[An(H2O)9](CF3SO3)3 (An=U-Cm, Cf): Exploring their stability, structural chemistry, and magnetic behavior by experiment and theory

Angewandte Chemie - International Edition

Volumn 49, Issue 36, 2010, Pages 6343-6347

  Apostolidis, Christos ^b   Schimmelpfennig, Bernd ^a   Magnani, Nicola ^b   Lindqvist Reis, Patric ^a   Walter, Olaf ^a   Sykora, Richard ^c   Morgenstern, Alfred ^b   Colineau, Eric ^b   Caciuffo, Roberto ^b   Klenze, Reinhardt ^a   Haire, Richard G ^d   Rebizant, Jean ^b   Bruchertseifer, Frank ^b   Fanghänel, Thomas ^b  

^a KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

^b JOINT RESEARCH CENTRE   (Italy)

^c UNIVERSITY OF SOUTH ALABAMA   (United States)

^d OAK RIDGE NATIONAL LABORATORY   (United States)

Author keywords

Actinides; Coordination modes; Hydrates; Lanthanides

Indexed keywords

COORDINATE GEOMETRY; COORDINATION MODES; ELECTROSTATIC BONDING; LANTHANIDES; MAGNETIC BEHAVIOR; STRUCTURAL CHEMISTRY; TRIFLATES;

ACTINIDES; CRYSTAL STRUCTURE; HYDRATES; HYDRATION; NEUTRON DETECTORS; RARE EARTH ELEMENTS; X RAY DIFFRACTION;

DENSITY FUNCTIONAL THEORY;

EID: 77955461768     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201001077     Document Type: Article

References (67)

