Impact of reaction conditions on MnO2 genesis during permanganate oxidation

Journal of Environmental Engineering

Volumn 130, Issue 5, 2004, Pages 562-572

  Crimi, Michelle L ^a   Siegrist, Robert L ^a  

^a Department of Metallurgical and Materials Engineering   (United States)

Author keywords

Calcium; Contaminants; Degradation; Oxidation; Permeability; TCE

Indexed keywords

FILTRATION; MANGANESE COMPOUNDS; OXIDATION; PH EFFECTS; PRECIPITATION (CHEMICAL); SCANNING ELECTRON MICROSCOPY;

BATCH EXPERIMENTS; IN SITU CHEMICAL OXIDATION (ISCO);

ENVIRONMENTAL ENGINEERING;

OXIDATION; PRECIPITATION (CHEMISTRY);

EID: 2442531849     PISSN: 07339372     EISSN: None     Source Type: Journal    
DOI: 10.1061/(ASCE)0733-9372(2004)130:5(562)     Document Type: Article

References (23)

1. American Public Health Association (APHA). (1998). Standard methods for the examination of water and wastewater. 20th Ed., L. S. Clesceri, A. E. Greenberg, and R. R. Trussell, eds., APHA-AWWA-WPCF, Washington, D.C.
2. Chandrakanth, M. S., and Amy, G. L. (1996). "Effects of ozone on the colloidal stability and aggregation of particles coated with natural organic matter." Environ. Sci. Technol., 30(2), 431-442.
3. Crimi, M. L. (2002). "Particle genesis and effects on metals in the subsurface during in situ chemical oxidation using permanganate." PhD dissertation, Colorado School of Mines, Golden, Colo.
4. Doona, C. J., and Schneider, F. W. (1993). "Identification of colloidal Mn(IV) in permanganate oscillating reactions." J. Am. Chem. Soc., 115, 9683-9686.
5. Fu, G., Allen, H. E., and Cowan, C. E. (1991). "Adsorption of cadmium and copper by manganese oxide." Soil Sci., 152(2), 72-81.
6. Huang, K. H., Hoag, G. E., Chheda, P., Woody, B. A., and Dobbs, G. M. (1999). "Kinetic study of oxidation of trichloroethylene by potassium permanganate." Environ. Eng. Sci., 16(4), 265-274.
7. Insausti, M. J., Mata-Perez, F., and Alvarez-Macho, P. (1992). "Permanganate oxidation of glycine: Influence of amino acid on colloidal manganese dioxide." Int. J. Chem. Kinet., 24(5), 411-419.
8. Insausti, M. J., Mata-Perez, F., and Alvarez-Macho, P. (1993). "UV-VIS spectrophotometric study and dynamic analysis of the colloidal product of permanganate oxidation of α-amino acids." React. Kinet. Catal. Lett., 51(1), 51-59.
9. McKenzie, R. M. (1977). "Manganese oxides and hydroxides." Minerals in soil environments, J. B. Dixon and S. B. Weed, eds., Soil Society of America, Madison, Wis., 181-193.
10. Morgan, J. J., and Stumm, W. (1964). "Colloid-chemical properties of manganese dioxide." J. Colloid Sci., 19, 347-359.
11. Perez-Benito, J. F., and Arias, C. (1991). "A kinetic study of the permanganate oxidation of triethylamine. Catalysis by soluble colloids." Int. J. Chem. Kinet., 23, 717-732.
12. Perez-Benito, J. F., and Arias, C. (1992a). "A kinetic study of the reaction between soluble (colloidal) manganese dioxide and formic acid." J. Colloid Interface Sci., 149(1), 92-97.
13. Perez-Benito, J. F., and Arias, C. (1992b). "Occurrence of colloidal manganese dioxide in permanganate reactions." J. Colloid Interface Sci., 152(1), 70-84.
14. Perez-Benito, J. F., Arias, C., and Brillas, E. (1990). "A kinetic study of the autocatalytic permanganate oxidation of formic acid." Int. J. Chem. Kinet., 22, 261-287.
15. Perez-Benito, J. F., Brillas, E., and Pouplana, R. (1989). "Identification of a soluble form of colloidal manganese (IV ." Inorg. Chem., 28, 390-392.
16. Siegrist, R. L., Urynowicz, M. A., Crimi, M. L., and Lowe, K. S. (2002). "Genesis and effects of particles produced during in situ chemical oxidation using permanganate." J. Environ. Eng., 128(11), 1068-1079.
17. Siegrist, R. L., Urynowicz, M. A., West, O. R., Crimi, M. L., and Lowe, K. S. (2001). Principles and practices of in situ chemical oxidation using permanganate, Battelle, Columbus, Ohio.
18. Struse, A. M., Siegrist, R. L., Dawson, H. E., and Urynowicz, M. A. (2002). "Diffusive transport of permanganate during in situ oxidation." J. Environ. Eng., 128(4), 327-334.
19. Urynowicz, M. A. (2000). "Dense non-aqueous phase trichloroethene degradation with permanganate ion." PhD dissertation, Colorado School of Mines, Golden, Colo.
20. U.S. Environmental Protection Agency (1998). "In situ remediation technology: In situ chemical oxidation." EPA 542-R-98-008, Office of Solid Waste and Emergency Response, Washington, D.C.
21. West, O. R., Cline, S. R., Holden, W. L., Gardner, F. G., Schlosser, B. M., Thate, J. E., Pickering, D. A., and Houk, T. C. (1998a). "A full-scale field demonstration of in situ chemical oxidation through recirculation at the X-701B site." Rep. No. ORNL.TM-13556, Oak Ridge National Laboratory, Oak Ridge, Tenn.
22. West, O. R., Cline, S. R., Siegrist, R. L., Houk, T. C., Holden, W. L., Gardner, F. G., and Schlossner, R. M. (1998b). "A field-scale test of in situ chemical oxidation through recirculation." Proc., Spectrum '98 Int. Conf. on Nuclear and Hazardous Waste Management, Denver, 1051-1057.
23. Yan, Y., and Schwartz, F. W. (1996). "In-situ oxidative dechlorination of trichloroethylene by potassium permanganate." 3rd Int. Conf. on AOTs, Cincinnati.