Synthesis, isolation, and characterization of 1, 1-digrignard and 1, 1-dizincio silanes

Angewandte Chemie - International Edition

Volumn 49, Issue 39, 2010, Pages 7086-7088

  Dobrovetsky, Roman ^a   Bravo Zhivotovskii, Dmitry ^a   Tumanskii, Boris ^a   Botoshansky, Mark ^a   Apeloig, Yitzhak ^a  

^a TECHNION ISRAEL INSTITUTE OF TECHNOLOGY   (Israel)

Author keywords

Dianions; Grignard reagents; Radicals; Silicon transmetalation

Indexed keywords

DIANIONS; GRIGNARD REAGENT; RADICALS; SILYL RADICAL; TETRA-HYDROFURAN; TRANSMETALATION REACTION;

LITHIUM; ORGANIC SOLVENTS; SILANES; X RAY CRYSTALLOGRAPHY;

REDOX REACTIONS;

EID: 77956922995     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201002876     Document Type: Article

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36. Crystallographic data for 2:C40H92Cl4Mg4O4Si6, Mr= 1044.72, monoclinic, space group C 2/c, a = 30.776(6), b = 11.059(2), c = 20.051(4) Å, β = 114.51(3)°, V = 6209(2) Å3, Z = 8, Nonius Kappa CCD, MoKa radiation (0.71073 Å), 240 K, 2θmax = 25°, R = 0.0627 (I > 2θI), WR2 = 0.1803 (I > 2σI), Rw = 0.1016 (all data), GOF = 1.223. CCDC 773215 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data-request/cif.
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