1. M. Ephritikhine, Dalton Trans. 2006, 2501-2516
2. W. J. Evans, S. A. Kozimor, Coord. Chem. Rev. 2006, 250, 911-935.
3. 3+ ions may to some extent participate in bonding with soft donor ligands; see, A. J. Gaunt, B. L. Scott, M. P. Neu, Angew. Chem. 2006, 118, 1668-1671
4. Angew. Chem. Int. Ed. 2006, 45, 1638-1641
5. L. Karmazin, M. Mazzanti, J. Pécaut, Chem. Commun. 2002, 654-655
6. J.-C. Berthet, Y. Miquel, P. B. Iveson, M. Nierlich, P. Thuéry, Ch. Madic,M. Ephritikhine, J. Chem. Soc. Dalton Trans. 2002, 3265-3272.
7. T. Cantat, C. R. Graves, B. L. Scott, J. L. Kiplinger, Angew. Chem. 2009, 121, 3735-3738
8. Angew. Chem. Int. Ed. 2009, 48, 3681-3684
9. O. P. Lam, C. Anthon, K. Mayer, Dalton Trans. 2009, 9677-9691
10. O. T. Summerscales, G. F. N. Cloke, P. B. Hitchcock, J. C. Green, N. Hazari, Science 2006, 311, 829-831
11. I. Castro-Rodriguez, H. Nakai, L. N. Zakharov, A. L. Rheingold, K. Meyer, Science 2004, 305, 1757-1759
12. I. Castro-Rodriguez, H. Nakai, P. Gantzel, L. N. Zakharov, A. L. Rheingold, K. Meyer, J. Am. Chem. Soc. 2003, 125, 15734-15735.
13. Z. Kolarik, Chem. Rev. 2008, 108, 4208-4252.
14. J. H. Matonic, B. L. Scott, M. P. Neu, Inorg. Chem. 2001, 40, 2638-2639
15. P. Lindqvist-Reis, C. Apostolidis, J. Rebizant, A. Morgenstern, R. Klenze, O. Walter, T. Fanghänel, R. G. Haire, Angew. Chem. 2007, 119, 937-940
16. Angew. Chem. Int. Ed. 2007, 46, 919-922
17. S. Skanthakumar, M. R. Antonio, R. E. Wilson, L. Soderholm, Inorg. Chem. 2007, 46, 3485-3491.
18. E. Galbis, J. Hernández-Cobos, C. den Auwer, C. Le Naour, D. Guillaumont, E. Simoni, R. R. Pappalardo, E. Sánchez Marcos, Angew. Chem. 2010, 122, 3899-3903
19. Angew. Chem. Int. Ed. 2010, 49, 3811-3815
20. B. Brendebach, N. L. Banik, M. Marquardt, J. Rothe, M. A. Denecke, H. Geckeis, Radiochim. Acta 2009, 97, 701-708
21. T. Stumpf, C. Hennig, A. Bauer, M. A. Denecke, T. Fanghänel, Radiochim. Acta 2004, 92, 133-138
22. M. R. Antonio, C.W. Williams, L. Soderholm, Radiochim. Acta 2002, 90, 851-856
23. P. G. Allen, J. J. Bucher, D. K. Shuh, N. M. Edelstein, I. Craig, Inorg. Chem. 2000, 39, 595-601
24. R. Revel, C. Den Auwer, C. Madic, F. David, B. Fourest, S. Hubert, J.-F. Le Du, L. R. Morss, Inorg. Chem. 1999, 38, 4139-4141.
25. E. N. Rizkalla, G. R. Choppin in Handbook on the Physics and Chemistry of Rare Earths. Lanthanides/Actinides: Chemistry, Vol. 18 (Eds.: K. A. Gschneidner, Jr., L. Eyring, G. R. Choppin, G. H. Lander), Elsevier Science, Amsterdam, 1994, pp. 529-558.
26. J. M. Harrowfield, D. L. Kepert, J. M. Patrick, A. H. White, Aust. J. Chem. 1983, 36, 483-492
27. C. O. Paiva Santos, E. E. Castellano, L. C. Machado, G. Vicentini, Inorg. Chim. Acta 1985, 110, 83-86
28. A. Chatterjee, E. N. Maslen, K. J. Watson, Acta Crystallogr. Sect. B 1988, 44, 381-386
29. C. Bisi Castellani, O. Carugo, M. Giusti, Eur. J. Solid State Inorg. Chem. 1995, 32, 1089-1099.
30. 3/m; however, vacancies occur for Er-Lu (0≤x≤1) and Sc (x ≈ 1);
31. see, A. Abbasi, P. Lindqvist-Reis, L. Eriksson, D. Sandstr̈m, S. Lidin, I. Persson, M. Sandstr̈m, Chem. Eur. J. 2005, 11, 4065-4077
32. I. Persson, P. D'Angelo, S. De Panfilis, M. Sandstr̈m, L. Eriksson, Chem. Eur. J. 2008, 14, 3056-3066.
33. G. Ionova, C. Madic, R. Guillaumont, Polyhedron 1998, 17, 1991-1995.
34. III hydrates have been characterized to date. These include various chloride, bromide, and sulfate salts; see, A. Mech, M. Karbowiak, T. Lis, J. Drożdżyński, Polyhedron 2006, 25, 2083-2092;
35. J. Drożdżyński, Coord. Chem. Rev. 2005, 249, 2351-2373.
36. J.-C. Berthet, M. Lance, M. Nierlich, M. Ephritikhine, Eur. J. Inorg. Chem. 1999, 2005-2007
37. L. Natrajan, M. Mazzanti, J.-P. Bezombes, J. Pécaut, Inorg. Chem. 2005, 44, 6115-6121.
38. CCDC 765808, CCDC 765809, CCDC 765810, CCDC 765811, and CCDC 765812 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www. ccdc.cam.ac.uk/data-request/cif.
39. R. E. Gerkin,W. J. Reppart, Acta Crystallogr. Sect. C 1984, 40, 781-786
40. J. Albertsson, I. Elding, Acta Crystallogr. Sect. B 1977, 33, 1460-1469.
41. R. D. Shannon, Acta Crystallogr. Sect. A 1976, 32, 751-767
42. F. David, J. Less-Common Met. 1986, 121, 27-42
43. J.K. Beattie, S. P. Best, B. W. Skelton, A. H. White, J. Chem. Soc. Dalton Trans. 1981, 2105-2111.
44. P. Lindqvist-Reis, C. Walther, R. Klenze, N. M. Edelstein, J. Phys. Chem. C 2009, 113, 449-458.
45. G. B. Deacon, T. D. Toung, Polyhedron 1988, 7, 249-250
46. D. L. Clark, A. P. Sattelberger, S. G. Bott, R. N. Vrtis, Inorg. Chem. 1989, 28, 1771-1773
47. L. R. Avens, S. G. Bott, D. L. Clark, A. P. Sattelberger, J. G. Watkin, B. D. Zwick, Inorg. Chem. 1994, 33, 2248-2256
48. W. J. Evans, S. A. Kozimor, J. W. Ziller, A. A. Fagin, M. N. Bochkarev, Inorg. Chem. 2005, 44, 3993-4000
49. C. D. Carmichael, N. A. Jones, P. L. Arnold, Inorg. Chem. 2008, 47, 8577-8589.
50. G. Brauer, Handbuch der Präparativen Anorganischen Chemie, Bd. 3, F. Enke Verlag, Stuttgart, 1981, pp. 2064-2065.
51. P. A. M. Dirac, Proc. R. Soc. London, Ser. A 1929, 123, 714-733
52. J. C. Slater, Phys. Rev. 1951, 81, 385-390;
53. S. H. Vosko, L. Wilk, M. Nusair, Can. J. Phys. 1980, 58, 1200-1211
54. J. P. Perdew, Phys. Rev. B 1986, 33, 8822-8824
55. A. D. Becke, Phys. Rev. A 1988, 38, 3098-3100
56. K. Eichkorn, O. Treutler, H. Öhm, M. Häser, R. Ahlrichs, Chem. Phys. Lett. 1995, 242, 283-290
57. Erratum: K. Eichkorn, O. Treutler, H. Öhm, M. Häser, R. Ahlrichs, Chem. Phys. Lett. 1995, 242, 652
58. K. Eichkorn, F. Weigend, O. Treutler, R. Ahlrichs, Theor. Chim. Acta 1997, 97, 119-124
59. TURBOMOLE V6.0, TURBOMOLE GmbH Karlsruhe, 2009; http://www.turbomole.com;
60. F. Weigend, R. Ahlrichs, Phys. Chem. Chem. Phys. 2005, 7, 3297-3305
61. M. Dolg, H. Stoll, A. Savin, H. Preuss, Theor. Chim. Acta 1989, 75, 173-194
62. M. Dolg, H. Stoll, H. Preuss, Theor. Chim. Acta 1993, 85, 441-450
63. A. Moritz, X. Cao, M. Dolg, Theor. Chem. Acc. 2007, 117, 473-481
64. X. Cao, M. Dolg, H. Stoll, J. Chem. Phys. 2003, 118, 487-496
65. X. Cao, M. Dolg, J. Mol. Struct. 2004, 673, 203-209
66. F. Weigend, Phys. Chem. Chem. Phys. 2006, 8, 1057-1065
67. N. L. Banik, B. Schimmelpfennig, C. M. Marquardt, B. Brendebach, A. Geist, M. A. Denecke, Dalton Trans. 2010, 5117-5122.