Description and molecular interpretations of anomalous compositional dependences of the glass transition temperatures in binary organic mixtures

Thermochimica Acta

Volumn 509, Issue 1-2, 2010, Pages 135-146

  Kalogeras, Ioannis M ^a,b  

^a UNIVERSITY OF ATHENS   (Greece)

^b UNIVERSITY OF WEST ATTICA   (Greece)

Author keywords

Blends; Excess free mixing volume; Glass transition; Hydrogen bonding; Miscibility

Indexed keywords

ASSOCIATING POLYMERS; BINARY POLYMER BLENDS; BINARY SYSTEMS; BLENDS; COMPOSITION DEPENDENCE; COMPOSITION DEPENDENCY; COMPOSITIONAL DEPENDENCE; CONTACT FORCES; CRYSTALLINE PHASIS; DRUG MOLECULES; EXCESS FREE MIXING VOLUME; FITTING PARAMETERS; FREE VOLUME EFFECTS; FUNCTIONAL FORMS; GLASS TRANSITION TEMPERATURE; GORDON-TAYLOR; HYDROGEN-BONDING; INTERACTION TERM; INTERMOLECULAR INTERACTIONS; INTERPOLYMER COMPLEXES; LOW MOLECULAR MASS; MISCIBILITY; MOLECULAR INTERPRETATION; NANOSCALE EFFECTS; ORGANIC MIXTURES; ORGANICS; PHYSICOCHEMICAL PHENOMENA; PRIME PARAMETERS; SECOND ORDERS; SEMI-EMPIRICAL; SEMI-QUANTITATIVE; SEMICRYSTALLINES; THREE-PARAMETER EQUATIONS; WEIGHT FRACTIONS;

BINARY MIXTURES; COMPLEXATION; GLASS; GLASS BONDING; HYDROGELS; HYDROGEN; MOLECULAR MASS; PLASTICIZERS; POLYMER BLENDS; SOLUBILITY; TEMPERATURE;

GLASS TRANSITION;

EID: 77956190588     PISSN: 00406031     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tca.2010.06.016     Document Type: Article

References (71)

