DNAPL remediation with in situ chemical oxidation using potassium permanganatey. Part I. Mineralogy of Mn oxide and its dissolution in organic acids

Journal of Contaminant Hydrology

Volumn 68, Issue 1-2, 2004, Pages 39-53

  Li, X David ^a   Schwartz, Franklin W ^a  

^a OHIO STATE UNIVERSITY   (United States)

Author keywords

Dissolution; Mineralogy; Mn oxide; Organic ligand; Permanganate; Remediation

Indexed keywords

ACETIC ACID; AMORPHOUS MATERIALS; DISSOLUTION; MANGANESE COMPOUNDS; OXIDATION; POTASSIUM COMPOUNDS; PRECIPITATION (CHEMICAL); PROTONS; REACTION KINETICS; REMEDIATION;

REACTION PRODUCTS; SURFACE AREAS;

HYDROLOGY;

CARBOXYLIC ACID; CITRIC ACID; EDETIC ACID; MANGANESE OXIDE; OXALIC ACID; PERMANGANATE POTASSIUM; TRICHLOROETHYLENE;

DISSOLUTION; MANGANESE OXIDE; NON-AQUEOUS PHASE LIQUID; OXIDATION; POROUS MEDIUM; REMEDIATION; TRICHLOROETHYLENE;

DISSOLUTION; MANGANESE OXIDE; NONAQUEOUS PHASE LIQUID; OXIDATION; POROUS MEDIUM; REMEDIATION; TRICHLOROETHYLENE;

ARTICLE; DISSOLUTION; MINERALOGY; NONAQUEOUS PHASE LIQUID; OXIDATION; PERMEABILITY; PH; PRIORITY JOURNAL; REDUCTION;

EID: 0347052908     PISSN: 01697722     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0169-7722(03)00144-X     Document Type: Article

References (35)

