Selective dehydrocoupling of phosphines by triamidoamine zirconium catalysts

Organometallics

Volumn 26, Issue 10, 2007, Pages 2492-2494

  Waterman, Rory ^a  

^a UNIVERSITY OF VERMONT   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

DEHYDROCOUPLING; MECHANISTIC ANALYSIS; TRIAMIDOAMINE ZIRCONIUM;

CATALYSTS; CHEMICAL BONDS; ORGANOMETALLICS; ZIRCONIUM;

PHOSPHATES;

EID: 34249085537     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om070189o     Document Type: Article

References (34)

1. (a) Gauvin, F.; Harrod, J. F.; Woo, H. G. Adv. Organomet. Chem. 1998, 42, 363-405.
2. (b) Corey, J. Y. Adv. Organomet. Chem. 2004, 51, 1-52.
3. Bohm, V. P. W.; Brookhart, M. Angew. Chem., Int. Ed. 2001, 40, 4694-4696.
4. Han, L.-B.; Tilley, T. D. J. Am. Chem. Soc. 2006, 128, 13698-13699.
5. (a) Fermin, M. C.; Stephan, D. W. J. Am. Chem. Soc. 1995, 117, 12645-12646.
6. (b) Etkin, N.; Fermin, M. C.; Stephan, D. W. J. Am. Chem. Soc. 1997, 119, 2954-2955.
7. (c) Hoskin, A. J.; Stephan, D. W. Angew. Chem., Int. Ed. 2001, 40, 1865-1867.
8. (d) Stephan, D. W. Angew. Chem., Int. Ed. 2000, 39, 314-329.
9. (e) Masuda, J. D.; Hoskin, A. J.; Graham, T. W.; Beddie, C.; Fermin, M. C.; Etkin, N.; Stephan, D. W. Chem.-Eur. J. 2006, 12, 8696-8707.
10. Xin, S.; Woo, H. G.; Harrod, J. F.; Samuel, E.; Lebuis A.-M. J. Am. Chem. Soc. 1997, 119, 5307-5313.
11. Catalytic dehydrocoupling of phosphine-borane adducts has been reported with early transition-metal catalysts: (a) Dorn, H.; Singh, R. A.; Massey, J. A.; Nelson, J. M.; Jaska, C. A.; Lough, A. J.; Manners, I. J. Am. Chem. Soc. 2000, 122, 6669-6678.
12. (b) Jaska, C. A.; Manners I. In Inorganic Chemistry in Focus II; Meyer, G., Naumann, D., Wesemann, L., Eds.; Wiley-VCH Verlag GmbH & Co. KGaA: Weinheim, Germany, 2005; pp 53-64.
13. Schrock, R. R. Acc. Chem. Res. 1997, 30, 9-16.
14. (a) Duan, Z.; Naiini, A. A.; Lee, J.-H.; Verkade, J. G. Inorg. Chem. 1995, 34, 5477-5482.
15. (b) Morton, C.; Munslow, I. J.; Sanders, C. J.; Alcock, N. W.; Scott, P. Organometallics 1999, 18, 4608-4613.
16. Baker, R. T. Whitney, J. F. Wreford, S. S. Organometallics 1983, 2, 1049-1051.
17. 6, 202.4 MHz) -26.19 (s).
18. (a) Benac, B. L; Jones, R. A. Polyhedron 1989, 8, 1774-1777.
19. (b) Baker, R. T.; Fultz, W. C.; Marder, T. B.; Williams, I. D. Organometallics 1990, 9, 2357-2367.
20. (c) Larsonneur, A.-M.; Choukroun, R.; Daran, J.-C.; Cuenca, T.; Flores, J. C.; Royo, P. J. Organomet. Chem. 1993, 444, 83-89.
21. (d) Danopoulos, A. A.; Edwards, P. G.; Harman, M.; Hursthouse, M. B.; Parry, J. S. J. Chem. Soc., Dalton Trans. 1994, 7, 977-985.
22. (e) Lindenberg, F.; Shribman, T.; Sieler, J.; Hey-Hawkins, E.; Eisen, M. S. J. Organomet. Chem. 1996, 515, 19-25.
23. (f) Breen, T. L.; Stephan, D. W. Organometallics 1996, 15, 4509-4514.
24. (g) Urnėžius, E.; Klippenstein, S. J.; Protasiewicz, J. D. Inorg. Chim. Acta 2000, 297, 181 -190.
25. (h) Urnėžius, E.; Kin-Chung, L.; Rheingold, A. L.; Protasiewicz, J. D. J. Organomet. Chem. 2001, 630, 193-197.
26. Other group 4 metals with phosphido ligands display similar spectroscopic properties: (a) Roddick, D. M.; Santarsiero, B. D.; Bercaw, J. E J. Am. Chem. Soc. 1985, 107, 4670-4678.
27. (b) Vaughn, G. A.; Hillhouse, G. L.; Rheingold, A. L. Organometallics 1989, 8, 1760-1765.
28. PH values: Basuli, F.; Tomaszewski, J.; Huffman, J. C.; Mindiola, D. J. J. Am. Chem. Soc. 2003, 125, 10170-10171.
29. 2O followed by distillation. A description of this competition experiment can be found in the Supporting Information.
30. (a) Fendrick, C. M.; Marks, T. J. J. Am. Chem. Soc. 1986, 108, 425.
31. (b) Thompson, M. E.; Baxter, S. M.; Bulls, A. R.; Burger, B. J.; Nolan, M. C.; Santarsiero, B. D.; Schaefer, W. P.; Bercaw, J. E. J. Am. Chem. Soc. 1987, 109, 203-219.
32. (c) Tilley, T. D. Comments Inorg. Chem. 1990, 10, 37-46.
33. (a) Blaurock, S.; Hey-Hawkins, E. Zeit. Anorg. Allg. Chem. 2002, 628, 37-40.
34. (b) Baudler, M.; Gruner, C.; Tschaebunin, H.; Hahn, J. Chem. Ber. 1982, 115, 1739-1745.