Ligation of substituted pyridines to metallosalphen complexes - crystallographic characterization of an unexpected four-component supramolecular assembly comprising a sterically demanding ligand

European Journal of Inorganic Chemistry

Volumn , Issue 24, 2009, Pages 3562-3568

  Escudero Adán, Eduardo C ^a   Benet Buchholz, Jordi ^a   Kleij, Arjan W ^a,b  

^a INSTITUTE OF CHEMICAL RESEARCH OF CATALONIA ICIQ   (Spain)

^b INSTITUCIÓ CATALANA DE RECERCA I ESTUDIS AVANÇATS ICREA   (Spain)

Author keywords

Coordination chemistry; N heterocyclic ligands; Salen; Supramolecular chemistry; Zinc

Indexed keywords

BINDING ENERGY; LIGANDS; SUPRAMOLECULAR CHEMISTRY; ULTRAVIOLET VISIBLE SPECTROSCOPY; X RAY DIFFRACTION ANALYSIS; ZINC COMPOUNDS;

CO-ORDINATION CHEMISTRIES; CRYSTALLOGRAPHIC CHARACTERIZATION; HETEROCYCLIC LIGANDS; N-HETEROCYCLIC; N-HETEROCYCLIC LIGAND; ORTHO-SUBSTITUTION; PYRIDINE LIGANDS; SALEN; ZINC; ZN IONS;

PYRIDINE;

EID: 68549120892     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200900401     Document Type: Article

References (33)

1. a) J. F. Larrow, E. N. Jacobsen, Top. Organomet. Chem. 2004, 6, 123-152;
2. b) P. G. Cozzi, Chem. Soc. Rev. 2004, 33, 410-421;
3. c) E. M. McGarrigle, D. G. Gilheany, Chem. Rev. 2005, 105, 1563-1602;
4. d) D. A. Atwood, M. J. Harvey, Chem. Rev. 2001, 101, 37-52;
5. e) D. J. Darensbourg, Chem. Rev. 2007, 107, 23882410;
6. f) T. Katsuki, Chem. Soc. Rev. 2004, 33, 437-444;
7. g) N. Madhavan, C. W. Jones, M. Week, Acc. Chem. Res. 2008, 41, 1153-1165.
8. a) S. J Wezenberg, A. W. Kleij, Angew. Chem. Int. Ed. 2008, 47, 2354-2364;
9. b) A. W. Kleij, Chem. Eur. J. 2008, 14, 1052010529.
10. a) P. D. Frischmann, J. Jiang, J. K.-H. Hui, J. J. Grzybowski, M. J. MacLachlan, Org. Lett. 2008, 10, 1255-1258;
11. b) C. Ma, A. Lo, A. Abdolmaleki, M. J. MacLachlan, Org. Lett. 2004, 6, 3841-3844.
12. S. J. Wezenberg, E. C. Escudero-Adán, J. Benet-Buchholz, A. W. Kleij, Org. Lett. 2008, 10, 3311-3314.
13. See for instance: G. H. Clever, Y. Söltl, H. Burks, W. Spahl, T. Carell, Chem. Eur. J. 2006, 12, 8708-8718.
14. a) P. Goyal, X. Zheng, M. Week, Adv. Synth, Catal. 2008, 350, 1816-1822;
15. b) C. Mazet, E.N. Jacobsen, Angew. Chem. Int. Ed. 2008, 47, 1762-1765.
16. a) A. W Kleij, M. Kuil, D. M. Tooke, A. L. Spek, J N. H. Reek, Inorg. Chem, 2007, 46, 5829-5831;
17. b) A. W Kleij, M. Kuil, M. Lutz, D. M. Tooke, A. L. Spek, P. C. J Kamer, P. W. N. M. van Leeuwen, J. N. H. Reek, Inorg. Chim. Actabn 2006, 359, 1807-1814;
18. c) E. C. Escudero-Adán, J. Benet-Buchholz, A. W. Kleij, Inorg. Chem. 2008, 47, 410-412;
19. d) S. J. Wezenberg, E. C. Escudero-Adán, J. Benet-Buchholz, A. W. Kleij, Inorg. Chem. 2008, 47, 2925-2927.
20. a.) A. W. Kleij, D. M. Tooke, M. Lutz, A. L. Spek, J. N. H. Reek, Eur. J. Inorg. Chem. 2005, 4626-4634;
21. b) S. Curreli, E. C. Escudero-Adán, J. Benet-Buchholz, A. W Kleij, J. Org. Chem. 2007, 72, 7018-7021;
22. S. Curreli, E. C. Escudero-Adán, J Benet-Buchholz, A. W. Kleij, Eur. J. Inorg. Chem. 2008, 2863-2873.
23. A. W Kleij, D.M. Tooke, M. Kuil, M. Lutz, A. L. Spek, J. N. H. Reek, Chem. Eur. J. 2005, 11, 4743-4750.
24. Recently we reported the isolation of four-coordinate Zn(salphen) species using a supramolecular strategy: E. C. Escudero-Adán, J Benet-Buchholz, A. W Kleij, Chem. Eur. J. 2009, 15, 4233-4237.
25. A. Dalla Cort, L. Mandolini, C. Pasquini, K. Rissanen, L. Russo, L. Schiaffino, New J. Chem. 2007, 31, 1633-1638.
26. See for an example: E. C. Escudero-Adán, J. Benet-Buchholz, A. W Kleij, Dalton Trotts. 2008, 734-737.
27. II-salphen complexes 1-5 is dynamic and thus sharp resonances are observed in all cases under the NMR conditions employed. Typically 10-20 mM solutions were examined.
28. For similar NMR features of Zn(salphen) complexes ligated by nicotine alkaloid donor ligands see: E. C. Escudero-Adán, J. Benet-Buchholz, A. W. Kleij, Inorg. Chem. 2008, 47, 4256-4263.
29. See for software details: A. P. Bisson, C. A. Hunter, J. C. Morales, Chem. Eur. J. 1998, 4, 845-851.
30. E. C. Escudero-Adán, J. Benet-Buchholz, A. W. Kleij, Inorg. Chem. 2007, 46, 7265-7267.
31. L. San Felices, E. Escudero-Adán, J. Benet-Buchholz, A. W. Kleij, Inorg. Chem. 2009, 48, 846-853.
32. K.-H. Chang, C.-C. Huang, Y.-H. Liu, Y.-H. Hu, P.-T. Chou, Y.-C. Lin, Dalton Trans. 2004, 1731-1738.
33. M.-A. Muñoz-Hernández, T. S. Keizer, S. Parkin, B. Patrick, D. A. Atwood, Organometallics 2000, 19, 4416-4421.