Synthesis, structure and catalytic activities for the hydrogen transfer reactions of the ruthenium(II) carbonyl chloride complexes with pyridine-2,6-diimine

Inorganic Chemistry Communications

Volumn 12, Issue 9, 2009, Pages 887-889

  Lu, Xiang Yong ^a   Xu, Hui Jun ^a   Chen, Xue Tai ^a  

^a NANJING UNIVERSITY   (China)

Author keywords

Crystal structure; Pyridine 2,6 diimine; Ruthenium complex; Transfer hydrogenation

Indexed keywords

EID: 69249210883     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2009.07.004     Document Type: Article

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26. n (0.13 g, 0.59 mmol). The mixture was refluxed at 80 °C for 2.5 h. After cooling, a dark brown microcrystalline solid was collected, and washed with cooled absolute ethanol and then dried at air. Yield: 71%. Complex 2 was prepared by the similar procedure. Yield: 51%.
27. + 646.08 (100 %). Anal. Calc. for: C, 59.82; H, 6.50; N, 6.15. Found: C, 59.92; H, 6.78; N, 6.35%.
28. 2 (all data) = 0.1993.
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30. iPrOH at 82 °C (ketone/catalyst/base = 500/1/24). The reaction was monitored by gas chromatography.