2-aminopyrimidine-silver(I) based hybrid organic polymers: Self-assembly and phase transitions of a novel class of electronic material

Chemistry of Materials

Volumn 22, Issue 16, 2010, Pages 4749-4755

  Stoll, Ion ^a   Brockhinke, Regina ^a   Brockhinke, Andreas ^a   Böttcher, Markus ^a   Koop, Thomas ^a   Stammler, Hans Georg ^a   Neumann, Beate ^a   Niemeyer, Andrea ^a   Hütten, Andreas ^a   Mattay, Jochen ^a  

^a BIELEFELD UNIVERSITY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

2-AMINOPYRIMIDINE; ABSORBANCES; COUNTERIONS; CRYSTALLINE FILMS; ELECTRICAL CONDUCTANCE; ELECTRONIC MATERIALS; EMISSIVE STATE; OPTOELECTRICAL PROPERTIES; ORGANIC SEMICONDUCTOR; PARENT COMPOUNDS; POLYMER STRANDS; SMALL MOLECULES; SOLID-STATE ABSORPTION; SOLUTION-PROCESSING; SOLVENT MOLECULES; TRIFLATES;

CONJUGATED POLYMERS; DIFFERENTIAL SCANNING CALORIMETRY; FILLED POLYMERS; PHASE TRANSITIONS; SELF ASSEMBLY; SILVER; SILVER COMPOUNDS; SINGLE CRYSTALS; SOLVENTS;

ORGANIC POLYMERS;

EID: 77955686265     PISSN: 08974756     EISSN: 15205002     Source Type: Journal    
DOI: 10.1021/cm101193g     Document Type: Article

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41. Because of the anisotropy of the conducting material, a four probe measurement was not applied. The I-V characteristics curve in the darkness is unchanged in reference to the bulb lighted sample. Therefore, since the conducting properties are strongly determined by the Schottky-contact resistance at the semiconductor-metal interface, we also do not derive any physical data from these experiments at this point, and we do not discuss a participation of the photo excited state in the charge transport mechanism based on these preliminary experiments. The characterization of the electrical conductivity requires more experimental and theoretical work, and therefore this preliminary conductivity experiment proves only the general conductance and the applicability for device fabrication of the material.