1. J.D. Menczel, R.B. Prime, Thermal Analysis of Polymers, Fundamentals and Applications 2009 Wiley, Hoboken New Jersey pp. 1-688
2. G.B. McKenna, S.L. Simon, The glass transition-its measurement and underlying physics, in: S.Z.D. Cheng, (Ed.), Handbook of Thermal Analysis and Calorimetry, vol. 3, Applications to Polymers and Plastics, Elsevier, Amsterdam, 2002, pp. 49-110 [Chapter 2].
3. B. Wunderlich Thermodynamics and properties of nanophases Thermochim. Acta 492 2009 2 15
4. C.E. Corcione, and A. Maffezzoli Glass transition in thermosetting clay-nanocomposite polyurethanes Thermochim. Acta 485 2009 43 48
5. F.L. Jara, and A.M.R. Pilosof Glass transition temperature of protein/polysaccharide co-dried mixtures as affected by the extent and morphology of phase separation Thermochim. Acta 487 2009 65 73
6. K. Lewandowska Miscibility and thermal stability of poly(vinyl alcohol)/chitosan mixtures Thermochim. Acta 493 2009 42 48
7. W. Brostow, S. Deshpande, D. Pietkiewicz, S.R. Wisner, Accuracy of locating glass transitions: aging and gamma sterilization of vulcanized thermoplastic elastomers, E-polymers (2009) [art. no. 109].
8. F.X. Perrin, N. Chaoui, and A. Margaillan Effects of octa(3- chloroammoniumpropyl)octasilsesquioxane on the epoxy self-polymerization and epoxy-amine curing Thermochim. Acta 491 2009 97 102
9. C. Harrats, S. Thomas, G. Groeninckx, Micro- and Nanostructured Multiphase Polymer Blend Systems: Phase Morphology and Interfaces 2006 CRC Press 1 454
10. L.A. Utracki Polymer Alloys and Blends 1989 Hanser Publishers Munich
11. T.P. Lodge, E.R. Wood, and J.C. Haley Two calorimetric glass transitions do not necessarily indicate immiscibility: the case of PEO/PMMA J. Polym. Sci. Phys. 44 2006 756 763
12. M. Gordon, and J.S. Taylor Ideal copolymers and the second-order transitions of synthetic rubbers. I. Non-crystalline copolymers J. Appl. Chem. USSR 2 1952 493
13. T.G. Fox Bull. Am. Phys. Soc. 1 1956 123
14. P.R. Couchman, and F.E. Karasz Classical thermodynamic discussion of effect of composition on glass-transition temperatures Macromolecules 11 1978 117 119
15. P.R. Couchman Macromolecules Composition variation of glass-transition temperatures. 2. Application of thermodynamic theory to compatible polymer blends 11 1978 1156 1161
16. E. Jenckel, and R. Heusch Die ernidrigung der einfriertemperatur organischer glaser durch losungsmittel Kolloid Z. 130 1953 89 105
17. W. Brostow, R. Chiu, I.M. Kalogeras, and A. Vassilikou-Dova Prediction of glass transition temperatures: binary blends and copolymers Mater. Lett. 62 2008 3152 3155
18. T.K. Kwei The effect of hydrogen-bonding on the glass transition temperatures of polymer mixtures J. Polym. Sci. Part C: Polym. Lett. 22 1984 307 313
19. X. Lu, and R.A. Weiss Relationship between the glass-transition temperature and the interaction parameter of miscible binary polymer blends Macromolecules 25 1992 3242 3246
20. J.M.G. Cowie, M.T. Garay, D. Lath, and I.J. McEween Formation of polymer-polymer complexes and blends in the system poly(acrylic acid)-poly(vinyl methyl-ether) Br. Polym. J. 21 1989 81 85
21. P.D. Harding, PhD Thesis, Heriot-Watt University, Edinburgh, 1997.
22. M.-J. Brekner, A. Schneider, and H.-J. Cantow Makromol. Chem. 189 1988 2085
23. M.-J. Brekner, A. Schneider, and H.-J. Cantow Approach to the composition dependence of the glass-transition temperature of compatible polymer blends 1 Polymer 78 1988 78 85
24. Z. Yang, and C.D. Han Rheology of miscible polymer blends with hydrogen bonding Macromolecules 41 2008 2104
25. G. Kanig Zur theorie der glastemperatur von polymerhomologen, copolymeren und weichgemachten polymeren Kolloid Z-Z. Polym. 190 1963 1 16
26. H.A. Schneider Conformational entropy contributions to the glass transition of blends of miscible polymers J. Res. Natl. Inst. Stand. Technol. 102 1997 229 248
27. I.M. Kalogeras, and W. Brostow Glass transition temperatures in binary polymer blends J. Polym. Sci. Phys. 47 2009 80 95
