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3+ aqua ions is governed mainly by steric and electrostatic interactions. This gives rise to relatively high kinetic lability with considerably high exchange rates between the waters in the first and second hydration spheres; the TTP coordination geometry is thus the mean structure.
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3+ aqua ions is governed mainly by steric and electrostatic interactions. This gives rise to relatively high kinetic lability with considerably high exchange rates between the waters in the first and second hydration spheres; the TTP coordination geometry is thus the mean structure.
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In an early EPR study of Cm3+ in [La(H2O) 9](C2H5SO4)3, no details were given about the zero-field splitting of the 8Ś 7/2 multiplet. Abraham, M, Judd, B. R, Wickman, H. H. Phys. Rev. 1963, 130, 611-612
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(a) Broach, R. W.; Williams, J. M. Acta Crystallogr., Sect. B 1979, 35, 2317-2321.
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(b) Gerkin, R. E.; Reppart, W. J. Acta Crystallogr., Sect. C 1984, 40, 781-786.
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Gerkin, R.E.1
Reppart, W.J.2
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25
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84868924709
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3 (0 ≤ x ≤ 1); see refs 19b and c.
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3 (0 ≤ x ≤ 1); see refs 19b and c.
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26
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0035805708
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Matonic, J. H.; Scott, B. L.; Neu, M. P. Inorg. Chem. 2001, 40, 2638-2639.
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28
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84868927211
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252Cf neutron source.
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252Cf neutron source.
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29
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65349112838
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SMART, 5.046 (area detector control), SAINT, 5.01 (integration software), SADABS (empirical absorption correction program), SHELXTL, 5.1, Bruker Analytical X-ray Systems, Madison, WI, 1998.
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SMART, 5.046 (area detector control), SAINT, 5.01 (integration software), SADABS (empirical absorption correction program), SHELXTL, 5.1, Bruker Analytical X-ray Systems, Madison, WI, 1998.
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30
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84868924710
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Crystal structure determination of 4. C10H40Cl 3LaO15, fw, 645.68 g mol-1, orthorhombic, a, 10.7084(14, b, 15.3419(19, c, 15.984(2) Å, V, 2626.0(6) Å3, T, 295(2) K, space group P21212 1 (No. 19, Z, 4, ρcalc, 1.628 g cm-1, μ (Mo KR), 1.99 mm-1, θmax, 27.75°, 16483 reflections measured, 4393 reflections with I> 2σ(I, 6035 independent reflections (R int= 0.0386, 317 parameters, 45 restraints, R[F2 > 2σ(F2, 0.034, wRF2, 0.077, S, 0.93
-
2) = 0.077, S = 0.93.
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-
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31
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65349104339
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DIAMOND 2.1, Crystal Impact GbR, 2001.
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DIAMOND 2.1, Crystal Impact GbR, 2001.
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-
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32
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33744541346
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and references therein
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Abbasi, A.; Eriksson, L. Acta Crystallogr., Sect. E 2006, 62, i126-i128, and references therein.
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Acta Crystallogr., Sect. E
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Abbasi, A.1
Eriksson, L.2
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35
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0000875156
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An early luminescence and absorption spectroscopic paper on Cm 3+ in LaCl3at 77 K reports all four crystal-filed levels (A1-A4) of the 6D́7/2 multiplets at 16813, 16866, 16935, 16977 cm-1; see: Gruber, J. B, Cochran, W. R, Conway, J. G, Nicol, A. T. J. Chem. Phys. 1966, 45, 1423-1427
-
-1; see: Gruber, J. B.; Cochran, W. R.; Conway, J. G.; Nicol, A. T. J. Chem. Phys. 1966, 45, 1423-1427.
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38
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84868924707
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This parameter may be used for comparisons of crystal-field strengths of different fN ions in a given crystal host or for a particular f N ion in different hosts, and it is proportional to the total (δEmax) splitting J levels with small J-mixing; Nv́ is linearly related to Nv (defined in ref 33) according to Nv́, Nv/(2√π, Σk,q (Bk q)2/(2k, 1))1/2
-
1/2.
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39
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0024645593
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Hammond, R. M.; Reid, M. F.; Richardson, F. S. J. Less-Common Met. 1989, 148, 311.
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Hammond, R.M.1
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Richardson, F.S.J.3
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42
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65349196516
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An upper limit for kr may be estimated, for example, in 2 where kobs(H2O), 15.6 ms-1 and k obs(D2O), 0.645 ms-1, and since kr is the same for the hydrated and deuterated compounds, kr < 0.645 ms-1. This value may be compared to that calculated for Cm 3+aq, 0.769 ms-1
-
-1.
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43
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0041322026
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Beeby, A.; Clarkson, I. M.; Dickins, R. S.; Faulkner, S.; Parker, D.; Royle, L.; de Sousa, A. S.; Williams, J. A. G.; Woods, M. J. Chem. Soc., Perkin Trans. 2 1999, 493-503.
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de Sousa, A.S.7
Williams, J.A.G.8
Woods, M.9
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0038037392
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(e) Nelig, A.; Elhabiri, M.; Billard, I.; Albrecht-Gary, A.-M.; Lützenkirchen, K. Radiochim. Acta 2003, 91, 37.
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67649990083
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Lanthanide and Actinide Solution Chemistry Studied by Time-Resolved Emission Spectroscopy
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For recent Review, see:, Gschneidner, K. A, Jr, Bünzli, J.-C, Pecharsky, V. K, Eds, Elsevier: Amsterdam, Chapter 216, section 3.3
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(h) For recent Review, see: Billard, I. Lanthanide and Actinide Solution Chemistry Studied by Time-Resolved Emission Spectroscopy. In Handbook on the Physics and Chemistry of Rare Earths; Gschneidner, K. A., Jr., Bünzli, J.-C., Pecharsky, V. K., Eds.; Elsevier: Amsterdam, 2003; Vol. 33, Chapter 216, section 3.3.
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