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85153280499
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+ feature an absorption band at longer wavelength. This and further results will be presented separately.
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+ feature an absorption band at longer wavelength. This and further results will be presented separately.
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85153226410
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pa = +1.10 V vs. SCE tentatively assigned to the copper (I/II) redox couple. Rough estimates for the MLCT excited state redox potentials (electronic origin around 600 nm or 2.07 eV) are therefore +1.40 V and -0.97 V vs. SCE (+1.64 V and -0.73 V vs. NHE) for reductive and oxidative quenching processes, respectively.
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pa = +1.10 V vs. SCE tentatively assigned to the copper (I/II) redox couple. Rough estimates for the MLCT excited state redox potentials (electronic origin around 600 nm or 2.07 eV) are therefore +1.40 V and -0.97 V vs. SCE (+1.64 V and -0.73 V vs. NHE) for reductive and oxidative quenching processes, respectively.
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