Manganese valence in oxides formed from in situ chemical oxidation of TCE by KMnO4

Environmental Science and Technology

Volumn 44, Issue 15, 2010, Pages 5934-5939

  Loomer, Diana B ^a   Al, Tom A ^a   Banks, Vernon J ^a,d   Parker, Beth L ^b   Mayer, K Ulrich ^c  

^a UNIVERSITY OF NEW BRUNSWICK   (Canada)

^b UNIVERSITY OF GUELPH   (Canada)

^c UNIVERSITY OF BRITISH COLUMBIA   (Canada)

^d AMECEarth and Environmental   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

CHLORINATED SOLVENT; COLUMN EXPERIMENTS; IN-SITU; MN OXIDATION; PH CONDITION; PREPARATION METHOD; XPS;

AQUIFERS; ELECTRON ENERGY LOSS SPECTROSCOPY; MANGANESE; OXIDATION; OXIDES; TRICHLOROETHYLENE; X RAY PHOTOELECTRON SPECTROSCOPY;

MANGANESE OXIDE;

MANGANESE OXIDE; TRICHLOROETHYLENE;

CHEMICAL REACTION; EXPERIMENTAL STUDY; MANGANESE; MANGANESE OXIDE; OXIDATION; PH; SPECTROSCOPY;

AQUIFER; ARTICLE; CHEMICAL REACTION; CHLORINATION; ELECTRON ENERGY LOSS SPECTROSCOPY; OXIDATION; PH; X RAY PHOTOELECTRON SPECTROSCOPY;

MANGANESE; OXIDATION-REDUCTION; OXIDES; PHOTOELECTRON SPECTROSCOPY; POTASSIUM PERMANGANATE; SPECTROSCOPY, ELECTRON ENERGY-LOSS; TRICHLOROETHYLENE;

EID: 77955123517     PISSN: 0013936X     EISSN: 15205851     Source Type: Journal    
DOI: 10.1021/es100879w     Document Type: Article

References (45)

