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Despite the lack of ring strain, macrocyclic esters also proved to be efficient albeit not activated monomers for entropically driven ROP: (a) Zhang, D.; Xu, J.; Alcazar-Roman, L.; Greenman, L.; Cramer, C. J.; Hillmyer, M. A.; Tolman, W. B. Macromolecules 2004, 37, 5274-5281.
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Despite the lack of ring strain, macrocyclic esters also proved to be efficient albeit not activated monomers for entropically driven ROP: (a) Zhang, D.; Xu, J.; Alcazar-Roman, L.; Greenman, L.; Cramer, C. J.; Hillmyer, M. A.; Tolman, W. B. Macromolecules 2004, 37, 5274-5281.
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n < 4.000) could be obtained whatever the monomer feed.
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n < 4.000) could be obtained whatever the monomer feed.
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The related α-amino acid N-carboxyanhydrides (NCA) proved to be convenient precursors for polypeptides: (a) Deming, T. J. J. Polym. Sci. Part A: Polym. Chem. 2000, 38, 3011-3018.
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84961979150
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Monoesters of carbonic acids are known to be highly unstable with respect to decarboxylation. See
-
Monoesters of carbonic acids are known to be highly unstable with respect to decarboxylation. See: Dibenedetto, A.; Aresta, M.; Giannoccaro, P.; Pastore, C.; Pápai, I.; Schubert, G. Eur. J. Inorg. Chem. 2006, 908-913.
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46
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33845926839
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nH oligomers in ES1-MS indicates that complete decarboxylation occurs during the polymerization (Figure S2).
-
nH oligomers in ES1-MS indicates that complete decarboxylation occurs during the polymerization (Figure S2).
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47
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33845964176
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Bourissou, D.; Thillaye du Boullay, O.; Marchal, E.; Martin-Vaca, B. WO2006037812, April 13, 2006.
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