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Volumn , Issue 26, 2010, Pages 4148-4156

Mononuclear copper(I) complexes containing redox-active 1,2-bis(arylimino)acenaphthene acceptor ligands: Synthesis, crystal structures and tuneable electronic properties

Author keywords

Charge transfer; Copper; Electronic spectra; Solvatochromism

Indexed keywords

CHARGE TRANSFER; CHELATION; COPPER COMPOUNDS; ELECTRONIC PROPERTIES; EXCITED STATES; PHOTOSENSITIZERS; REDOX REACTIONS; SPECTROSCOPIC ANALYSIS; SYNTHESIS (CHEMICAL); TRANSITION METALS; X RAY CRYSTALLOGRAPHY;

EID: 77956586074     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.201000061     Document Type: Article
Times cited : (49)

References (53)
  • 11
    • 0037472713 scopus 로고    scopus 로고
    • Some related copper(II) and dimeric copper(I) complexes carrying Ar-BIAN ligands have recently been investigated, see: a
    • Some related copper(II) and dimeric copper(I) complexes carrying Ar-BIAN ligands have recently been investigated, see: a) U. El-Ayaan, A. Paulovicova, Y. Fukuda, J Mol. Struct, 2003, 645, 205;
    • (2003) J Mol. Struct , vol.645 , pp. 205
    • El-Ayaan, U.1    Paulovicova, A.2    Fukuda, Y.3
  • 21
    • 0038829070 scopus 로고
    • For monodentate copper(I) phosphane complexes see: and references cited therein.
    • For monodentate copper(I) phosphane complexes see: S. J. Lippard, J. J. Mayerle, Inorg Chem. 1972, 11, 753, and references cited therein.
    • (1972) Inorg Chem. , vol.11 , pp. 753
    • Lippard, S.J.1    Mayerle, J.J.2
  • 25
    • 85153280499 scopus 로고    scopus 로고
    • + feature an absorption band at longer wavelength. This and further results will be presented separately.
    • + feature an absorption band at longer wavelength. This and further results will be presented separately.
  • 34
    • 0003787137 scopus 로고
    • This can be readily derived by qualitative Hückel MO considerations for the parent system butadiene: I. Fleming, Wiley, New York
    • This can be readily derived by qualitative Hückel MO considerations for the parent system butadiene: I. Fleming, Frontier Orbitals and Organic Chemical Reactions, Wiley, New York, 1976, p 17.
    • (1976) Frontier Orbitals and Organic Chemical Reactions
  • 37
    • 85153226410 scopus 로고    scopus 로고
    • pa = +1.10 V vs. SCE tentatively assigned to the copper (I/II) redox couple. Rough estimates for the MLCT excited state redox potentials (electronic origin around 600 nm or 2.07 eV) are therefore +1.40 V and -0.97 V vs. SCE (+1.64 V and -0.73 V vs. NHE) for reductive and oxidative quenching processes, respectively.
    • pa = +1.10 V vs. SCE tentatively assigned to the copper (I/II) redox couple. Rough estimates for the MLCT excited state redox potentials (electronic origin around 600 nm or 2.07 eV) are therefore +1.40 V and -0.97 V vs. SCE (+1.64 V and -0.73 V vs. NHE) for reductive and oxidative quenching processes, respectively.
  • 51
    • 0004210336 scopus 로고    scopus 로고
    • version 2.89, Stoe & Cie GmbH, Darmstadt, Germany
    • Stoe IPDS software, version 2.89, Stoe & Cie GmbH, Darmstadt, Germany, 1998.
    • (1998) Stoe IPDS Software
  • 53
    • 0004150157 scopus 로고    scopus 로고
    • Program for crystal structure refinement. University of Gottingen, Germany
    • G. M. Sheldrick, SHELXL-97, Program for crystal structure refinement. University of Gottingen, Germany, 1997.
    • (1997) SHELXL-97
    • Sheldrick, G.M.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.