Seven-coordinate rhenium(III) complexes with a labile coordination site assembled on indium-doped tin oxide (ITO) electrodes: Catalytic reduction of dioxygen to hydrogen peroxide

Chemistry Letters

Volumn 39, Issue 9, 2010, Pages 986-988

  Sugimoto, Hideki ^a   Tano, Hiroyuki ^b   Miyake, Hiroyuki ^b   Itoh, Shinobu ^a  

^a OSAKA UNIVERSITY   (Japan)

^b Osaka Prefecture University   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 77956163304     PISSN: 03667022     EISSN: 13480715     Source Type: Journal    
DOI: 10.1246/cl.2010.986     Document Type: Article

References (31)

1. a) S. Welter, K. Brunner, J. W. Hofstraat, L. D. Cola, Nature 2003, 421, 54.
2. b) O. S. Wenger, B. S. Leigh, R. M. Villahermosa, H. B. Gray, J. R. Winkler, Science 2005, 307, 99.
3. c) S. H. Choi, B.-S. Kim, C D. Frisbie, Science 2008, 320, 1482.
4. R. Argazzi, C A. Bignozzi, T. A. Heimer, G. J. Meyer, Inorg. Chem, 1997, 36, 2.
5. T. Kurita, Y. Nishimori, F. Toshimitsu, S. Muratsugu, S. Kume, H. Nishihara, J. Am. Chem. Soc. 2010, 132, 4524.
6. K. Terada, K. Kobayashi, M. Haga, Dalton Trans. 2008, 4846.
7. M. K. Ludlow, A. V. Soudackov, S. Hammes-Schiffer, J. Am. Chem. Soc. 2010, 132, 1234.
8. Y. Nishimori, K. Kanaizuka, T. Kurita, T. Nagatsu, Y. Segawa, F. Toshimitsu, S. Muratsugu, M. Utsuno, S. Kume, M. Murata, H. Nishihara, Chem. Asian J. 2009, 4, 1361.
9. a) T. Wada, K. Tsuge, K. Tanaka, Inorg. Chem. 2001, 40, 329.
10. b) H. Sugimoto, H. Tsukube, K. Tanaka, Eur. J. Inorg. Chem, 2004, 4550.
11. c) I. Takahashi, T. Inomata, Y. Funahashi, T. Ozawa, H. Masuda, Chem.-Eur. J. 2007, 13, 8007.
12. d) T. Inomata, K. Shinozaki, Y. Hayashi, H. Arii, Y. Funahashi, T. Ozawa, H. Masuda, Chem. Commun. 2008, 392.
13. e) W. Zhou, Y. Zhang, M. Abe, K. Uosaki, M. Osawa, Y. Sasaki, S. Ye, Langmuir 2008, 24, 8027.
14. f) J. J. Concepción, J. W. Juras, P. G. Hoertz, T. J. Meyer, Angew. Chem, Int. Ed. 2009, 48, 9473.
15. a) M. Stebler, A. Gutierrez, A. Ludi, H.-B. Burgi, Inorg. Chem, 1987, 26, 1449.
16. b) L. E. Helberg, S. D. Orth, M. Sabat, W. D. Harman, Inorg. Chem, 1996, 35, 5584.
17. K. Wang, M. Haga, M. D. Hossain, H. Shindo, K. Hasebe, H. Monjushiro, Langmuir 2002, 18, 3528.
18. H. Wolpher, S. Sinha, J. Pan, A. Johansson, M. J. Lundqvist, P. Persson, R. Lomoth, J. Bergquist, L. Sun, V. Sundström, B. Akermark, T. Polívka, Inorg. Chem. 2007, 46, 638.
19. 3): δ 8.84 (d, 2H), 8.74 (d, 2H), 8.61 (d, 2H), 7.88 (td, 2H), 7.35 (ddd, 2H), 3.87 (d, 6H).
20. 2O: C, 39.45; H, 3.31; N, 6.00%. Found: C, 39.19; H, 3.35; N, 6.18%.
21. 3CN): δ 9.54 (ddd, 2H), 9.32-9.18 (m, 4H), 8.75 (dd, 2H), 8.22-8.09 (m, 4H), 7.52 (dd, 2H), 7.14-7.07 (m, 2H), 7.05-6.95 (m, 4H), 3.99 (ddd, 12H).
22. 2 = 18.05.
23. -1).
24. -1).
25. 4OH and thoroughly rinsed with purified water. After heating at 120 °C for 60 min, the electrode was cooled and stored under dry dinitrogen.
26. Me and size of the anions were neglected.
27. Pc was employed for the plot.
28. a value would be higher.
29. J. Rail, F. Weingart, D. M. Ho, M. J. Heeg, F. Tisato, E. Deutsch, Inorg. Chem. 1994, 33, 3442.
30. S. Fukuzumi, S. Kuroda, T. Tanaka, J. Am. Chem. Soc. 1985, 107, 3020.
31. Supporting Information is available electronically on the CSJ-Journal Web site, http://www.csj.jp/journals/chem-lett/ index.html.