1. Ardizzone S., Trasatti S. Interfacial properties of oxides with technological impact in electrochemistry. Adv. Colloid Interface Sci. 64:1996;173-251.
2. Arndt, D., 1975. Manganese Compounds as Oxidizing Agents in Organic Chemistry. Open Court Publishing, La Salle, IL 1975, pp. 4 and 27.
3. Biber M.V., Afonso M.D.S., Stumm W. The coordination chemistry of weather: IV. Inhibition of the dissolution of oxide minerals. Geochim. Cosmochim. Acta. 58(9):1994;1999-2010.
4. Faure G. Principles and Applications of Geochemistry. 2nd ed. 1998;219 Prentice Hall Press, New Jersey.
5. 3 and BeO. Geochim. Cosmochim. Acta. 50:1986;1847-1860.
6. Insausti M.J., Mata-Perez F., Alvarez-Macho M.P. Kinetic study of the oxidation of L-phenylalanine by potassium permanganate in acid medium. Int. J. Chem. Kinet. 27:1995;507-515.
7. Klewicki J.K., Morgan J.J. Kinetic behavior of Mn(III) complexes of pyrophosphate, EDTA, and Citrate. Environ. Sci. Technol. 32(19):1998;2916-2922.
8. Li X.D., Schwartz F.W. Efficiency problems related to permanganate oxidation schemes. Wickramanayake G.B., Gavaskar A.R., Chen A.S.C. Chemical Oxidation and Reactive Barriers: Remediation of Chlorinated and Recalcitrant Compounds. 2000;41-47 Battelle Press, Columbus, OH.
9. Li X.D., Schwartz F.W. Permanganate oxidation schemes for the remediation of source zone DNAPLs and dissolved contaminant plumes. Henry S.M., Warner S.D. Chlorinated Solvent and DNAPL Remediation. Innovative Strategies for Subsurface Cleanup. 2002;73-85 America Chemical Society Press, Washington, DC.
10. Li X.D., Schwartz F.W. DNAPL remediation with in situ chemical oxidation using potassium permanganate: II. Increasing removal efficiency by dissolving Mn oxide precipitates. J. Contam. Hydrol. 2004;. in press.
11. Liang L., Hofmann A., Gu B. Ligand-induced dissolution and release of ferrihydrite colloids. Geochim. Cosmochim. Acta. 64(12):2000;2027-2037.
12. McKay D.J., Stark J.A., Young B.L., Govoni J.W., Berini C.M., Cronan T.J., Hewitt A.D. A field demonstration of trichloroethylene oxidation using potassium permanganate. Wickramanayake G.B., Gavaskar A.R., Chen A.S.C. Chemical Oxidation and Reactive Barriers: Remediation of Chlorinated and Recalcitrant Compounds. 2000;109-116 Battelle Press, Columbus, OH.
13. Morgan J.J., Stumm W. Colloid-chemical properties of manganese dioxide. J. Coll. Sci. 19:1964;347-359.
14. Mott-Smith E., Leonard W.C., Lewis R., Clayton W.S., Ramirez J. In situ oxidation of DNAPL using permanganate: IDC cape canaveral demonstration. Wickramanayake G.B., Gavaskar A.R., Chen A.S.C. Chemical Oxidation and Reactive Barriers: Remediation of Chlorinated and Recalcitrant Compounds. 2000;125-134 Battelle Press, Columbus, OH.
15. Perez-Benito J.F., Arias C., Amat E. A kinetic study of the reduction of colloidal manganese dioxide by oxalic acid. J. Colloid Interface Sci. 177:1996;288-297.
16. Post J.E. Crystal structures of Manganese oxide minerals. Catena. (Supplement 21):1992;51-73. (Cremlingen).
17. Post J.E. Manganese oxide minerals: crystal structures and economic and environmental significance. Proceedings of National Academy of Science, USA. 96:1999;3447-3454.
18. Post J.E., Veblen D.R. Crystal structure determinations of synthetic sodium magnesium, and potassium birnessite using TEM and Rietveld method. Am. Mineral. 75:1990;477-489.
19. Reitsma S., Marshall M. Experimental study of oxidation of pooled NAPL. Wickramanayake G.B., Gavaskar A.R., Chen A.S.C. Chemical Oxidation and Reactive Barriers: Remediation of Chlorinated and Recalcitrant Compounds. 2000;25-33 Battelle Press, Columbus, OH.
20. Schnarr M., Truax C., Farguhar G., Hood E., Gonullu T., Stickney B. Laboratory and controlled field experiments using potassium permanganate to remediate trichloroethylene and perchloroethylene DNAPLs in porous media. J. Contam. Hydrol. 29(3):1998;205-224.
21. Sigg L., Stumm W. The interaction of anions and weak acids with the hydrous goethite (α-FeOOH) surface. Colloids Surf. 2:1981;101-117.
22. Stewart R. Oxidation by permanganate. Wiberg E.B. Oxidation in Organic Chemistry (Part A). 1965;7 Academic Press, New York.
23. Stone A.T. Microbial metabolites and the reductive dissolution of manganese oxides: oxalate and pyruvate. Geochim. Cosmochim. Acta. 51:1987;919-925.
24. Stone A.T. Reductive Dissolution of manganese(III/IV) oxides by substituted phenols. Environ. Sci. Technol. 21(10):1987;979-988.
25. Stone A.T., Morgan J.J. Reduction and dissolution of manganese (III) and manganese (IV) oxides by organics: Part 2. Survey of the reactivity of organics. Environ. Sci. Technol. 18:1984;617-624.
26. Thomson N.R., Hood E.D., MacKinnon L.K. Source-zone mass removal using permanganate: expectations and potential limitations. Wickramanayake G.B., Gavaskar A.R., Chen A.S.C. Chemical Oxidation and Reactive Barriers: Remediation of Chlorinated and Recalcitrant Compounds. 2000;9-16 Battelle Press, Columbus, OH.
27. Varentsov I.M., Gransselly G.Y. Geology and Geochemistry of Manganese. General Problems: Mineralogy, Geochemistry, Methods. vol. 1:1980;E. Schweizerbart, Stuttgart. pp. 150 and 208.
28. Vella P.A., Veronda B. Oxidation of trichloroethylene: comparison of potassium permanganate and Fenton's reagent. Echenfelder W.W. Chemical Oxidation Technologies for the Nineties. 1992;62-73 Technomic Publishing, Lancaster, Basel.
29. Wang, L., 1996. Adsorpton of (poly)maleic acid and aquatic fulvic acids by goethite. MS thesis, The Ohio State University, 1996.
30. West O.R., Cline S.R., Holden W.L., Gardner F.G., Schlosser B.M., Thate J.E., Pickering D.A., Houk T.C. A full-scale demonstration of in situ chemical oxidation through recirculation at the X-701B site. 1997;101 Oak Ridge National Laboratory, Oak Ridge, TN. ORNL/TM-13556.
31. Wieland E., Wehrli B., Stumm W. The coordination chemistry of weather: III. A generalization on the dissolution rates of minerals. Geochim. Cosmochim. Acta. 52:1988;1969-1981.
32. Yan Y.E., Schwartz F.W. Oxidative degradation and kinetics of chlorinated ethylenes by potassium permanganate. J. Contam. Hydrol. 37(3-4):1999;343-365.
33. Yan Y.E., Schwartz F.W. Kinetics and mechanism for TCE oxidation by permanganate. Environ. Sci. Technol. 34(12):2000;2535-2541.
34. Yoshino Y., Ouchi A., Tsunoda Y., Kojima M. Manganese(III) complexes with ethylenediaminetetraacetic acid. Can. J. Chem. 40:1962;775-783.
35. Zinder B., Furrer G., Stumm W. The coordination chemistry of weather: II. The dissolution of Fe(III) oxides. Geochim. Cosmochim. Acta. 50:1986;1861-1869.