28. J.H. Kim, B.R. Min, and Y.S. Kang Thermodynamic model of the glass transition behavior of miscible polymer blends Macromolecules 39 2006 1297 1299
29. A. Kovacs J. Adv. Polym. Sci. 3 1963 394
30. G. Braun, A. Kovacs, in: J.A. Prim (Ed.), Physics of Non-Crystalline Solids, North-Holland, Amsterdam, 1965.
31. A.V. Lesikar Glass-transition in organic halide alcohol mixtures J. Chem. Phys. 63 1975 2297 2302
32. P.C. Painter, J.F. Graf, and M.M. Coleman Effect of hydrogen-bonding on the enthalpy of mixing and the composition dependence of the glass-transition temperature in polymer blends Macromolecules 24 1991 5630 5638
33. P.R. Couchman Interaction strength, nonrandom mixing, and the compositional variation of glass-transition temperatures Macromolecules 24 1991 5772 5774
34. R. Pinal Entropy of mixing and the glass transition of amorphous mixtures Entropy 10 2008 207 223
35. K. ElMiloudi, S. Djadoun, N. Sbirrazzuoli, and S. Geribaldi Miscibility and phase behavior of binary and ternary homoblends of poly(styrene-co-acrylic acid), poly(styrene-co-N,N-dimethylacrylamide) and poly(styrene-co-4- vinylpyridine) Thermochim. Acta 483 2009 49
36. K. ElMiloudi, and S. Djadoun A thermodynamic analysis of specific interactions in homoblends of poly(styrene-co-4-vinylpyridine) and poly(styrene-co-methacrylic acid) J. Polym. Sci. Phys. 47 2009 923 931
37. A.S.H. Hamou, K. ElMiloudi, and S. Djadoun A thermodynamic analysis of specific interactions in blends of poly(styrene-co-N,N-dimethylacrylamide) and poly(styrene-co-acrylic acid). Screening and self-association effects J. Polym. Sci. Phys. 47 2009 2074 2082
38. N. Haddadine-Rahmoun, F. Amrani, V. Arrighi, and J.M.G. Cowie Interpolymer complexation and thermal behavior of poly(styrene-co-maleic acid)/poly(vinyl pyrrolidone) mixtures Thermochim. Acta 475 2008 25 32
39. R. Thongtan, Morphological study of compatibilization of immiscible polymer blends using a functionalized block copolymer, MSc Thesis, University of Akron, 2006.
40. C.M. Roland, and R. Casalini Dynamics of poly(cyclohexyl methacrylate): neat and in blends with poly(α-methylstyrene) Macromolecules 40 2007 3631 3639
41. A. Alegría, I. Tellería, and J. Colmenero Miscibility and dielectric α-relaxation of PECH/PVME polymer blends J. Non-Cryst. Solids 172 1994 961 965
42. M. Maldonado-Santoyo, L.C. Cesteros, I. Katime, and S.M. Nuno-Donlucas Miscible blends of poly(vinyl phenyl ketone hydrogenated) and poly(styrene-co-4-vinylpyridine) Polymer 45 2004 5591 5596
43. C.M. Roland, P.G. Santangelo, K.L. Ngai, and G. Meier Relaxation dynamics in poly(methylphenylsiloxane), 1,1-bis(p-methoxyphenyl)cyclohexane, and their mixtures Macromolecules 26 1993 6164 6170
44. R. Casalini, P.G. Santangelo, and C.M. Roland Anomalous behavior in blends of a polychlorinated biphenyl with polystyrene oligomer investigated by mechanical and dielectric spectroscopy J. Phys. Chem. B 106 2002 11492 11494
45. P.G. Santangelo, K.L. Ngai, and C.M. Roland Anomalous relaxation in polychlorinated biphenyl polybutadiene mixtures Macromolecules 27 1994 3859 3863
46. C.M. Roland Mechanical and dielectric spectroscopy of aroclor, 1,2 polybutadiene, and their mixtures Macromolecules 28 1995 3463 3467
47. C.M. Roland, P.G. Santangelo, Z. Baram, and J. Runt Segmental relaxation in blends of polychloroprene and epoxidized polyisoprene Macromolecules 27 1994 5382 5386
48. A.K. Rizos, and K.L. Ngai Anomalous reduction of solvent friction in chlorinated biphenyl solutions of 1,2-polybutadiene Phys. Rev. B 46 1992 8126 8131
49. V. Abetz, G. Müller, R. Stadler, and S. Schlick The glass-transition of mixtures of polystyrene with alkyl-terminated oligostyrene-experimental evidence for microphase separation in a polymer blend Macromol. Chem. Phys. 196 1995 3845 3857
50. R.J. Babu, W. Brostow, I.M. Kalogeras, and S. Sathigari Glass transitions in binary + polymer systems Mater. Lett. 63 2009 2666
