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Volumn 39, Issue 37, 2010, Pages 8733-8740

Isolation and characterization of a new type of μ-hydroxo-bis- Zn(salphen) assembly

Author keywords

[No Author keywords available]

Indexed keywords

BUILDING BLOCKES; CATALYTIC POTENTIAL; CLEAVAGE REACTION; DINUCLEAR; ISOLATION AND CHARACTERIZATION; POLAR MEDIA; SOLUTION STABILITY;

EID: 77956476712     PISSN: 14779226     EISSN: 14779234     Source Type: Journal    
DOI: 10.1039/c001801e     Document Type: Article
Times cited : (9)

References (32)
  • 13
  • 23
    • 21844455264 scopus 로고    scopus 로고
    • For a recent example of a functional model for metallohydrolases see
    • J. Weston Chem. Rev. 2005 105 2151
    • (2005) Chem. Rev. , vol.105 , pp. 2151
    • Weston, J.1
  • 25
    • 25444481610 scopus 로고    scopus 로고
    • 4OH and X-ray diffraction in this case confirmed the presence of the sandwich structure. The crystal quality in this case proved to be poor; an image of the structure is reported in the ESI TWINABS Version 2008/4 Bruker AXS
    • N. Itagaki M. Kimura T. Sugahara Y. Iwabuchi Org. Lett. 2005 7 4185
    • (2005) Org. Lett. , vol.7 , pp. 4185
    • Itagaki, N.1    Kimura, M.2    Sugahara, T.3    Iwabuchi, Y.4
  • 26
    • 84977289324 scopus 로고
    • The coordination ability of (tertiary) amines to analogous Zn(salphen) structures was previously studied by Dalla Cort showing a large steric effect, see reference 3b. For a more recent account on this subject:
    • Blessing Acta Crystallogr., Sect. A: Found. Crystallogr. 1995 51 33
    • (1995) Acta Crystallogr., Sect. A: Found. Crystallogr. , vol.51 , pp. 33
    • Blessing1
  • 27
    • 68549120892 scopus 로고    scopus 로고
    • 4OH since this assembly proved to be more soluble than the one based on 1 under the applied conditions. The increase in intensity of the band related to p-nitro-phenolate anion formation (* ∼ 400 nm) was monitored. See for more experimental details:
    • E. C. Escudero-Adán J. Benet-Buchholz A. W. Kleij Eur. J. Inorg. Chem. 2009 3562
    • (2009) Eur. J. Inorg. Chem. , pp. 3562
    • Escudero-Adán, E.C.1    Benet-Buchholz, J.2    Kleij, A.W.3
  • 32
    • 34548618121 scopus 로고    scopus 로고
    • 1H NMR spectrum as a consequence of the non-symmetrical nature of 3. Nonetheless, the data are in line with those reported for the other assemblies, i.e., large upfield shifts are noted for the imine-H. Also, some de-assembled 3 may be present This compound crystallizes from deuterated acetone/benzene and affected the quality of the spectra. The data given are for the major component
    • E. C. Escudero-Adán J. Benet-Buchholz A. W. Kleij Inorg. Chem. 2007 46 7265
    • (2007) Inorg. Chem. , vol.46 , pp. 7265
    • Escudero-Adán, E.C.1    Benet-Buchholz, J.2    Kleij, A.W.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.