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2 (10mol%) or pyridine (10mol%) did not implov the yield of 3aa. The reaction of 2a with carbonylsalicylamides 1, which proceed via elimination of other isocyanate, such as methyl isocyanate, 2-pyridyl isocyanate, did not give cycloadduct 3
-
2 (10mol%) or pyridine (10mol%) did not implov the yield of 3aa. The reaction of 2a with carbonylsalicylamides 1, which proceed via elimination of other isocyanate, such as methyl isocyanate, 2-pyridyl isocyanate, did not give cycloadduct 3.
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23
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0002523083
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For Ni catalyzed [2 + 2 + 2] cycloaddition of alkynes and isocyanates, see: a
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77954807476
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1HNMR spectroscopy of crude reaction mixture (ca. 30% yield). The side product, N-phenyl-3,4,5,6-tetrapropyl-2-pyridone, was observed in ca. 10% yield
-
1HNMR spectroscopy of crude reaction mixture (ca. 30% yield). The side product, N-phenyl-3,4,5,6-tetrapropyl-2-pyridone, was observed in ca. 10% yield.
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31
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0037148763
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For pioneering works of transition-metal-catalyzed reaction, involving β-elimination of oxygen, see: a
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