메뉴 건너뛰기




Volumn 16, Issue 36, 2010, Pages 11089-11099

The effect of ligand denticity in size-selective synthesis of calix[n]arenestabilized gold nanoparticles: A multitechnique approach

Author keywords

Calixarenes; Denticity; Gold; Ligand effects; Nanoparticles

Indexed keywords

ARENE DERIVATIVES; ARENE LIGANDS; CALIXARENES; CONTROL ELEMENTS; DENTICITY; DIRECT SYNTHESIS; ELEMENTAL ANALYSIS; EXPERIMENTAL CONDITIONS; EXPERIMENTAL DATA; GOLD NANOPARTICLE; GOLD NANOPARTICLES; LIGAND EFFECTS; MONODENTATES; MULTI-TECHNIQUE APPROACH; MULTIDENTATE; NMR SPECTROSCOPY; NUCLEARITY; SIZE-SELECTIVE; TEM; THIOLATES; X-RAY PHOTOELECTRONS; XPS;

EID: 77956948190     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201001039     Document Type: Article
Times cited : (16)

References (76)
  • 4
    • 0345977867 scopus 로고
    • d) G. Schmid, Chem. Rev. 1992, 92, 1709-1727.
    • (1992) Chem. Rev. , vol.92 , pp. 1709-1727
    • Schmid, G.1
  • 6
    • 0344047480 scopus 로고    scopus 로고
    • (Eds.: P. Gomez-Romero, C. Sanchez), WileyVCH, Weinheim
    • b) Functional Hybrid Materials (Eds.: P. Gomez-Romero, C. Sanchez), WileyVCH, Weinheim, 2004.
    • (2004) Functional Hybrid Materials
  • 8
    • 76649144500 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2010, 49, 1362-1395;
    • (2010) Angew. Chem. Int. Ed. , vol.49 , pp. 1362-1395
  • 10
    • 9244223728 scopus 로고    scopus 로고
    • (Ed.: V.M. Rotello) Kluwer Academic/Plenum Publisher, New York
    • c) Nanoparticles-Building Blocks for Nanotechnology (Ed.: V.M. Rotello) Kluwer Academic/Plenum Publisher, New York, 2004;
    • (2004) Nanoparticles-Building Blocks for Nanotechnology
  • 17
    • 33748799131 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2006, 45, 5924-5948;
    • (2006) Angew. Chem. Int. Ed. , vol.45 , pp. 5924-5948
  • 22
    • 18844365434 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2005, 44, 2913-2916.
    • (2005) Angew. Chem. Int. Ed. , vol.44 , pp. 2913-2916
  • 26
    • 33751285162 scopus 로고    scopus 로고
    • Monodispersed alkylthiol-stabilized undecagold clusters can be obtained through ligand-exchange reactions starting from the corresponding rather unstable phosphine-stabilized clusters. See, for example: a) M. F. Bertino, Z. M. Sun, R. Zhang, L. S. Wang, J. Phys. Chem. B 2006, 110, 21416-21418;
    • (2006) J. Phys. Chem. B , vol.110 , pp. 21416-21418
    • Bertino, M.F.1    Sun, Z.M.2    Zhang, R.3    Wang, L.S.4
  • 29
    • 67651233657 scopus 로고    scopus 로고
    • The exploitation of these properties in fields such as biology and medicine has been already documented. See, for example: a) E. Boisselier, D. Astruc, Chem. Soc. Rev. 2009, 38,1759-1782;
    • (2009) Chem. Soc. Rev. , vol.38 , pp. 1759-1782
    • Boisselier, E.1    Astruc, D.2
  • 32
    • 36148968077 scopus 로고    scopus 로고
    • For a review on kinetic and mechanistic studies of the nucleation and growth of gold nanoparticles, see, for example: E. E. Finney, R. G. Finke, J. Colloid Interface Sci. 2008, 317, 351-374.
    • (2008) J. Colloid Interface Sci. , vol.317 , pp. 351-374
    • Finney, E.E.1    Finke, R.G.2
  • 45
    • 33645472460 scopus 로고    scopus 로고
    • Wei et al. have shown, that resorc[4]arenes with SH groups on their upper rim can be used for the stabilization of AuNPs. See: a) A. Wei, Chem. Commun. 2006, 1581-1591;