51. Z. Yang, Rheology of miscible polymer blends with hydrogen bonding, PhD Thesis, University of Akron, 2007.
52. P.J. Flory Thermodynamics of heterogeneous polymers and their solutions J. Chem. Phys. 12 1944 425 439
53. A. Habi, and S. Djadoun Miscibility and thermal behavior of poly(styrene-co-methacrylic acid)/poly(isobutyl methacrylate-co-4-vinylpyridine) mixtures Thermochim. Acta 469 2008 1 7
54. A. Habi, and S. Djadoun Study of miscibility of poly(styrene-co- methacrylic acid) with copolymers of isobutyl methacrylate containing a basic comonomer Eur. Polym. J. 35 1999 483 489
55. M. Bolsinger, and H.A. Schneider Influence of spacer length between interacting group and polymer backbone on the glass-transition temperature of electron-donor electron-acceptor blends Macromol. Chem. Phys. 195 1994 2683 2692
56. H.A. Schneider, and M.-J. Breckner Thermodynamic aspects of the glass-transition in the compatible blend of poly(styrene)-poly(vinylmethylether) Polym. Bull. 14 1985 173 178
57. H.A. Schneider, and B. Leikauf Glass-transition temperatures of PVME-PS blends: influence of the molecular-weight of PS Thermochim. Acta 114 1987 165 170
58. L.J. An, D.Y. He, J.K. Jing, Z. Wang, D. Yu, Z. Jiang, and R. Ma Effects of molecular weight and interaction parameter on the glass transition temperature of polystyrene mixtures and its blends with polystyrene/poly(2,6- dimethyl-p-phenylene oxide) Eur. Polym. J. 33 1997 1523
59. T.K. Kwei, and H.L. Frisch Interaction parameter in polymer mixtures Macromolecules 11 1978 1267 1271
60. D.J. Hourston, M. Song, Applications of modulated temperature differential scanning calorimetry to polymer blends and related systems, in: M. Reading, D.J. Hourston (Eds.), Theory and Practice of Modulated Temperature Differential Scanning Calorimetry, Springer, 2006, pp. 161-216 [Chapter 3].
61. N. Bouslah, N. Haddadine, F. Amrani, and R. Hammachin Comparison of specific interactions in P4VP/PSCA and PSVP/PSCA blends and complexes J. Appl. Polym. Sci. 108 2008 3256 3261
62. L.G. Parada, L.C. Cesteros, E. Meaurio, and I. Kattime Miscibility and specific interactions in blends of poly(vinyl acetate-co-vinyl alcohol) with poly(ethyloxazoline) Macromol. Chem. Phys. 198 1997 2505 2517
63. N. Hameed, and Q. Guo Natural wool/cellulose acetate blends generated from ionic liquid 1-butyl-3-methylimidazolium chloride Carbohydr. Polym. 78 2009 999 1004
64. S. Saeki, J.M.G. Cowie, and I.J. McEwen The effect of molecular-weight and casting solvent on the miscibility of polystyrene/poly(α-methyl styrene) blends Polymer 24 1983 60 64
65. F.-C. Chiu, K. Min, and Miscibility Morphology and tensile properties of vinyl chloride polymer and poly(ε-caprolactone) blends Polym. Int. 49 2000 223 234
66. K. Khougaz, and S.-D. Clas Crystallization inhibition in sold dispersions of MK-0591 and poly(vinylpyrrolidone) blends J. Pharm. Sci. 89 2000 1325 1334
67. C. Wiranidchapong, T. Rades, P. Kulvanich, and I.G. Tucker Method of preparation does not affect the miscibility between steroid hormone and methacrylate Thermochim. Acta 485 2009 57 64
68. T. Matsumoto, and G. Zografi Physical properties of solid molecular dispersions of indomethacin with poly(vinylpyrrolidone) and poly(vinylpyrrolidone-co-vinylacetate) in relation to indomethacin crystallization Pharm. Res. 16 1999 1722 1728
69. S.L. Shamblin, E.Y. Huang, and G. Zografi The effects of co-lyophilized polymeric additives on the glass transition and crystallization of amorphous sucrose J. Thermal Anal. 47 1996 1567 1569
70. S.L. Shamblin, L.S. Taylor, and G. Zografi Mixing behavior of colyophilized binary systems J. Pharm. Sci. 87 1998 694 701
71. F. Qian, J. Huang, and M.A. Hussain Drug-polymer solubility and miscibility: stability consideration and practical challenges in amorphous solid dispersion development J. Pharm. Sci. 99 2010 2941 2947