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Volumn , Issue 10, 2001, Pages 2613-2618

The Photochemistry of [CpMo(CO)3(η1-C3H5)] in frozen gas matrices at 10 K and the behaviour of [CpMo(CO)2(η3-C3H5)] isomers in different media

Author keywords

Allyl ligands; Matrix isolation; Molybdenum; Photochemistry

Indexed keywords

CHLORINE COMPOUNDS; DENSITY FUNCTIONAL THEORY; IRRADIATION; ISOMERS; PHOTOLYSIS; PLANTS (BOTANY); SOLVENTS; TEMPERATURE;

EID: 0034795993     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0682(200109)2001:10<2613::AID-EJIC2613>3.0.CO;2-6     Document Type: Article
Times cited : (14)

References (31)
  • 10
    • 0002626017 scopus 로고
    • Spectroscopy of Matrix Isolated Species
    • (Eds.: R. J. H. Clark, R. E. Hester), Wiley, Chichester
    • M. J. Almond, A. J. Downs, Spectroscopy of Matrix Isolated Species (Eds.: R. J. H. Clark, R. E. Hester), Advances in Spectroscopy, Vol. 17, Wiley, Chichester, 1989;
    • (1989) Advances in Spectroscopy , vol.17
    • Almond, M.J.1    Downs, A.J.2
  • 14
    • 84942751414 scopus 로고
    • (Eds.: G. Wilkinson, F. G. A. Stone, E. W. Abel), Pergamon Press, Oxford
    • B. E. Mann, Comprehensive Organometallic Chemistry (Eds.: G. Wilkinson, F. G. A. Stone, E. W. Abel), Pergamon Press, Oxford, 1982, Vol. 3, p. 89.
    • (1982) Comprehensive Organometallic Chemistry , vol.3 , pp. 89
    • Mann, B.E.1
  • 21
    • 0002872527 scopus 로고
    • m-1 compounds (plus free CO) and also for the reverse type of reactivity. See for instance: [15a] R. B. Hitam, K. A. Mahmoud, A. J. Rest, Coord. Chem. Rev. 1984, 55, 1-29.
    • (1984) Coord. Chem. Rev. , vol.55 , pp. 1-29
    • Hitam, R.B.1    Mahmoud, K.A.2    Rest, A.J.3
  • 30
    • 85163235373 scopus 로고    scopus 로고
    • note
    • -1 as determined in benzene solution, the time the molecules would require to reach thermal equilibrium of the two forms would certainly be much longer than the time actually available to them. This means either that the isomerisation barrier almost vanishes in the gas phase or - more likely - that the solid, having been collected in the vessel by condensation of gaseous 2, already contained both isomers in almost equal proportions. The second possibility is difficult to prove, however, since it has not been possible to resolve the distinct carbonyl bands of the two isomers in the vibrational spectra of solid samples.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.