1. Schnarr, M.; Truax, C.; Farquhar, G.; Hood, E.; Gonullu, T.; Stickney, B. Laboratory and controlled field experiments using potassium permanganate to remediate trichloroethylene and perchloroethylene DNAPLs in porous media J. Contam. Hydrol. 1998, 29, 205-224
2. 4 in a sandy aquifer Environ. Sci. Technol. 2001, 35, 1266-1275
3. 2 genesis during permanganate oxidation J. Environ. Eng. 2004, 130, 562-572
4. Thomson, N. R.; Hood, E. D.; Farquhar, G. J. Permanganate treatment of an emplaced DNAPL source Ground Water Monit. Rem. 2007, 27, 74-85
5. 2 particle stabilization: Evaluation in 1-D transport systems J. Contam. Hydrol. 2009, 105, 69-79
6. Heiderscheidt, J. L.; Siegrist, R. L.; Illangasekare, T. H. Intermediate-scale 2D experimental investigation of in situ chemical oxidation using potassium permanganate for remediation of complex DNAPL source zones J. Contam. Hydrol. 2008, 102, 3-16
7. Siegrist, R. L.; Urynowicz, M. A.; Crimi, M. L.; Lowe, K. S. Genesis and effects of particles produced during in situ chemical oxidation using permanganate J. Environ. Eng. 2002, 128, 1068-1079
8. Li, X. D.; Schwartz, F. W. DNAPL mass transfer and permeability reduction during in situ chemical oxidation with permanganate Geophys. Res. Lett. 2004, 31, 5
9. Crimi, M. L.; Siegrist, R. L. Geochemical effects on metals following permanganate oxidation of DNAPLS Ground Water 2003, 41, 458-469
10. 4 J. Contam. Hydrol. 2006, 88, 137-152
11. Li, X. D.; Schwartz, F. W. DNAPL remediation with in situ chemical oxidation using potassium permanganate. Part I. Mineralogy of Mn oxide and its dissolution in organic acids J. Contam. Hydrol. 2004, 68, 39-53
12. Lind, C. J.; Hem, J. D. Manganese minerals and associated fine particulates in the streambed of Pinal Creek, Arizona, U.S.A.: a mining-related acid drainage problem Appl. Geochem. 1993, 8, 67-80
13. 4+ oxides. In Geol. Soc. Spec. Publ.; Nicholson, K.; Hein, J. R.; Bühn, B.; Dasgupta, S., Eds.; The Geological Society: Bath, U.K., 1997; Vol. 119, pp 265 - 280.
14. Post, J. E. Manganese oxide minerals: Crystal structures and economic and environmental significance Proc. Natl. Acad. Sci. U.S.A. 1999, 96, 3447-3454
15. Silvester, E.; Manceau, A.; Drits, V. A. Structure of synthetic monoclinic Na-rich birnessite and hexagonal birnessite: II. Results from chemical studies and EXAFS spectroscopy Am. Mineral. 1997, 82, 962-978 (Pubitemid 127568297)
16. Banerjee, D.; Nesbitt, H. W. Oxidation of aqueous Cr(III) at birnessite surfaces: Constraints on reaction mechanism Geochim. Cosmochim. Acta 1999, 63, 1671-1687
17. Banerjee, D.; Nesbitt, H. W. XPS study of reductive dissolution of birnessite by oxalate: Rates and mechanistic aspects of dissolution and redox processes Geochim. Cosmochim. Acta 1999, 63, 3025-3038
18. 2 precipitation Am. Mineral. 1998, 83, 305-315
19. McKeown, D. A.; Post, J. E. Characterization of manganese oxide mineralogy in rock varnish and dendrites using X-ray adsorption spectroscopy Am. Mineral. 2001, 86, 701-713
20. Pecher, K.; McCubbery, D.; Kneedler, E.; Rothe, J.; Bargar, J.; Meigs, G.; Cox, L.; Nealson, K.; Tonner, B. Quantitative charge state analysis of manganese biominerals in aqueous suspension using Scanning Transmission X-ray Microscopy (STXM) Geochim. Cosmochim. Acta 2003, 67, 1089-1098
21. Artyushkova, K.; Farrar, J. O.; Fulghum, J. E. Data fusion of XPS and AFM images for chemical phase identification in polymer blends Surf. Interface Anal. 2009, 41, 119-126
22. Templeton, A.; Knowles, E. Microbial transformations of minerals and metals: Recent advances in geomicrobiology derived from synchrotron-based X-ray spectroscopy and X-ray microscopy Annu. Rev. Earth Planet. Sci. 2009, 37, 367-391
23. Loomer, D. B.; Al, T. A.; Weaver, L.; Cogswell, S. Manganese valence imaging in Mn minerals at the nanoscale using STEM-EELS Am. Mineral. 2007, 92, 72-79
24. 4+ in manganese oxides as revealed by parallel EELS Ultramicroscopy 1994, 54, 83-92
25. Kurata, H.; Colliex, C. Electron-energy-loss core-edge structures in manganese oxides Phys. Rev. B: Condens. Matter 1993, 48, 2102-2108
26. 2,3-edges in inorganic manganese compounds Phys. Chem. Miner. 1994, 21, 191-206
27. Egerton, R. F. Electron energy-loss spectroscopy in the electron microscope, ed. 2; Plenum Press: New York, 1996.
28. Cavé, L.; Al, T.; Loomer, D.; Cogswell, S.; Weaver, L. A STEM/EELS method for mapping iron valence ratios in oxide minerals Micron 2006, 37, 301-309
29. Murray, J. W.; Dillard, J. G.; Giovanoli, R.; Moers, H.; Stumm, W. Oxidation of Mn(II): Initial mineralogy, oxidation state and ageing Geochim. Cosmochim. Acta 1985, 49, 463-470
30. Ross, D. S.; Hales, H. C.; Shea-McCarthy, G. C.; Lanzirotti, A. Sensitivity of soil manganese oxides: drying and storage cause reduction Soil Sci. Soc. Am. J. 2001, 65, 736-743 (Pubitemid 32550449)
31. Korshin, G. V.; Chang, H.-S.; Frenkel, A. I.; Ferguson, J. F. Structural study of the incorporation of heavy metals into solid phase formed during oxidation of EDTA by permanganate at high pH Environ. Sci. Technol. 2007, 41, 2560-2565
32. Kim, K.; Gurol, M. D. Reaction of nonaqueous phase TCE with permanganate Environ. Sci. Technol. 2005, 39, 9303-9308
33. Simandi, L. I.; Jaky, M. Nature of the detectable intermediate in the permanganate oxidation of trans -cinnamic acid J. Am. Chem. Soc. 1976, 98, 1995-1997
34. Ulrich, H.-J.; Stone, A. T. Oxidation of chlorophenols adsorbed to manganese oxide surfaces Environ. Sci. Technol. 1989, 23, 421-428
35. Perez-Benito, J. F.; Arias, C. Occurrence of colloidal manganese dioxide in permanganate reactions J. Colloid Interface Sci. 1992, 152, 70-84
36. Insausti, M. J.; Mata-Pérez, F.; Alvarez-Macho, P. Kinetic study of the oxidation of L-phenylalanine by potassium permanganate in acid medium Int. J. Chem. Kinet. 1995, 27, 507-515
37. Yan, Y. E.; Schwartz, F. W. Oxidative degradation and kinetics of chlorinated ethylenes by potassium permanganate J. Contam. Hydrol. 1999, 37, 343-365
38. 2O at 25° and one atmosphere total pressure Am. Mineral. 1965, 50, 1296-1354
39. Rhazi, M. A.; Hayashi, K. Origin and formational environment of Noda-Tamagawa Manganese Ore, Northeast Japan: Constraints from isotopic studies Chem. Erde-Geochem. 2003, 63, 149-162
40. Zhang, F.-S.; Lin, C.-Y.; Bian, L.-Z.; Glasby, G. P.; Zhamoida, V. A. Possible evidence for the biogenic formation of spherical ferromanganese concretions from the eastern Gulf of Finland, the Baltic Sea Baltica 2002, 15, 23-29
41. Morgan, J. J.; Stumm, W. Colloid-chemical properties of manganese dioxide J. Colloid Sci. 1964, 19, 347-359
42. Hem, J. D.; Lind, C. J. Nonequilibrium models for predicting forms of precipitated manganese oxides Geochim. Cosmochim. Acta 1983, 47, 2037-2046
43. 14C] dichloroethene under Mn(IV)-reducing conditions Appl. Enivron. Microb. 1998, 64, 1560-1562
44. Hrapovic, L.; Sleep, B. E.; Major, D. J.; Hood, E. D. Laboratory study of treatment of trichloroethene by chemical oxidation followed by bioremediation Environ. Sci. Technol. 2005, 39, 2888-2897
45. Sahl, J. W.; Munakata-Marr, J.; Crimi, M. L.; Siegrist, R. L. Coupling permanganate oxidation with microbial dechlorination of tetrachloroethene Water Environ. Res. 2007, 79, 5-12