Formation of an iodide-bridged diruthenium complex from [(n 5-Ph4C4COH)(CO)2RuI] and [(Ph 4C4CO)(CO)2Ru]2: An efficient catalyst for alcohol oxidation with Ag2O

Organometallics

Volumn 28, Issue 15, 2009, Pages 4624-4627

  Do, Youngshil ^a   Ko, Soo Byung ^a   Hwang, In Chul ^a   Lee, Kyung Eun ^b   Lee, Soon W ^b   Park, Jaiwook ^a  

^a Pohang University of Science and Technology (POSTECH)   (South Korea)

^b Sungkyunkwan University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL OXIDATION; CATALYTIC ACTIVITY; DIRUTHENIUM COMPLEX; EFFICIENT CATALYSTS; OXIDATION OF ALCOHOLS; ROOM TEMPERATURE; SILVER OXIDES;

ORGANIC POLYMERS; OXIDATION; RUTHENIUM COMPOUNDS; SILVER; SILVER COMPOUNDS;

CATALYTIC OXIDATION;

EID: 68149098744     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9003434     Document Type: Article

References (36)

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27. Despite the presence of an intervening octahedral calcium fragment, the Ru-I-Ru bond angle (126.00(2)°) in 8 is practically the same as that (125.97(2)°) found in the analogous structure of 4 in Scheme 2.
28. 2.
29. 3 pad, 8 was obtained quantitatively.
30. See Supporting Information.
31. The distances between two oxygen atoms of the Cp rings in 6b and 8 are 5.44 and 4.92 Å, respectively.
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