Importance of equilibrium fluctuations between most stable conformers in the control of the reaction mechanism

Journal of Organic Chemistry

Volumn 75, Issue 21, 2010, Pages 7186-7193

  Souza, Bruno S ^a   Nome, Faruk ^a  

^a FEDERAL UNIVERSITY OF SANTA CATARINA   (Brazil)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRONIC EFFECTS; EQUILIBRIUM FLUCTUATION; GENERAL BASE; INTRAMOLECULAR GENERAL BASE CATALYSIS; INTRAMOLECULAR NUCLEOPHILIC ATTACK; NAPHTHOIC ACIDS; NUCLEOPHILIC ATTACK; REACTING GROUPS; REACTION COORDINATES; REACTION MECHANISM; RELATED COMPOUNDS; STABLE CONFORMERS; STRUCTURAL DIFFERENCES; WATER MOLECULE;

ACIDS; HYDROLYSIS; ROTATION;

CATALYSIS;

1 ACETOXY 2 NAPHTHOIC ACID; 1 HYDROXY 2 NAPHTHOIC ACID; 3 ACETOXY 2 NAPHTHOIC ACID; 3 HYDROXY 2 NAPHTHOIC ACID; ACETYLSALICYLIC ACID; AROMATIC CARBOXYLIC ACID; HYDROXYACID; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; CONFORMATION; CRYSTAL STRUCTURE; ELECTROSPRAY MASS SPECTROMETRY; EQUILIBRIUM CONSTANT; HYDROLYSIS; IONIC STRENGTH; ISOMER; ISOTOPE LABELING; MOLECULAR ELECTRONICS; NUCLEOPHILICITY; REACTION ANALYSIS; STEREOCHEMISTRY; STRUCTURE ANALYSIS; THERMODYNAMICS;

EID: 78049510005     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo101366m     Document Type: Article

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