Coordination Chemistry of Low-Valent Rhenium Polypyridyl Complexes: Synthesis, Reactivity, and Electrochemistry

Inorganic Chemistry

Volumn 35, Issue 19, 1996, Pages 5584-5594

  Helberg, Lisa E ^a   Orth, Stephen D ^a   Sabat, Michal ^a   Harman, W Dean ^a  

^a UNIVERSITY OF VIRGINIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000025504     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic960001l     Document Type: Article

References (69)

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11. For a few recent examples: Christensen, P.; Hamnett, A.; Muir, A. V. G.; Timney, J. A. J. Chem. Soc., Dalton Trans. 1992, 9, 1455. Yoshida, T.; Tsutsumida, K.; Teratain, S.; Yasufuku, K.; Kaneko, M. J. Chem. Soc., Chem. Commun. 1993, 7, 631. Thornton, N. B.; Schanze, K. S. Inorg. Chem. 1993, 32, 4994. Westmoreland, T. D.; Schanze, K. S.; Neveaux, P. E., Jr.; Danielson, E.; Sullivan, B. P.; Chen, P.; Meyer, T. J. Inorg. Chem. 1985, 24, 2596. Schanze, K. S.; MacQueen, D. B.; Perkins, T. A.; Cabana, L. A. Chord. Chem. Rev. 1993, 122, 63.
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26. Harman, W. D.; Sekine, M.; Taube, H. J. Am. Chem. Soc. 1988, 110, 5725. Cordone, R.; Harman, W. D.; Taube, H. J. Am. Chem. Soc. 1989, 111, 5969. Kopach, M. E.; Gonzalez, J.; Harman, W. D. J. Am. Chem. Soc. 1991, 113, 8972. Kopach, M. E.; Kelsh, L. P.; Stork, K. C.; Harman, W. D. J. Am. Chem. Soc. 1993, 115, 5322. Hodges, L. M.; Koontz, J. I.; Gonzalez, J.; Myers, W. H.; Harman, W. D. J. Org. Chem. 1993, 58, 4788. Gonzalez, J.; Sabat, M.; Harman, W. D. J. Am. Chem. Soc. 1993, 115, 8857. Chen, H.; Hodges, L. M.; Lui, R.; Stevens, W. C., Jr.; Sabat, M.; Harman, W. D. J. Am. Chem. Soc. 1994, 116, 5499.
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28. Harman, W. D.; Sekine, M.; Taube, H. J. Am. Chem. Soc. 1988, 110, 5725. Cordone, R.; Harman, W. D.; Taube, H. J. Am. Chem. Soc. 1989, 111, 5969. Kopach, M. E.; Gonzalez, J.; Harman, W. D. J. Am. Chem. Soc. 1991, 113, 8972. Kopach, M. E.; Kelsh, L. P.; Stork, K. C.; Harman, W. D. J. Am. Chem. Soc. 1993, 115, 5322. Hodges, L. M.; Koontz, J. I.; Gonzalez, J.; Myers, W. H.; Harman, W. D. J. Org. Chem. 1993, 58, 4788. Gonzalez, J.; Sabat, M.; Harman, W. D. J. Am. Chem. Soc. 1993, 115, 8857. Chen, H.; Hodges, L. M.; Lui, R.; Stevens, W. C., Jr.; Sabat, M.; Harman, W. D. J. Am. Chem. Soc. 1994, 116, 5499.
29. Harman, W. D.; Sekine, M.; Taube, H. J. Am. Chem. Soc. 1988, 110, 5725. Cordone, R.; Harman, W. D.; Taube, H. J. Am. Chem. Soc. 1989, 111, 5969. Kopach, M. E.; Gonzalez, J.; Harman, W. D. J. Am. Chem. Soc. 1991, 113, 8972. Kopach, M. E.; Kelsh, L. P.; Stork, K. C.; Harman, W. D. J. Am. Chem. Soc. 1993, 115, 5322. Hodges, L. M.; Koontz, J. I.; Gonzalez, J.; Myers, W. H.; Harman, W. D. J. Org. Chem. 1993, 58, 4788. Gonzalez, J.; Sabat, M.; Harman, W. D. J. Am. Chem. Soc. 1993, 115, 8857. Chen, H.; Hodges, L. M.; Lui, R.; Stevens, W. C., Jr.; Sabat, M.; Harman, W. D. J. Am. Chem. Soc. 1994, 116, 5499.
30. Harman, W. D.; Sekine, M.; Taube, H. J. Am. Chem. Soc. 1988, 110, 5725. Cordone, R.; Harman, W. D.; Taube, H. J. Am. Chem. Soc. 1989, 111, 5969. Kopach, M. E.; Gonzalez, J.; Harman, W. D. J. Am. Chem. Soc. 1991, 113, 8972. Kopach, M. E.; Kelsh, L. P.; Stork, K. C.; Harman, W. D. J. Am. Chem. Soc. 1993, 115, 5322. Hodges, L. M.; Koontz, J. I.; Gonzalez, J.; Myers, W. H.; Harman, W. D. J. Org. Chem. 1993, 58, 4788. Gonzalez, J.; Sabat, M.; Harman, W. D. J. Am. Chem. Soc. 1993, 115, 8857. Chen, H.; Hodges, L. M.; Lui, R.; Stevens, W. C., Jr.; Sabat, M.; Harman, W. D. J. Am. Chem. Soc. 1994, 116, 5499.
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35. 2+ (6) will be obtained as a side product in the formation of 3.
36. +.
37. The reaction does not proceed as cleanly or in as high yield as the reaction from the benzil complex (2).
38. 6.
39. 1H NMR spectrum.
40. 6, or other ligands such as py or bpy does not proceed cleanly.
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42. 6 as observed by the rapid formation of TlCl; however, no characterizable products could be isolated from this reaction.
43. As an example, see: ref 6 and references cited therein.
44. 3 (1).
45. 2 (10) since, when 9 is taken under the same reaction conditions used in the synthesis of 10, only unreacted starting material is observed.
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47. 3+ complex is reported in reference 11.
48. p.c (III/II) = -0.26 V vs NHE.
49. p.c (III/II) = -0.20 V vs NHE.
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