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Volumn 130, Issue 28, 2008, Pages 9089-9098

Ranging correlated motion (1.5 nm) of two coaxially arranged rotors mediated by helix inversion of a supramolecular transmitter

Author keywords

[No Author keywords available]

Indexed keywords

SILVER;

EID: 47349113434     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja8014583     Document Type: Article
Times cited : (64)

References (27)
  • 24
    • 47349083399 scopus 로고    scopus 로고
    • The 1H NMR spectrum of [Ag6Hg312·32]12+ complex at 323 K displayed three resonances for protons a, c, and d of 1, exhibiting the relatively free rotation of the two rotors. VT 1H NMR spectra are shown in Figure S10. The formation of [Ag6Hg 312·32]12+ was also demonstrated by ESI-TOF mass spectrometry Figure S6
    • 12+ was also demonstrated by ESI-TOF mass spectrometry (Figure S6).
  • 26
    • 47349096847 scopus 로고    scopus 로고
    • In this study the synchronous helix inversions were demonstrated for the RTRs. Since the helix inversion takes place both by the ligand exchange (EX) and the flip motion (flip, if both motions take place at the same frequency, every co-occurring combination of the ligand exchange and the flip motion on both sides, that is, EX(rotor A)-EX(rotor B, EX(rotor A)-flip(rotor B, flip(rotor A)-EX(rotor B, or flip(rotor A)-flip(rotor B) is possible. In the present case, the detailed information is missing on this point
    • In this study the synchronous helix inversions were demonstrated for the RTRs. Since the helix inversion takes place both by the ligand exchange (EX) and the flip motion (flip), if both motions take place at the same frequency, every co-occurring combination of the ligand exchange and the flip motion on both sides, that is, EX(rotor A)-EX(rotor B), EX(rotor A)-flip(rotor B), flip(rotor A)-EX(rotor B), or flip(rotor A)-flip(rotor B) is possible. In the present case, the detailed information is missing on this point.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.