A stereocontrolled synthesis of (±)-xenovenine via a scandium(III)-catalyzed internal aminodiene bicyclization terminated by a 2-(5-ethyl-2-thienyl)ethenyl group

Organic Letters

Volumn 12, Issue 19, 2010, Pages 4271-4273

  Jiang, Tao ^a   Livinghouse, Tom ^a  

^a MONTANA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMINE; ETHYLENE; ETHYLENE DERIVATIVE; PYRROLIZIDINE ALKALOID; SCANDIUM; XENOVENINE;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; CYCLIZATION; STEREOISOMERISM; SYNTHESIS;

AMINES; CATALYSIS; CYCLIZATION; ETHYLENES; MOLECULAR STRUCTURE; PYRROLIZIDINE ALKALOIDS; SCANDIUM; STEREOISOMERISM;

EID: 77957149896     PISSN: 15237060     EISSN: 15237052     Source Type: Journal    
DOI: 10.1021/ol101646t     Document Type: Article

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54. 3 and hydrolysis.
55. (±)-Xenovenine prepared in this manner was spectroscopically identical to the natural and previously synthesized products.