Cyclopentadienyl molybdenum dicarbonyl η3-allyl complexes as catalyst precursors for olefin epoxidation. Crystal structures of Cp′Mo(CO)2(η3-C3H5) (Cp′ = η5-C5H4Me, η5-C5Me5)

Journal of Organometallic Chemistry

Volumn 695, Issue 21, 2010, Pages 2311-2319

  Neves, Patrícia ^a   Pereira, Cláudia C L ^a,b   Almeida Paz, Filipe A ^a   Gago, Sandra ^a   Pillinger, Martyn ^a   Silva, Carlos M ^a   Valente, Anabela A ^a   Romão, Carlos C ^c,d   Gonalves, Isabel S ^a  

^a UNIVERSITY OF AVEIRO   (Portugal)

^b INSTITUTO TECNOLÓGICO E NUCLEAR   (Portugal)

^c INSTITUTO DE TECNOLOGIA QUÍMICA E BIOLÓGICA   (Portugal)

^d Alfama   (Portugal)

Author keywords

Cyclopentadienyl ligands; Homogeneous catalysis; Molybdenum; Olefin epoxidation; Oxidative decarbonylation

Indexed keywords

1-OCTENE; ALLYL COMPLEXES; AQUEOUS SOLUTIONS; CATALYST PRECURSORS; CATALYST RECYCLING; CIS-CYCLOOCTENE; COMPLEX 1; CYCLODODECENE; CYCLOPENTADIENYL LIGANDS; CYCLOPENTADIENYLS; DICHLOROETHANE; EPOXIDE SELECTIVITY; HOMOGENEOUS CATALYSIS; OLEFIN EPOXIDATION; ORDER OF MAGNITUDE; OXIDATIVE DECARBONYLATION; RING SUBSTITUENTS; SELECTIVE EPOXIDATION; TERT-BUTYLHYDROPEROXIDE; TURNOVER FREQUENCY;

CATALYSIS; CATALYSTS; IONIC LIQUIDS; LIGANDS; MOLYBDENUM; OLEFINS; OXIDANTS; PARAFFINS; REACTION RATES; SOLUTIONS; X RAY DIFFRACTION;

MOLYBDENUM COMPOUNDS;

EID: 77956056329     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2010.07.001     Document Type: Article

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