. J. Org. Chem. 2010, 75, 6581 - 6587.
    • (2010) J. Org. Chem. , vol.75 , pp. 6581
    • Susperregui, N.1    Delcroix, D.2    Martin-Vaca, B.3    Bourissou, D.4    Maron, L.5
  • 26
    • 36849000315 scopus 로고    scopus 로고
    • Theoretical studies have substantiated the bifunctional behavior of TBD and of a thiourea/sparteine derivative in the ROP of δ-valerolactone and lactide
    • Theoretical studies have substantiated the bifunctional behavior of TBD and of a thiourea/sparteine derivative in the ROP of δ-valerolactone and lactide: Simon, L.; Goodman, J. M. J. Org. Chem. 2007, 72, 9656-9662
    • (2007) J. Org. Chem. , vol.72 , pp. 9656-9662
    • Simon, L.1    Goodman, J.M.2
  • 39
    • 0033707242 scopus 로고    scopus 로고
    • Feasibility of the ROP of 1,3-dioxepan-2-one (7CC) catalyzed by HCl has also been reported
    • Feasibility of the ROP of 1,3-dioxepan-2-one (7CC) catalyzed by HCl has also been reported: Shibasaki, Y.; Sanada, H.; Yokoi, M.; Sanda, F.; Endo, T. Macromolecules 2000, 33, 4316-4320
    • (2000) Macromolecules , vol.33 , pp. 4316-4320
    • Shibasaki, Y.1    Sanada, H.2    Yokoi, M.3    Sanda, F.4    Endo, T.5
  • 41
    • 0032188225 scopus 로고    scopus 로고
    • Feasibility of the ROP of 7CC and TMC catalyzed by trifluoroacetic acid has also been reported
    • Feasibility of the ROP of 7CC and TMC catalyzed by trifluoroacetic acid has also been reported: Matsuo, J.; Nakano, S.; Sanda, F.; Endo, T. J. Polym. Sci., Part A: Polym. Chem. 1998, 36, 2463-2471
    • (1998) J. Polym. Sci., Part A: Polym. Chem. , vol.36 , pp. 2463-2471
    • Matsuo, J.1    Nakano, S.2    Sanda, F.3    Endo, T.4


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.