    • (2006) Chem. Commun. , pp. 1581-1591
    • Wei, A.1
  • 47
    • 69549118600 scopus 로고    scopus 로고
    • The partial functionalization of the phenolic groups present on the lower rim of calix[4]arenes enhances the preorganization of these hosts in solution of low polar solvents. Unlike the tetralkylated ones, the aromatic cavity of mono- or dialkylated calix[4]arene derivatives has been indeed exploited as a binding site for the recognition of charged organic species. See, for example: L. Pescatori, A. Arduini, A. Pochini, A. Secchi, C. Massera, F. Ugozzoli, Org. Biomol. Chem. 2009, 7, 3698-3708.
    • (2009) Org. Biomol. Chem. , vol.7 , pp. 3698-3708
    • Pescatori, L.1    Arduini, A.2    Pochini, A.3    Secchi, A.4    Massera, C.5    Ugozzoli, F.6
  • 52
    • 0037031418 scopus 로고    scopus 로고
    • A survey of the literature data shows that similar results were found in the synthesis of silver nanoparticles in a monophase system (solution in DMF) by using multithiolate β-cyclodextrins (CDs) as stabilizing agents. The reduced size of the resulting nanoparticles was ascribed to a "macrocyclic effect". See: J. Liu, W. Ong, A. E. Kaifer, C. Peinador, Langmuir 2002, 18, 5981-5983.
    • (2002) Langmuir , vol.18 , pp. 5981-5983
    • Liu, J.1    Ong, W.2    Kaifer, A.E.3    Peinador, C.4
  • 53
    • 77956966097 scopus 로고    scopus 로고
    • note
    • 4 collapsed after the reaction workup.
  • 56
    • 77956965549 scopus 로고    scopus 로고
    • note
    • 28.
  • 59
    • 0033943114 scopus 로고    scopus 로고
    • 2*; FWHM = full width at half-maximum) and is usually correlated with slow rotating molecules in solution. See: A. Badia, R. B. Lennox, L. Reven, Acc. Chem. Res. 2000, 33, 475-481.
    • (2000) Acc. Chem. Res. , vol.33 , pp. 475-481
    • Badia, A.1    Lennox, R.B.2    Reven, L.3
  • 68
    • 77952083987 scopus 로고    scopus 로고
    • See, for example: a) R. Jin, Nanoscale 2010, 2, 343-362;
    • (2010) Nanoscale , vol.2 , pp. 343-362
    • Jin, R.1
  • 69
    • 35349013043 scopus 로고    scopus 로고
    • and references therein
    • b) R. L. Whetten, R. C. Price, Science 2007, 318, 407-408, and references therein.
    • (2007) Science , vol.318 , pp. 407-408
    • Whetten, R.L.1    Price, R.C.2
  • 71
    • 35048859425 scopus 로고    scopus 로고
    • These findings could be also useful in explaining the improved stability and reduced core size of AuNPs coated with natural molecules such as glutathione that contain an oxygen atom other than a thiol group as surface stabilizing agent. See, for example: Y. Negishi, N. K. Chaki, Y. Shichibu, R. L. Whetten, T. Tsukuda, J. Am. Chem. Soc. 2007, 129, 11322-11323.
    • (2007) J. Am. Chem. Soc. , vol.129 , pp. 11322-11323
    • Negishi, Y.1    Chaki, N.K.2    Shichibu, Y.3    Whetten, R.L.4    Tsukuda, T.5
  • 76
    • 77956959673 scopus 로고    scopus 로고
    • ImageJ, Image Processing and Analysis in Java. Public domain software developed at the National Institute of Health and available on the Internet from
    • ImageJ, Image Processing and Analysis in Java. Public domain software developed at the National Institute of Health and available on the Internet from http://rsbweb.nih.gov/ij/.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.