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Volumn 16, Issue 28, 2010, Pages 8285-8290

A bevel-gear-shaped rotor bearing a double-decker porphyrin complex

Author keywords

Molecular devices; Molecular gears; Porphyrinoids; Supramolecular chemistry

Indexed keywords

CHEMICAL STIMULATION; MECHANICAL INTERACTIONS; MOLECULAR DEVICE; MOLECULAR DEVICES; MOLECULAR ROTORS; PORPHYRIN COMPLEXES; PORPHYRINOIDS; ROTATIONAL MOTION; ROTOR BEARING;

EID: 77954855921     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201000276     Document Type: Article
Times cited : (70)

References (72)
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    • for early studies of molecular rotors, see
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    • (1988) Acc. Chem. Res. , vol.21 , pp. 175-182
    • Iwamura, H.1    Mislow, K.2
  • 35
    • 0032722883 scopus 로고    scopus 로고
    • For molecular rotor, motor and gear, see: a
    • For molecular rotor, motor and gear, see: a) L. Raehm, J. M. Kern, J. P. Sauvage, Chem. Eur. J. 1999, 5, 3310-3317;
    • (1999) Chem. Eur. J. , vol.5 , pp. 3310-3317
    • Raehm, L.1    Kern, J.M.2    Sauvage, J.P.3
  • 38
    • 0242720306 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2003, 42, 5182-5185;
    • (2003) Angew. Chem. Int. Ed. , vol.42 , pp. 5182-5185
  • 59
    • 0034596923 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2000, 39, 3348-3391;
    • (2000) Angew. Chem. Int. Ed. , vol.39 , pp. 3348-3391
  • 68
    • 77954856708 scopus 로고    scopus 로고
    • note
    • III coordination bond can be regarded as the robust rotational axis of the side rotor (also see Figure S4 in the Supporting Information).
  • 71
    • 77954854053 scopus 로고    scopus 로고
    • note
    • To obtain direct structural information on 1, we have been trying to obtain single crystals that are suitable for X-ray analyses with and without TEA, but unfortunately we have been unsuccessful at the present stage. As far as we know, there is no report of the singlecrystal analysis of lanthanum(III) bis(porphyrinate). Instead, we utilised a computer-generated model to discuss the mechanical interaction between top and side rotors (see Figure S9 in the Supporting Information).
  • 72
    • 77954857337 scopus 로고    scopus 로고
    • We assume that the slippage would still occur although the activation energies for the rotations of the top and side rotors are almost same
    • We assume that the slippage would still occur although the activation energies for the rotations of the top and side rotors are almost same.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.