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Volumn 49, Issue 38, 2010, Pages 6852-6855

Selective P-P and P-O-P bond formations through copper-catalyzed aerobic oxidative dehydrogenative couplings of H-phosphonates

Author keywords

Copper; Dehydrogenation; Homogeneous catalysis; Phosphorus

Indexed keywords

BOND FORMATION; CHEMICAL EQUATIONS; COPPER COMPLEXES; DEHYDROGENATIVE COUPLING; H-PHOSPHONATES; HIGH SELECTIVITY; HIGH YIELD; HOMOGENEOUS CATALYSIS; OXIDATIVE COUPLINGS; TETRAMETHYLETHYLENEDIAMINE;

EID: 77956587930     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201003484     Document Type: Article
Times cited : (86)

References (64)
  • 25
    • 71549170228 scopus 로고    scopus 로고
    • For metal-catalyzed dehydrocoupling reactions of other heteroatom compounds, see also: j) D. Miles, J. Ward, D. A. Foucher, Macromolecules 2009, 42, 9199;
    • (2009) Macromolecules , vol.42 , pp. 9199
    • Miles, D.1    Ward, J.2    Foucher, D.A.3
  • 43
    • 77956579277 scopus 로고    scopus 로고
    • 2P(O)OH+ 2AcOH. However, the exact pathway for the formation of 3 is not clear
    • 2P(O)OH+ 2AcOH. However, the exact pathway for the formation of 3 is not clear.
  • 44
    • 77956575610 scopus 로고    scopus 로고
    • CCDC 777312 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via
    • CCDC 777312 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc. cam.ac.uk/data-request/cit.
  • 50
    • 77956579527 scopus 로고    scopus 로고
    • 2→1 + 2 Cu(OAc) + 2 AcOH
    • 2→1 + 2 Cu(OAc) + 2 AcOH.
  • 51
    • 77956567714 scopus 로고    scopus 로고
    • For details of the experiments, see the Supporting Information. A separate experiment using isolated la showed that compound la is stable under the reaction conditions for the formation of 2a, indicating that 2a was not formed by further oxidation of 1a
    • For details of the experiments, see the Supporting Information. A separate experiment using isolated la showed that compound la is stable under the reaction conditions for the formation of 2a, indicating that 2a was not formed by further oxidation of 1a.
  • 58
    • 61349164417 scopus 로고    scopus 로고
    • Cu-catalyzed oxidative couplings are of high interest, but their mechanisms are not well understood
    • Cu-catalyzed oxidative couplings are of high interest, but their mechanisms are not well understood: a) K. Kamata, S. Yamaguchi, M. Kotani, K. Yamaguchi, N. Mizuno, Angew. Chem. 2008, 120, 2441;
    • (2008) Angew. Chem. , vol.120 , pp. 2441
    • Kamata, K.1    Yamaguchi, S.2    Kotani, M.3    Yamaguchi, K.4    Mizuno, N.5


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.