Reactions of benzene based half sandwich ruthenium(II) complex with 2,6-bis((phenylseleno)methyl)pyridine: Preferential substitution of ring resulting in a catalyst of high activity for oxidation of alcohols

Inorganic Chemistry Communications

Volumn 13, Issue 11, 2010, Pages 1370-1373

  Das, Dipanwita ^a   Singh, Pradhumn ^a   Prakash, Om ^a   Singh, Ajai K ^a  

^a INDIAN INSTITUTE OF TECHNOLOGY DELHI   (India)

Author keywords

Alcohols; Catalytic oxidation; Crystal structure; Pincer ligand; Ruthenium(II); Synthesis

Indexed keywords

EID: 77956901992     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2010.07.039     Document Type: Article

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19. - 3] 1.054/-0.893.
20. (a) Selected bond angles (°) of 1: N(3)-Ru(1)-N(2) 89.1(3), N(3)-Ru(1)-N(1) 93.1(3), N(2)-Ru(1)-N(1) 177.2(3), N(3)-Ru(1)-Cl(1) 177.73(19), N(2)-Ru(1)-Cl(1) 89.3(2), N(1)-Ru(1)-Cl(1) 88.5(2), N(3)-Ru(1)-Se(1) 94.1(2), N(2)-Ru(1)-Se(1) 92.8(2), N(1)-Ru(1)-Se(1) 85.4(2), N(3)-Ru(1)-Se(2) 94.8(2), N(2)-Ru(1)-Se(2) 98.6(2), N(1)-Ru(1)-Se(2) 82.99(1) Se(1)-Ru(1)-Se(2) 165.65(5)
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