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-1 as determined in benzene solution, the time the molecules would require to reach thermal equilibrium of the two forms would certainly be much longer than the time actually available to them. This means either that the isomerisation barrier almost vanishes in the gas phase or - more likely - that the solid, having been collected in the vessel by condensation of gaseous 2, already contained both isomers in almost equal proportions. The second possibility is difficult to prove, however, since it has not been possible to resolve the distinct carbonyl bands of the two isomers in the vibrational spectra of solid samples.
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