Berkelium redox speciation

Radiochimica Acta

Volumn 90, Issue 12, 2002, Pages 851-856

  Antonio, Mark R ^a   Williams, Clayton W ^a   Soderholm, L ^a  

^a ARGONNE NATIONAL LABORATORY   (United States)

Author keywords

Aquo ion; Berkelium; EXAFS; Hydration; Nernst analysis; Spectroelectrochemistry; XANES

Indexed keywords

ACTINIDE; BERKELIUM; HYDROXIDE; LANTHANIDE; PERCHLORIC ACID; WATER;

ABSORPTION SPECTROPHOTOMETRY; ARTICLE; CHEMICAL BOND; CYCLIC POTENTIOMETRY; ELECTROCHEMISTRY; HYDRATION; OXIDATION REDUCTION POTENTIAL; OXIDATION REDUCTION REACTION;

EID: 0038710444     PISSN: 00338230     EISSN: None     Source Type: Journal    
DOI: 10.1524/ract.2002.90.12_2002.851     Document Type: Article

References (35)

1. Katz, J. J., Seaborg, G. T., Morss, L. R. (eds.): The Chemistry of the Actinide Elements. Chapman and Hall, London (1986).
2. David, F. H., Fourest, B.: Structure of trivalent lanthanide and actinide aquo ions. New J. Chem. 21, 167 (1997).
3. Fourest, B., Duplessis, J., David, F.: Hydrated radii determination for some trivalent actinide ions. C. R. Seances Acad. Sci., Ser. 2 294, 1179 (1982).
4. Latrous, H., Oliver, J.: Self-diffusion coefficients and structure of the trivalent transplutonium ion berkelium in aqueous solution. J. Mol. Liq. 81, 115 (1999).
5. Lundqvist, R., Hulet, E. K., Baisden, P. A.: Electromigration method in tracer studies of complex chemistry. II. Hydrated radii and hydration numbers of trivalent actinides. Acta Chem. Scand., Ser. A 35, 653 (1981).
6. Hobart, D. E., Peterson, J. R.: Berkelium. In: The Chemistry of the Actinide Elements. (Katz, J. J., Seaborg, G. T., Morss, L. R., eds.) Chapman and Hall, London (1986) Vol. 2, p. 989.
7. Soderholm, L., Antonio, M. R., Williams, C., Wasserman, S. R.: XANES spectroelectrochemistry: A new method for determining formal potentials. Anal. Chem. 71, 4622 (1999).
8. Antonio, M. R., Soderholm, L., Song, I.: Design of spectroelectrochemical cell for in situ X-ray absorption fine structure measurements of bulk solution species. J. Appl. Electrochem. 27, 784 (1997).
9. Peppard, D. F., Moline, S. W., Mason, G. W.: Isolation of berkelium by solvent extraction of the quadrivalent species. J. Inorg. Nucl. Chem. 4, 344 (1957).
10. Bott, A. W.: Practical problems in voltammetry 3: Reference electrodes for voltammetry. Current Separations 14, 64 (1995).
11. Beno, M. A., Engbretson, M., Jennings, G., Knapp, G. S., Linton, J., Kurtz, C., Rütt, U., Montano, P. A.: BESSRC-CAT bending magnet beamline at the advanced photon source. Nucl. Instrum. Methods Phys. Res., Sect. A 467-468, 699 (2001).
12. Ressler, T.: WinXAS: a program for X-ray absorption spectroscopy data analysis under MS-Windows. J. Synchrotron Radiat. 5, 118 (1998).
13. Antonio, M. R., Soderholm, L., Williams, C. W., Blaudeau, J. P., Bursten, B. E.: Neptunium redox speciation. Radiochim. Acta 89, 17 (2001).
14. Rehr, J. J., Leon, J. M., de Zabinsky, S. I., Albers, R. C.: Theoretical X-ray absorption fine structure standards. J. Am. Chem. Soc. 113, 5135 (1991).
