MHz unidirectional rotation of molecular rotary motors

Journal of the American Chemical Society

Volumn 130, Issue 32, 2008, Pages 10484-10485

  Klok, Martin ^a   Boyle, Nicola ^b   Pryce, Mary T ^b   Meetsma, Auke ^a   Browne, Wesley R ^a   Feringa, Ben L ^a  

^a UNIVERSITY OF GRONINGEN   (Netherlands)

^b DUBLIN CITY UNIVERSITY   (Ireland)

Author keywords

[No Author keywords available]

Indexed keywords

MOLECULAR MOTOR;

ABSORPTION SPECTROSCOPY; ARTICLE; CHEMICAL STRUCTURE; ENVIRONMENTAL TEMPERATURE; KINETICS;

CIRCULAR DICHROISM; COLD; CYCLOPENTANES; ROTATION; SOLUTIONS; SPECTROPHOTOMETRY, ULTRAVIOLET;

EID: 49449086629     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja8037245     Document Type: Article

References (27)

1. Molecular Motors; Schliwa, M., Ed.; Wiley-VCH: Weinheim, Germany, 2003.
2. Vale, R. D.; Milligan, R. A. Science 2000, 288, 88, and references therein.
3. (a) Boyer, P. D. Angew. Chem., Int. Ed. 1998, 37, 2296.
4. (b) Walker, J. E. Angew. Chem., Int. Ed. 1998, 37, 2308.
5. (a) Balzani, V.; Credi, A.; Raymo, F. M.; Stoddart, J. F. Angew. Chem., Int. Ed. 2000, 39, 3349.
6. (b) Feringa, B. L.; van Delden, R. A.; Koumura, N.; Geertsema, E. M. Chem. Rev. 2000, 100, 1789.
7. (c) Browne, W. R.; Feringa, B. L. Nat. Nanotechnol. 2006, 1, 25.
8. (d) Stoddard, J. F., Acc. Chem. Res. 2000, 100, 409.
9. (e) Leigh, D. A.; Zerbetto, F.; Kay, E. R. Angew. Chem., Int. Ed. 2007, 46, 72.
10. Feringa, B. L. J. Org. Chem. 2007, 72, 6635.
11. Fletcher, S. P.; Dumur, F.; Pollard, M. M.; Feringa, B. L. Science 2005, 310, 80.
12. Vicario, J.; Walko, M.; Meetsma, A.; Feringa, B. L. J. Am. Chem. Soc. 2006, 128, 5127.
13. Pollard, M. M.; Klok, M.; Pijper, D.; Feringa, B. L. Adv. Funct. Mater. 2007, 17, 718.
14. (a) Waldeck, D. H. Chem. Rev. 1991, 91, 415.
15. (b) Meier, H. Angew Chem., Int. Ed. 1992, 31, 1399.
16. (c) Zijlstra, R. W. J.; van Duijnen, P. T.; Feringa, B. L.; Steffen, T.; Duppen, K.; Wiersma, D. A. J. Phys. Chem. A 1997, 101, 9828.
17. (d) Schuddeboom, W.; Jonker, S. A.; Warman, J. M.; de Haas, M. P.; Vermeulen, M. J. W.; Jager, W. F.; de Lange, B.; Feringa, B. L.; Fessenden, R. W. J. Am. Chem. Soc. 1993, 115, 3286.
18. Koumura, N.; Geertsema, E. M.; van Gelder, M. B.; Meetsma, A.; Feringa, B. L. J. Am. Chem. Soc. 2002, 124, 5037.
19. Ter Wiel, M. K. J.; Vicario, J.; Davey, S. G.; Meetsma, A.; Feringa, B. L. Org. Biomol. Chem. 2005, 3, 28.
20. Macanita, A. L.; Moreira, P. F.; Lima, J. C.; Quina, F. H.; Yihwa, C.; Vautier-Giongo, C. J. Phys. Chem. A. 2002, 106, 1248.
21. Devanathan, S; Genick, U. K.; Canestrelli, I. G.; Meyer, T. E.; Cusanovich, M. A.; Getzoff, E. D.; Tollin, G. Biochemistry 1998, 37, 11563.
22. Agranat, I.; Kalisky, O; Tapuhi, Y. J. Org. Chem. 1979, 44, 1949.
23. 1/2 (20°C) = 2.9 and 2.6 h for thermal cis to trans and trans to cis conversion, respectively).
24. For properties of this solvent combination see: (a) Fischer, E.; Greenspan, H. J. Phys. Chem. 1965, 2466.
25. (b) von Salis, G. A.; Labhart, H. J. Phys. Chem. 1967, 752.
26. Thermal isomerization of stable isomers can be neglected in the TA kinetic analysis because of the longer time scale of that process.
27. 1/2 (20 °C) = 20 d and 14.8 d).