Rhodium(I)-catalyzed hydroacylation/cycloisomerization cascade reaction: Application to the construction of the tricyclic core of guanacastepenes

Synthesis

Volumn , Issue 17, 2010, Pages 2884-2892

  Oonishi, Yoshihiro ^a   Taniuchi, Ai ^a   Sato, Yoshihiro ^a  

^a HOKKAIDO UNIVERSITY   (Japan)

Author keywords

aldehydes; cascade reactions; dienes; guanacastepenes; rhodium

Indexed keywords

CARBOCYCLES; CASCADE REACTIONS; CYCLOISOMERIZATIONS; DIENES; GUANACASTEPENES; HYDROACYLATION; STEREOSELECTIVE MANNER;

ALDEHYDES; CATALYSIS; RHODIUM;

OLEFINS;

5 [2 [(TERT BUTYLDIMETHYLSILOXY)METHYL]CYCLOHEXYL]PENTA 2,4 DIEN 1 OL; DIMETHYL 1 ALLYL 4 OXO 3,3A,4,4A,5,6,7,8,8A,10A DECAHYDRO 1H BENZO[F]AZULENE 2,2 DICARBOXYLATE; DIMETHYL 2 [BUTA 1,3 DIENYL] 2 [3 (1 OXOOCTAHYDROINDEN 2 YL)ALLYL]MALONATE; DIMETHYL 2 [BUTA 1,3 DIENYL] 2 [5 (2 FORMYLCYCLOHEXYL)PENTA 2,4 DIENYL]MALONATE; DIMETHYL 2 [BUTA 1,3 DIENYL] 2 [5 [2 [(HYDROXYMETHYL)]CYCLOHEXYL]PENTA 2,4 DIENYL]MALONATE; DIMETHYL 2 [BUTA 1,3 DIENYL] 2 [5 [2 [(TERT BUTYLDIMETHYLSILOXY)METHYL]CYCLOHEXYL]PENTA 2,4 DIENYL]MALONATE; DITERPENOID; ETHYL 3 [2 [(TERT BUTYLDIMETHYLSILOXY)METHYL]CYCLOHEXYL]ACRYLATE; ETHYL 5 [2 [(TERT BUTYLDIMETHYLSILOXY)METHYL]CYCLOHEXYL]PENTA 2,4 DIENOATE; GUANACASTEPENE; RHODIUM; TERPENOID DERIVATIVE; UNCLASSIFIED DRUG;

ACYLATION; ARTICLE; CATALYSIS; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; ISOMERIZATION; SYNTHESIS;

EID: 77956046981     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0030-1258184     Document Type: Article

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