15. Rehr, J. J., Albers, R. C.: Theoretical approaches to X-ray absorption fine structure. Rev. Mod. Phys. 72, 621 (2000).
16. Conradson, S. D., Al Mahamid, I., Clark, D. L., Hess, N. J., Hudson, E. A., Neu, M. P., Palmer, P. D., Runde, W. H., Tait, C. D.: Oxidation state determination of plutonium aquo ions using X-ray absorption spectroscopy. Polyhedron 17, 599 (1998).
17. 8. Z. Phys. B 101, 539 (1996).
18. 8 (x = 0.0 and 0.5). Phys. Rev. B: Condens. Matter Mater. Phys. 64, 144521 (2001).
19. Morris, D. E., Hobart, D. E., Palmer, P. D., Haire, R. G., Peterson, J. R.: Voltammetric investigation of the berkelium(IV/III) couple in concentrated aqueous carbonate solutions. Radiochim. Acta 49, 125 (1990).
20. Propst, R. C., Hyder, M. L.: Electrochemistry of berkelium in acidic aqueous solution. J. Inorg. Nucl. Chem. 32, 2205 (1970).
21. Stokely, J. R., Baybarz, R. D., Peterson, J. R.: Formal potential of the berkelium(IV)-berkelium(III) couple in several media. J. Inorg. Nucl. Chem. 34, 392 (1972).
22. Simakin, G. A., Kosyakov, V. N., Baranov, A. A., Erin, E. A., Kopytov, V. V., Timofeev, G. A.: Redox potentials of a berkelium(IV)-berkelium(III) couple. II. Measurement of redox potentials of berkelium(IV)-berkelium(III) and cerium(IV)-cerium(III) couples in perchloric and nitric acid solutions. Soviet Radiochem., Engl. Transl. 19, 302 (1977).
23. Bratsch, S. G.: Standard electrode potentials and temperature coefficients in water at 298.15 K. J. Phys. Chem. Ref. Data 18, 1 (1989).
24. Shannon, R. D.: Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Cryst. A 32, 751 (1976).
25. 3+ is not tabulated for other CNs, all comparisons are made with the IR for CN = VI of Ref. [24].
26. Peterson, J. R., Cunningham, B. B.: Crystal structures and lattice parameters of the compounds of berkelium. I. Berkelium oxide and cubic berkelium sesquioxide. Inorg. Nucl. Chem. Lett. 3, 327 (1967).
27. Kimura, T., Choppin, G. R., Kato, Y., Yoshida, Z.: Determination of the hydration number of Cm(III) in various aqueous solutions. Radiochim. Acta 72, 61 (1996).
28. 249Cf aquo ion by X-ray absorption spectroscopy. Inorg. Chem. 38, 4139 (1999).
29. Latrous, H., Olivier, J., Chemla, M.: Self-diffusion coefficients and structure of the trivalent transplutonium ion berkelium-249 in aqueous solution. Z. Phys. Chem. (Munich) 159, 195 (1988).
30. 3, and series behavior. J. Chem. Phys. 73, 442 (1980).
31. Yaita, T., Narita, H., Suzuki, S., Tachimori, S., Motohashi, H., Shiwaku, H.: Structural study of lanthanides(III) in aqueous nitrate and chloride solutions by EXAFS. J. Radioanal. Nucl. Chem. 239, 371 (1999).
32. Yamaguchi, T., Nomura, M., Wakita, H., Ohtaki, H.: An extended X-ray absorption fine structure study of aqueous rare earth perchlorate solutions in liquid and glassy states. J. Chem. Phys. 89, 5153 (1988).
33. Conradson, S. D.: Application of X-ray absorption fine structure spectroscopy to materials and environmental science. Appl. Spectros. 52, 252A (1998).
34. 3. J. Chem. Phys. 70, 2797 (1979).
35. α X-ray lines and several KLL Auger lines. J. Phys. Chem. Ref. Data 8, 329 (1979).