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Preparation of the Ir(I) complex followed a published procedure (28). 2,6-Dichloro-1,4-benzoquinone (SigmaAldrich) was recrystallized from methanol before use. All solvents were high-purity grade; they were dried and distilled before use.
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29
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11844258384
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note
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2 (30) and 2,6-dichloro-1,4-benzoquinone (31).
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31
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11844278658
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note
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2 luminescence (>600 nm) and 2,6-dichloro-1,4- benzoquinone absorption (<520 nm).
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40
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11844301749
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note
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Fe.
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41
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11844288493
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note
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-1, n = 5.
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44
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84913602953
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47
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11844282299
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note
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We thank J. Kim, J. Lee, and J. Magyar for several helpful discussions. Supported by BP, the NSF (grant no. CHE-0078809), and the Arnold and Mabel Beckman Foundation. O.S.W. acknowledges a postdoctoral fellowship from the Swiss National Science Foundation and B.S.L, a graduate fellowship from the Parsons Foundation.
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